4,4'-bis(undec-10-en-1-yloxy)-1,1-biphenyl | 918875-95-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(undec-10-en-1-yloxy)-1,1-biphenyl
• 英文别名: 4,4'-Bis[(undec-10-en-1-yl)oxy]-1,1'-biphenyl；1-undec-10-enoxy-4-(4-undec-10-enoxyphenyl)benzene
• CAS: 918875-95-3
• 化学式: C₃₄H₅₀O₂
• 分子量: 490.77
• InChiKey: UNEMTEHICOKGQF-UHFFFAOYSA-N

物化性质

• 沸点：
  585.6±43.0 °C(Predicted)
• 密度：
  0.938±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  36
• 可旋转键数：
  23
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  10-十一烯-1-醇 在 四溴化碳 、 三苯基膦 、 sodium hydroxide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 14.0h， 生成 4,4'-bis(undec-10-en-1-yloxy)-1,1-biphenyl
  参考文献：
  名称：

  Synthesis and characterization of precisely-defined ethylene-co-aryl ether polymers via ADMET polymerization

  摘要：

  A new family of polyolefins containing various aryl ether units have been designed and synthesized, and their thermal properties were studied. We prepared six acyclic diene monomers di(undec-10-enyloxy) aryl ether by a two-step approach and the corresponding homopolymers and copolymers with 1,9-decadiene by ADMET. Subsequent hydrogenation gave the corresponding ethylene-co-aryl ether polymers. The structures of these polymers were confirmed by H-1 NMR, C-13 NMR and FT-IR. Additionally, crystallization behaviors and thermal properties were investigated by differential scanning calorimetry (DSC), X-ray diffraction and thermal gravimetric analysis (TGA). The results show that incorporation of these aryl ether units has improved the thermal stability of polymers. And these polymers show a tendency of semicrystallinity to amorphous state with the insertion of more rigid phenyl rings in functional sites of polymers' main chain. Interestingly, DSC analysis reveals that a sequence of melting/crystallization phenomenon occurs in the crystalline saturated homopolymers. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.03.039

文献信息

• Side-chain polysiloxane liquid crystalline elastomers from non-mesogenic components
  作者：K. Mohana、S. Umadevi

  DOI：10.1039/c9nj03482j

  日期：——

  a combination of differential scanning calorimetry, polarising optical microscopy and X-ray diffraction experiments. The X-ray diffraction studies revealed an intercalated lamellar structure for the mesophase. Interestingly, the elastomer containing biphenyl-based cross-linker showed mesophase with an extended thermal range compared to the mesophase displayed by its counterpart containing phenyl-based

  描述了两种新的含非介晶单体和不同交联剂的偶氮基聚硅氧烷弹性体的合成和表征。通过标准分析技术确认了合成化合物的化学结构。值得注意的是，尽管单体和交联剂是非介晶的，但两种弹性体均显示出中间相。中间相的特征在于差示扫描量热法，偏振光学显微镜法和X射线衍射实验的结合。X射线衍射研究揭示了中间相的层状结构。有趣的是，与基于联苯的交联剂的弹性体相比，含有联苯的交联剂的弹性体显示出具有更大的热范围的中间相。已经研究了弹性体在溶液中的光致异构化行为及其在固态下的光开关性能。弹性体的单畴样品在分别暴露于紫外线和可见光时表现出可逆的，不对称的弯曲和不弯曲的行为，具有更快的响应时间。
• Liquid crystal composition, liquid crystal element, and cross-linked siloxane polymer
  申请人：Takaku Koji

  公开号：US20070007492A1

  公开（公告）日：2007-01-11

  The present invention provides a liquid crystal composition obtained by dissolving a dichroic dye in a mixture of a cross-linked polymer having a liquid crystalline group in the side chains and a low molecular weight liquid crystal, and preferably the cross-linked polymer is a cross-linked siloxane polymer having a liquid crystalline group in the side chains, and the dielectric constant anisotropy of the liquid crystal composition is changed from positive to negative by increasing the frequency of the voltage to be applied. The present invention further provides a liquid crystal element containing the liquid crystal composition and a cross-linked siloxane polymer preferably usable for the liquid crystal composition.
• US7427364B2
  申请人：——

  公开号：US7427364B2

  公开（公告）日：2008-09-23
• Synthesis and characterization of precisely-defined ethylene-co-aryl ether polymers via ADMET polymerization
  作者：Shaofei Song、Weijun Miao、Zongbao Wang、Dirong Gong、Zhong-Ren Chen

  DOI：10.1016/j.polymer.2015.03.039

  日期：2015.5

  A new family of polyolefins containing various aryl ether units have been designed and synthesized, and their thermal properties were studied. We prepared six acyclic diene monomers di(undec-10-enyloxy) aryl ether by a two-step approach and the corresponding homopolymers and copolymers with 1,9-decadiene by ADMET. Subsequent hydrogenation gave the corresponding ethylene-co-aryl ether polymers. The structures of these polymers were confirmed by H-1 NMR, C-13 NMR and FT-IR. Additionally, crystallization behaviors and thermal properties were investigated by differential scanning calorimetry (DSC), X-ray diffraction and thermal gravimetric analysis (TGA). The results show that incorporation of these aryl ether units has improved the thermal stability of polymers. And these polymers show a tendency of semicrystallinity to amorphous state with the insertion of more rigid phenyl rings in functional sites of polymers' main chain. Interestingly, DSC analysis reveals that a sequence of melting/crystallization phenomenon occurs in the crystalline saturated homopolymers. (C) 2015 Elsevier Ltd. All rights reserved.