10-bromo-9-anthracenemethylamine | 357213-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 10-bromo-9-anthracenemethylamine
• 英文别名: 10-Bromo-9-anthracenemethanamine；(10-bromoanthracen-9-yl)methanamine
• CAS: 357213-92-4
• 化学式: C₁₅H₁₂BrN
• 分子量: 286.171
• InChiKey: IIBLCZRKOFLPIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  10-bromo-9-anthracenemethylamine 在 碘化1,2-二甲基吡啶鎓 、 三氟乙酸 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 9-bromo-10-(guanidinomethyl)anthracene
  参考文献：
  名称：

  9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

  摘要：

  9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2-1.4 x 10(5) M-1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77-92% yield. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00738-9
• 作为产物：
  描述：

  9-溴蒽 在 tris(dibenzylideneacetone)dipalladium (0) 、 三苯胂 、 硫酸 、 溶剂黄146 作用下， 反应 240.0h， 生成 10-bromo-9-anthracenemethylamine
  参考文献：
  名称：

  9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

  摘要：

  9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2-1.4 x 10(5) M-1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77-92% yield. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00738-9

文献信息

• Suitanes
  作者：Avril R. Williams、Brian H. Northrop、Theresa Chang、J. Fraser Stoddart、Andrew J. P. White、David J. Williams

  DOI：10.1002/anie.200602173

  日期：2006.10.13
• [EN] SOLVENT-FREE PHOTON UPCONVERSION SYSTEM<br/>[FR] SYSTÈME DE CONVERSION ASCENDANTE DE PHOTONS SANS SOLVANTS
  申请人：UNIV KYUSHU NAT UNIV CORP

  公开号：WO2015068858A1

  公开（公告）日：2015-05-14

  The present invention provides a solvent-free photon upconversion composition comprising an acceptor chromophore and organic donor, wherein the acceptor chromophore is liquidized and doped with the organic donor. The present invention also provides a method for achieving photon upconversion in air using said composition.