D-maltose | 70832-27-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: D-maltose
• 英文别名: O⁴-α-D-Glucopyranosyl-D-mannose；alpha-D-glucosyl-(1->4)-aldehydo-D-mannose；(2S,3R,4R,5R)-2,3,5,6-tetrahydroxy-4-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexanal
• CAS: 70832-27-8
• 化学式: C₁₂H₂₂O₁₁
• 分子量: 342.3
• InChiKey: DKXNBNKWCZZMJT-BBFNFCGLSA-N

物化性质

• 沸点：
  774.5±60.0 °C(Predicted)
• 密度：
  1.68±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -5
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  197
• 氢给体数：
  8
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  吲哚 、 D-maltose 在 scandium tris(trifluoromethanesulfonate) 作用下， 以 乙醇 、 水 为溶剂， 反应 120.0h， 生成 (2R,3R,4R,5R)-6,6-Bis-(1H-indol-2-yl)-3-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-hexane-1,2,4,5-tetraol
  参考文献：
  名称：

  Direct C-glycosylation of indole with unprotected mono-, di-, and trisaccharides: a one-pot synthesis of 1-deoxy-1,1-bis(3-indolyl)alditols

  摘要：

  1-Deoxy-1, 1-bis(3-indolyl)alditols were synthesized by reacting 2.5 equiv of indole with 1 equiv of the following seven monosaccharides (D-galactose, D-mannose, D-allose, 2-deoxy-D-arabinohexose (2-deoxy-D-glucose), D-arabinose, L-arabinose, D-xylose), two disaccharides (D-lactose, D-maltose), and a trisaccharide (D-maltotriose) in 1:1 EtOH-H(2)O at room temperature, or at 40 or 50 degrees C, in the presence of 5 mol % scandium(III) trifluoromethanesulfonate [Sc(OTf)(3)], in a one-pot reaction, in 36-95% yields. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2006.08.018
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 过氧化氢苯甲酰 、 乙醚 、 水 作用下， 生成 D-maltose
  参考文献：
  名称：

  Haworth et al., Journal of the Chemical Society, 1934, p. 302

  摘要：

  DOI：

文献信息

• CELLOBIOSE 2-EPIMERASE, ITS PREPARATION AND USES
  申请人：Watanabe Hikaru

  公开号：US20120040407A1

  公开（公告）日：2012-02-16

  The present invention has objects to provide a thermostable cellobiose 2-epimerase, its preparation and uses. The present invention attains the above objects by providing a thermostable cellobiose 2-epimerase, a DNA encoding the enzyme, a recombinant DNA and transformant comprising the DNA, a process for producing the enzyme, and a process for producing isomerized saccharides using the enzyme.

  本发明的目的是提供一种热稳定的纤维二糖2-表异构酶，其制备和用途。本发明通过提供一种热稳定的纤维二糖2-表异构酶，编码该酶的DNA，含有该DNA的重组DNA和转化体，生产该酶的过程以及使用该酶生产异构化糖的过程来实现上述目的。
• CELLOBIOSE 2-EPIMERASE, PROCESS FOR PRODUCING SAME, AND USE OF SAME
  申请人：Hayashibara Co., Ltd.

  公开号：EP2395080B1

  公开（公告）日：2014-08-06
• US9175282B2
  申请人：——

  公开号：US9175282B2

  公开（公告）日：2015-11-03
• Direct C-glycosylation of indole with unprotected mono-, di-, and trisaccharides: a one-pot synthesis of 1-deoxy-1,1-bis(3-indolyl)alditols
  作者：Shingo Sato、Hiroya Masukawa、Toshihiro Sato

  DOI：10.1016/j.carres.2006.08.018

  日期：2006.11

  1-Deoxy-1, 1-bis(3-indolyl)alditols were synthesized by reacting 2.5 equiv of indole with 1 equiv of the following seven monosaccharides (D-galactose, D-mannose, D-allose, 2-deoxy-D-arabinohexose (2-deoxy-D-glucose), D-arabinose, L-arabinose, D-xylose), two disaccharides (D-lactose, D-maltose), and a trisaccharide (D-maltotriose) in 1:1 EtOH-H(2)O at room temperature, or at 40 or 50 degrees C, in the presence of 5 mol % scandium(III) trifluoromethanesulfonate [Sc(OTf)(3)], in a one-pot reaction, in 36-95% yields. (c) 2006 Elsevier Ltd. All rights reserved.
• Haworth et al., Journal of the Chemical Society, 1934, p. 302
  作者：Haworth et al.

  DOI：——

  日期：——