1-(溴甲氧基)丁烷 | 59375-51-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(溴甲氧基)丁烷
• 英文名称: 1-bromomethoxy-butane
• 英文别名: bromomethyl-butyl ether；Brommethyl-butyl-aether；1-(Bromomethoxy)butane
• CAS: 59375-51-8
• 化学式: C₅H₁₁BrO
• 分子量: 167.046
• InChiKey: RTSBCGFVAMIDBC-UHFFFAOYSA-N

物化性质

• 沸点：
  159 °C(Press: 749.5 Torr)
• 密度：
  1.278±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  7
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(溴甲氧基)丁烷 以 乙醚 为溶剂， 生成 苄基正丁基醚
  参考文献：
  名称：

  Wittig,G.; Krauss,D., Justus Liebigs Annalen der Chemie, 1964, vol. 679, p. 34 - 41

  摘要：

  DOI：

文献信息

• Mass spectrometry in structural and stereochemical problems. CCXII. Electron impact induced triple hydrogen rearrangements and other fragmentations of alkyl vinyl ethers and thioethers
  作者：Mananobu Katoh、David A. Jaeger、Carl Djerassi

  DOI：10.1021/ja00764a037

  日期：1972.5
• 2-Alkyloxyalkylthiohypoxanthines as new potent inhibitors of xanthine oxidase
  作者：Giuliana Biagi、Irene Giorgi、Federica Pacchini、Oreste Livi、Valerio Scartoni

  DOI：10.1016/s0014-827x(01)01160-0

  日期：2001.11

  The title compounds were prepared and tested as xanthine oxidase (XO) inhibitors. Results evidenced that potency was related to the position of the oxygen atom in the 2-linear chain and that it grew with distance from the sulfur atom until it became equipotent to 2-n-hexylthiohypoxanthine. Enzymatic oxidation on C(2) occurred in the 8-alkylthiohypoxanthines. On the contrary, oxidation on C(8) did not occur in the 2-alkythioderivatives, demonstrating that the chain forced these molecules to form a complex with molybdenum(VI) involving only the N(3) and N(9) nitrogen atoms. (C) 2001 Elsevier Science S.A. All rights reserved.
• Mamedow, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1499,1503,1504;engl.Ausg.S.1574,1578,1579
  作者：Mamedow

  DOI：——

  日期：——
• BAGDASARYAN, G. B.;SARKISOVA, E. A.;INDZHIKYAN, M. G., ARM. XIM. ZH., 43,(1990) N, S. 473-475
  作者：BAGDASARYAN, G. B.、SARKISOVA, E. A.、INDZHIKYAN, M. G.

  DOI：——

  日期：——