1-ethoxy-4-vinyloxy-butane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-ethoxy-4-vinyloxy-butane
• 英文别名: 1-Aethoxy-4-vinyloxy-butan；1-Ethenoxy-4-ethoxybutane
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: BNWLJBLIQDSPHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-乙氧基-1-丁醇 、 乙炔 在 氢氧化钾 作用下， 120.0 ℃ 、2.45 MPa 条件下， 生成 1-ethoxy-4-vinyloxy-butane
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• Method for producing n-alkenyl amides
  申请人：——

  公开号：US20030028035A1

  公开（公告）日：2003-02-06

  A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst compounds of the general formulae (Ia) and/or (Ib) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n —H  (Ia): R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n —R 2 ,  (Ib): where n is 1, 2 or 3 and R 1 and R 2 are independently C 1 - to C 6 -alkyl or C 2 - to C 6 -alkenyl, or together a butenyl unit.

  制备N-烯基酰胺的过程包括通过在液相中让相应的NH-酰胺与炔烃反应，在碱性金属化合物和共催化剂的存在下，作为共催化剂使用的是具有以下通式(Ia)和/或(Ib)的化合物：R1O—(CH2CH2CH2CH2O)n—H  (Ia):R1O—(CH2CH2CH2CH2O)n—R2,  (Ib):其中n为1、2或3，R1和R2独立地为C1至C6烷基或C2至C6烯基，或者共同构成一个丁烯基团。
• Method for producing alkenyl ethers
  申请人：——

  公开号：US20030114715A1

  公开（公告）日：2003-06-19

  Alkenyl ethers are prepared by reacting the corresponding alcohols or phenols with acetylenes in the liquid phase in the presence of basic alkali metal compounds and a cocatalyst comprising compounds of the formula (Ia) and/or (Ib) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n— H  (Ia) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n— H 2 ,  (Ia) where R 1 , R 2 are, independently of one another, C 1 -C 6 -alkyl or C 2 -C 6 -alkenyl, or R 1 and R 2 together form a butyl unit and n is 1, 2, 3, 4 or 5.

  烯丙醚通过在液相中存在碱性金属化合物和协同催化剂的情况下，将相应的醇或酚与乙炔反应制备而成，其中所述协同催化剂包括化合物(Ia)和/或(Ib)的公式，(Ia)R1O—(CH2CH2CH2CH2O)n—H  (Ia)R1O—(CH2CH2CH2CH2O)n—H2,  (Ia)其中，R1，R2是独立的C1-C6烷基或C2-C6烯基，或R1和R2共同形成丁基单元，n为1、2、3、4或5。
• RESIN COMPOSITION
  申请人：Kyowa Hakko Chemical Co., Ltd.

  公开号：EP1679349A1

  公开（公告）日：2006-07-12

  The present invention provides a resin composition comprising a thermoplastic resin and a polymer having, in the molecule, a structural unit represented by Formula (I): (wherein n represents an integer of 2 to 1000; R1 represents a substituted or unsubstituted lower alkyl, a substituted or unsubstituted cycloalkyl, a substituted or unsubstituted aryl, or a substituted or unsubstituted aralkyl; and R2, R3, R4, and R5 are the same or different from one another and each represent a hydrogen atom, a substituted or unsubstituted lower alkyl, a substituted or unsubstituted cycloalkyl, a substituted or unsubstituted aryl, or a substituted or unsubstituted aralkyl, and when each of R1s, R2s, R3s, and R4s, represent two or more in number, they may be the same or different from each other, respectively) or the like.

  本发明提供了一种树脂组合物，该树脂组合物由热塑性树脂和聚合物组成，聚合物分子中具有由式 (I) 表示的结构单元： (其中 n 代表 2 至 1000 的整数；R1 代表取代或未取代的低级烷基、取代或未取代的环烷基、取代或未取代的芳基或取代或未取代的芳烷基；R2、R3、R4 和 R5 彼此相同或不同，且各自代表氢原子、取代或未取代的低级烷基、取代或未取代的环烷基、取代或未取代的芳基或取代或未取代的芳烷基，当 R1s、R2s、R3s 和 R4s 的数目分别代表两个或两个以上时，它们可以彼此相同或不同）或类似物。
• PROCESS FOR PRODUCTION OF POLYRADICAL COMPOUND AND BATTERY CELL
  申请人：NEC Corporation

