(diglyme)cerium(IV) tetra(hexafluoroisopropoxide) | 478796-39-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (diglyme)cerium(IV) tetra(hexafluoroisopropoxide)
• 英文别名: cerium(4+);1,1,1,3,3,3-hexafluoropropan-2-olate;1-methoxy-2-(2-methoxyethoxy)ethane
• CAS: 478796-39-3；216979-55-4
• 化学式: C₁₈H₁₈CeF₂₄O₇
• 分子量: 942.418
• InChiKey: OCDWGVHGQAMAOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (diglyme)cerium(IV) tetra(hexafluoroisopropoxide) 、 水 以 neat (no solvent) 为溶剂， 生成 cerium(IV) oxide
  参考文献：
  名称：

  Molecular structures of volatile Ce(IV) tetrafluoroisopropoxide complexes with TMEDA and diglyme. CVD experiments

  摘要：

  The structures of the cerium tetrafluoroisopropoxide adducts with TMEPA (1) and diglyme [Me(OC2H4)(2)OMe] (2) were established by single crystal X-ray diffraction (TMEDA=tetramethylethane-1,2-diamine). The cerium atom is hexa- and heptacoordinated for 1 and 2, respectively. The Ce-O(hfip) bond distances are quite short [2.115(5)-2.152(6) Angstrom] and are associated to large Ce-O(hfip) angles (>156degrees). Both complexes display a range of short F...C contacts, the shortest ones having values of 3.754 and 4.060 Angstrom for 1 and 2, respectively. Decomposition experiments were achieved in a cold-wall reactor. The films deposited on glass substrates were characterized by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and UV-Vis spectroscopy. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01005-7
• 作为产物：
  描述：

  二乙二醇二甲醚 、 cerium(IV) hexafluoroisopropoxide tetrahydofuran 以 not given 为溶剂， 生成 (diglyme)cerium(IV) tetra(hexafluoroisopropoxide)
  参考文献：
  名称：

  Molecular structures of volatile Ce(IV) tetrafluoroisopropoxide complexes with TMEDA and diglyme. CVD experiments

  摘要：

  The structures of the cerium tetrafluoroisopropoxide adducts with TMEPA (1) and diglyme [Me(OC2H4)(2)OMe] (2) were established by single crystal X-ray diffraction (TMEDA=tetramethylethane-1,2-diamine). The cerium atom is hexa- and heptacoordinated for 1 and 2, respectively. The Ce-O(hfip) bond distances are quite short [2.115(5)-2.152(6) Angstrom] and are associated to large Ce-O(hfip) angles (>156degrees). Both complexes display a range of short F...C contacts, the shortest ones having values of 3.754 and 4.060 Angstrom for 1 and 2, respectively. Decomposition experiments were achieved in a cold-wall reactor. The films deposited on glass substrates were characterized by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and UV-Vis spectroscopy. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01005-7

文献信息

• Hubert-Pfalzgraf, Liliane G.; Abada, Valerie; Vaissermann, Jacqueline, Journal of the Chemical Society, Dalton Transactions, 1998, # 20, p. 3437 - 3441
  作者：Hubert-Pfalzgraf, Liliane G.、Abada, Valerie、Vaissermann, Jacqueline

  DOI：——

  日期：——