2,2-bis(indane-1',3'-dione-2'-yl)indane-1,3-dione | 117310-83-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 2,2-bis(indane-1',3'-dione-2'-yl)indane-1,3-dione
• 英文别名: trisindanedione；[2,2';2',2'']terindene-1,3,1',3',1'',3''-hexaone；[2,2';2',2'']Terinden-1,3,1',3',1'',3''-hexaon；Trisindandion；Trisdiketohydrinden；2,2-Bis(1,3-dioxoinden-2-yl)indene-1,3-dione
• CAS: 117310-83-5
• 化学式: C₂₇H₁₄O₆
• 分子量: 434.405
• InChiKey: RJMJEOBWIGVPFM-UHFFFAOYSA-N

物化性质

• 熔点：
  282-284 °C (decomp)
• 沸点：
  710.2±60.0 °C(Predicted)
• 密度：
  1.549±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,2-bis(indane-1',3'-dione-2'-yl)indane-1,3-dione 在 sodium hydroxide 作用下， 生成 6,11-二羟基-5,12-萘并萘二酮
  参考文献：
  名称：

  Liebermann; Landau, Chemische Berichte, 1901, vol. 34, p. 2150

  摘要：

  DOI：
• 作为产物：
  描述：

  2-溴-1,3-茚二酮 在 水 作用下， 生成 2,2-bis(indane-1',3'-dione-2'-yl)indane-1,3-dione
  参考文献：
  名称：

  Flatow, Chemische Berichte, 1901, vol. 34, p. 2147

  摘要：

  DOI：

文献信息

• Facile acid-catalyzed condensation of 2-hydroxy-2,2′-biindan-1,1′,3,3′-tetrone with phenols, methoxyaromatic systems and enols
  作者：Suven Das、Animesh Pramanik、Roland Fröhlich、Amarendra Patra

  DOI：10.1016/j.tet.2004.09.004

  日期：2004.11

  with 2-hydroxy-2,2′-biindan-1,1′,3,3′-tetrone 1 in an acid medium producing 2-aryl/alkyl-2,2′-biindan-1,1′,3,3′-tetrones in high yields. The adducts of resorcinol, 1,3,5-trihydroxybenzene and α- and β-naphthols of 1 preferably remain in the intramolecular hemi-ketal form, confirmed by X-ray diffraction studies. On the other hand para and meta substituted phenols condense with 1 in an acid medium to

  各种酚，甲氧基芳族化合物，3-和4-羟基香豆素和烯醇在产生2-芳基/的酸性介质中与2-羟基-2,2'-biindan-1,1'，3,3'-四烯1平稳缩合。烷基-2,2'-biindan-1,1'，3,3'-四烯的收率很高。间苯二酚，1,3,5-三羟基苯和的α-和β萘酚的加合物1优选保持在分子内半缩酮形式，其通过X射线衍射研究所证实。另一方面，对位和间位取代的苯酚在酸性介质中与1缩合，以高收率生产6或7个取代的2'，4-螺（1'，3'-茚满）-茚并[3,2- b ]色烯。 。
• Chakrabarty, Manas; Mukherji, Ajanta, Journal of the Indian Chemical Society, 2013, vol. 90, # 10, p. 1681 - 1694
  作者：Chakrabarty, Manas、Mukherji, Ajanta

  DOI：——

  日期：——
• Expeditious reaction of ninhydrin with active methylene compounds on montmorillonite K10 clay
  作者：Manas Chakrabarty、Ajanta Mukherji、Shiho Arima、Yoshihiro Harigaya、Guillaume Pilet

  DOI：10.1007/s00706-008-0066-6

  日期：2009.2

  Ninhydrin reacted expeditiously with thirteen active methylene compounds on montmorillonite K10 clay at room temperature to furnish, in 5 min, a Knoevenagel condensate in one case, aldols in six cases, aldol-derived cyclic hemiketals in three cases, and interesting products in the remaining three cases. Almost identical results were obtained, but faster, when the reactions were carried out in water on steam-bath. The structures of two novel products were also confirmed by single-crystal X-ray diffraction analysis.
• One-pot electrosynthesis of 2,3-bis(spiro-2-indanyl-1,3-dione)-indeno[1,2-b]furan-4-one
  作者：Roberto Horcajada、Belen Batanero、Fructuoso Barba、Avelino Martín

  DOI：10.1016/j.tetlet.2007.07.065

  日期：2007.9

  The 2,3-bis(spiro-2-indanyl-1,3-dione)-indeno[1,2-b]furan-4-one has been synthesized by cathodic reduction of 2,2-dibroi-no-1,3-indandione in dichloromethane-BU4NBF4. In contrast, tris-indanedione was the main product when acetonitrile was used as a solvent. Sunlight exposition of the dispiro compound afforded the tris-indandione in quantitative yield. (c) 2007 Elsevier Ltd. All rights reserved.
• Liebermann; Flatow, Chemische Berichte, 1900, vol. 33, p. 2434
  作者：Liebermann、Flatow

  DOI：——

  日期：——