5-(2-hydroxyethoxy)pentan-2-one

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(2-hydroxyethoxy)pentan-2-one
• 化学式: C₇H₁₄O₃
• 分子量: 146.186
• InChiKey: GYNVDXAXUOFHLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-(2-hydroxyethoxy)pentan-2-one 在 甲基膦酸 、 potassium hydroxide 、 lithium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 10.0h， 生成
  参考文献：
  名称：

  硫电极导电固态电解质的噻吩二烷氧基含氟磺酸盐化合物

  摘要：

  一种锂硫电池硫电极导电固态电解质的噻吩‑3,4‑二（乙氧基烷基醚‑2‑羟基‑2‑二氟甲基磺酸盐）化合物及其合成方法，从3,4‑四甲氧基四氢噻吩为起始原料，经过三步化学反应合成；分子中集合了高电子电导率的富电子噻吩环和高Li+离子电导率的二氟甲基磺酸盐基团，从而能大幅改进锂硫电池硫电极固态电解质性能。

  公开号：

  CN114380789A
• 作为产物：
  描述：

  环丙甲基酮 、 乙二醇 在 palladium dichloride 作用下， 以 水 为溶剂， 反应 8.0h， 以39%的产率得到5-(2-hydroxyethoxy)pentan-2-one
  参考文献：
  名称：

  摘要：

  The possibility of the cleavage of the C-C bond in acetylcyclopropane (ACP) under the action of water or alcohols in the presence of copper or palladium salts was demonstrated for the first time. At 175-180 degreesC, the reactions proceeded regioselectively with the cleavage of the C(1)-C(2) bond in the cyclopropane ring. The reaction of ACP with water afforded 5-hydroxypentan-2-one, bis(3-acetylpropyl) ether, and furan compounds, whereas the reactions with alcohols proceeded selectively to form 5-alkoxypentan-2-ones. The yields of the latter depend on the nature and structure of the alcohol, the maximum values (98%) being achieved in the case of primary alcohols.

  DOI：

  10.1023/a:1014010907818

文献信息

• 高延伸率的芳叔烷基醚双烯二氟甲基磺酸锂离子膜化合物
  申请人：上海漫关越水处理有限公司

  公开号：CN114436908A

  公开（公告）日：2022-05-06

  本发明是一种芳叔烷基醚双烯二氟甲基磺酸锂的离子膜化合物及其合成方法，需要经过醚化反应、二氟甲基反应、膜电解氧化反应和脱水双烯的四步合成反应。在芳叔烷基乙氧基醚双烯二氟甲基磺酸锂分子中，包含能致密交联的双烯键，多醚键柔软烷基链和超强酸性的二氟甲基磺酸锂基团，聚合后的离子膜固态电解质具有高Li+电导率、紧贴金属锂片表面变形的低接触电阻、选择性只渗透通过Li+和阻挡穿梭效应等出色性能。
• Composition of Decolorable Ink and Decoloring Method
  申请人：Han Jong-Soo

  公开号：US20100255215A1

  公开（公告）日：2010-10-07

  The present invention is a method which erase information printed on a recording medium if necessary and thus reuse the recording medium, and includes 1) decolorable ink compositions which are not erased during the use but erased by a dye readily decolorable by a decolorant, 2) a decolorant composition including a thermal initiator or photoinitiator, and 3) a method for coating the decolorant and applying heat or irradiating UV to erase the dye. According to the present invention, it is possible to prepare various writing inks, and particularly, when applied to recording medium with a magnetic stripe as well as the general purpose papers, it is possible to reduce the production cost significantly, obtain a large import substitution effect of the magnetic ink all of which are imported, and largely reduce the environmental pollution.
• US8378006B2
  申请人：——

  公开号：US8378006B2

  公开（公告）日：2013-02-19
• [EN] THE COMPOSITION OF DECOLORABLE INK AND DECOLORING METHOD<br/>[FR] COMPOSITION D'ENCRE DÉCOLORABLE ET PROCÉDÉ DE DÉCOLORATION
  申请人：HAN JONG-SOO

  公开号：WO2009054621A2

  公开（公告）日：2009-04-30

  The present invention is a method which erase information printed on a recording medium if necessary and thus reuse the recording medium, and includes 1) decolorable ink compositions which are not erased during the use but erased by a dye readily decolorable by a decolorant, 2) a decolorant composition including a thermal initiator or photoinitiator, and 3) a method for coating the decolorant and applying heat or irradiating UV to erase the dye. According to the present invention, it is possible to prepare various writing inks, and particularly, when applied to recording medium with a magnetic stripe as well as the general purpose papers, it is possible to reduce the production cost significantly, obtain a large import substitution effect of the magnetic ink all of which are imported, and largely reduce the environmental pollution.
• ——
  作者：U. M. Dzhemilev、R. I. Khusnutdinov、A. M. Atnabaeva、Z. S. Muslimov、R. I. Parfenova、Yu. V. Tomilov

  DOI：10.1023/a:1014010907818

  日期：——

  The possibility of the cleavage of the C-C bond in acetylcyclopropane (ACP) under the action of water or alcohols in the presence of copper or palladium salts was demonstrated for the first time. At 175-180 degreesC, the reactions proceeded regioselectively with the cleavage of the C(1)-C(2) bond in the cyclopropane ring. The reaction of ACP with water afforded 5-hydroxypentan-2-one, bis(3-acetylpropyl) ether, and furan compounds, whereas the reactions with alcohols proceeded selectively to form 5-alkoxypentan-2-ones. The yields of the latter depend on the nature and structure of the alcohol, the maximum values (98%) being achieved in the case of primary alcohols.