9-bromo-10-(p-tolyl)anthracene | 23673-92-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9-bromo-10-(p-tolyl)anthracene
• 英文别名: 9-Bromo-10-p-tolyl-anthracene；9-bromo-10-(4-methylphenyl)anthracene
• CAS: 23673-92-9
• 化学式: C₂₁H₁₅Br
• 分子量: 347.254
• InChiKey: NKOXYHXAUSEGHT-UHFFFAOYSA-N

物化性质

• 熔点：
  196 °C
• 沸点：
  459.4±14.0 °C(Predicted)
• 密度：
  1.359±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-bromo-10-(p-tolyl)anthracene 在 正丁基锂 、 重水 作用下， 生成 9-(4-Methylphenyl)anthracene-10-d
  参考文献：
  名称：

  Aryl Proton Transfer Reactions of 9-Arylanthracene and 9-Substituted Anthracene Radical Cations with 2,6-Di-tert-butylpyridine

  摘要：

  Radical cations of anthracenes with substituents at the O-position (Br, CN, or NO2) or those of 9-arylanthracenes were observed to undergo proton transfer reactions with 2,6-di-tert-butylpyridine (TBP) to generate the corresponding anthracenyl radical. Under the same conditions 2,6-dimethylpyridine (LUT) undergoes combination reactions with the radical cations, and the proton transfer reactions could not be detected. The characteristic features of the reactions producing the anthracenyl radicals are as follows: (a) primary deuterium kinetic isotope effects are observed on substitution of the 10-H with 10-D, (b) the apparent Arrhenius activation energies vary from -2 to -11 kcal/mol, and (c) 10-Br-substituted anthracenes are formed during bromine atom abstraction from bromoform by the free radicals. The intermediate bromo derivatives are further oxidized under the reaction conditions. A two-step mechanism involving a reversible pi-complex formation followed by rate-determining proton transfer is proposed. The results of the reactions with TBP are compared to those obtained from the corresponding reactions of the radical cations with LUT.

  DOI：

  10.1021/jo00101a015
• 作为产物：
  描述：

  9-(4-methylphenyl)anthracene 在 copper(ll) bromide 作用下， 以 氯苯 为溶剂， 生成 9-bromo-10-(p-tolyl)anthracene
  参考文献：
  名称：

  卤化铜与有机化合物的反应-III：9-烷基和9-芳基蒽

  摘要：

  已显示9-烷基和9-芳基蒽通过卤化铜进行卤化以使其10-卤代衍生物具有良好的产率。显示9-芳基蒽中的给电子基团可增加反应速率。结果是根据配体转移机理来解释的。

  DOI：

  10.1016/s0040-4020(01)82883-0

文献信息

• Reactions of cupric halides with organic compounds—III
  作者：D. Mosnaim、D.C. Nonhebel、J.A. Russell

  DOI：10.1016/s0040-4020(01)82883-0

  日期：1969.1

  9-Alkyl and 9-arylanthracenes have been shown to undergo halogenation with cupric halides to give good yields of their 10-halogenated derivatives. Electron-donating groups in 9-arylanthracenes were shown to increase the rate of reaction. The results are interpreted in terms of a ligand-transfer mechanism.

  已显示9-烷基和9-芳基蒽通过卤化铜进行卤化以使其10-卤代衍生物具有良好的产率。显示9-芳基蒽中的给电子基团可增加反应速率。结果是根据配体转移机理来解释的。
• LUMINESCENT COMPOUNDS AND ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：Choi Il-Won

  公开号：US20110054229A1

  公开（公告）日：2011-03-03

  The present invention relates to organic electroluminescent compounds and organic electroluminescent devices employing the same. More specifically, the invention relates to organic electroluminescent compounds containing an anthracenyl group or an aryl group having an anthracenyl substituent m the aryl ring of fluorene or indenofluorene, as a blue electroluminescent material in an organic electroluminescent layer. The electroluminescent compounds according to the invention exhibit high luminous efficiency and excellent life property, so that an OLED device having very good operation lifetime can be prepared therefrom.

  本发明涉及有机电致发光化合物和采用这些化合物的有机电致发光器件。更具体地，该发明涉及含有蒽基或在芴或间芴芴环的芳基上具有蒽基取代基的有机电致发光化合物，作为有机电致发光层中的蓝色电致发光材料。根据本发明的电致发光化合物表现出高发光效率和优异的寿命特性，因此可以制备出具有非常良好操作寿命的OLED器件。
• METHOD FOR SYNTHESIS OF ANTHRACENE DERIVATIVE
  申请人：OSAKA Harue

  公开号：US20110172441A1

  公开（公告）日：2011-07-14

  A method for synthesizing an anthracene derivative represented by a general formula (G1) is provided, in which a 9-arylanthracene derivative having an active site at a 10-position is subjected to coupling with a carbazole-3-yl-aryl derivative having an active site in an aryl group with the use of a metal or a metal compound, wherein A represents a substituted or unsubstituted phenyl group, wherein D represents any of an alkyl group having 1 to 4 carbon atoms and a substituted or unsubstituted phenyl group, wherein α represents any of a substituted or unsubstituted phenylene group and a substituted or unsubstituted biphenyl-4,4′-diyl group, and wherein R 1 to R 9 independently represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group.

  提供一种合成由通用公式（G1）表示的蒽衍生物的方法，其中具有在第10位活性位点的9-芳基蒽衍生物与具有在芳基团中活性位点的咔唑-3-基-芳基衍生物经过金属或金属化合物的偶联反应，其中A代表取代或未取代的苯基团，D代表具有1至4个碳原子的烷基团或取代或未取代的苯基团中的任一种，α代表取代或未取代的苯撑基团或取代或未取代的联苯-4,4'-二基基团，R1至R9独立地代表氢、具有1至4个碳原子的烷基团或取代或未取代的苯基团中的任一种。
• 一种磷光铱配合物及其制备方法和应用
  申请人：南京邮电大学

  公开号：CN104086596B

  公开（公告）日：2017-01-25

  本发明涉及一种磷光铱配合物及其制备方法和应用，属于有机光电功能材料技术领域。具体涉及一类磷光铱配合物分子的制备方法及其在分子氧检测、细胞标记和成像中的应用。该类配合物材料由环金属配体、金属中心和苯甲基取代蒽的辅助配体组成，结构通式如下所示，该材料具有较长的发光寿命，反应条件温和，易提纯，在乏氧检测、细胞成像和病理诊断中有非常好的应用前景。
• COMPOSITION FOR FORMING ORGANIC FILM, DISPLAY DEVICE USING THE COMPOSITION, AND METHOD OF MANUFACTURING THE DISPLAY DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20190019958A1

  公开（公告）日：2019-01-17

  A composition for forming organic film, a display device utilizing the composition, and a method of manufacturing the display device are provided. The composition for forming an organic film includes a solvent; and a compound of Formula 1: Ar∛R) k .  Formula 1

  本发明提供了一种用于形成有机薄膜的组合物、利用该组合物的显示器件以及制造该显示器件的方法。用于形成有机薄膜的组合物包括溶剂和化学式1的化合物：Ar∛R)k。化学式1：