  公开号：EP2025689A1

  公开（公告）日：2009-02-18

  Disclosed is a polyradical compound which can be used as an electrode active material for at least one of a positive electrode and a negative electrode. The polyradical compound has a repeating unit represented by general formula (1) and is crosslinked using a bifunctional crosslinking agent having two polymerizing groups in the molecule represented by general formula (2), wherein R1 to R3 each independently represent hydrogen or methyl group; R4 to R7 each independently represent C1 to C3 alkyl group; X represents single bond, linear, branched or cyclic C1 to C15 alkylenedioxy group, alkylene group, phenylenedioxy group, phenylene group or structure represented by general formula (3); and R8 to R13 each independently represent hydrogen or methyl group, and k represents an integer of 2 to 5.

  本发明公开了一种可用作正极和负极中至少一个电极活性材料的多辐射化合物。该多辐射化合物具有通式（1）表示的重复单元，并使用通式（2）表示的分子中具有两个聚合基团的双官能团交联剂进行交联，其中 R1 至 R3 各自独立地代表氢或甲基；R4 至 R7 各自独立地代表 C1 至 C3 烷基；X 代表单键、线性、支链或环状 C1 至 C15 亚烷基二氧基、亚烷基、亚苯基、亚苯基或通式 (3) 所代表的结构；以及 R8 至 R13 各自独立地代表氢或甲基，且 k 代表 2 至 5 的整数。
• METAL-FILM-COATED MATERIAL AND PROCESS FOR PRODUCING THE SAME, METALLIC-PATTERN-BEARING MATERIAL AND PROCESS FOR PRODUCING THE SAME, COMPOSITION FOR POLYMER LAYER FORMATION, NITRILE POLYMER AND METHOD OF SYNTHESIZING THE SAME, COMPOSITION CONTAINING NITRILE POLYMER, AND LAYERED PRODUCT
  申请人：FUJIFILM Corporation

  公开号：EP2078607A1

  公开（公告）日：2009-07-15

  A process for producing a metal film-coated material, the process including: (a1) forming, on a substrate, a polymer layer formed from a polymer which has a functional group capable of interacting with a plating catalyst or a precursor thereof, and is directly chemically bonded to the substrate;(a2) providing a plating catalyst or a precursor thereof to the polymer layer; and (a3) performing plating with respect to the plating catalyst or a precursor thereof. The polymer layer satisfies all of the following requirements (1) to (4): (1) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25°C and relative humidity of 50 % is 0.01 to 10% by mass; (2) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25°C and relative humidity of 95 % is 0.05 to 20% by mass; (3) the water absorption coefficient of the polymer layer as measured after 1 hour of immersion in boiling water at 100°C is 0.1 to 30% by mass; and (4) the surface contact angle of the polymer layer as measured after dropping 5 µL of distilled water thereonto and leaving to stand for 15 seconds in an environment of temperature of 25°C and relative humidity of 50 % is 50 to 150 degrees.

  一种生产金属薄膜涂层材料的工艺，该工艺包括：(a1) 在基底上形成聚合物层，该聚合物层由具有能与电镀催化剂或其前体相互作用的官能团的聚合物形成，并直接与基底化学键合；(a2) 向聚合物层提供电镀催化剂或其前体；(a3) 对电镀催化剂或其前体进行电镀。聚合物层满足以下所有要求（1）至（4）：(1) 在温度为 25°C、相对湿度为 50%的环境下测得的聚合物层的饱和吸水系数为 0.01 至 10%（按质量计）； (2) 在温度为 25°C、相对湿度为 95%的环境下测得的聚合物层的饱和吸水系数为 0.(3) 在 100°C 沸水中浸泡 1 小时后测得的聚合物层吸水系数为 0.1 至 30%（按质量计）；以及 (4) 在温度为 25°C 和相对湿度为 50%的环境中，滴入 5 微升蒸馏水并静置 15 秒后测得的聚合物层表面接触角为 50 至 150 度。