1-Hydroxy-1,3,5-trimethyl-cyclohexan | 90760-75-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Hydroxy-1,3,5-trimethyl-cyclohexan
• 英文别名: 1,t-3,t-5-Trimethyl-r-1-cyclohexanol；1,c-3,c-5-Trimethyl-r-1-cyclohexanol；Opt.-inakt. 1-Hydroxy-1.3.5-trimethyl-cyclohexan；1,3,5-Trimethyl-cyclohexanol；1,3,5-Trimethylcyclohexan-1-ol
• CAS: 90760-75-1
• 化学式: C₉H₁₈O
• 分子量: 142.241
• InChiKey: KVZFVAMCMZOOOW-UHFFFAOYSA-N

物化性质

• 沸点：
  181 °C
• 密度：
  0.8876 g/cm3(Temp: 16.800009765625 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Hydroxy-1,3,5-trimethyl-cyclohexan 在 乙醚 、 sodium 、 三氯化磷 作用下， 生成 1,3,5-三甲基环己烷
  参考文献：
  名称：

  v. Auwers, Justus Liebigs Annalen der Chemie, 1920, vol. 420, p. 109

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基碘化镁 、 3,5-二甲基环己酮 生成 1-Hydroxy-1,3,5-trimethyl-cyclohexan
  参考文献：
  名称：

  Wallach, Justus Liebigs Annalen der Chemie, 1913, vol. 396, p. 278

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING CARBOXYLIC ACID
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1544190A1

  公开（公告）日：2005-06-22

  The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.

  本发明提供了一种安全、方便、高效的生产羧酸的方法，该方法通过脂环醇与过氧化氢水溶液反应，从而在温和的反应条件下，从脂环醇或脂环酮中高产率地获得羧酸，反应操作简单易行，反应完成后无需去除溶剂的步骤，对环境和人体的影响和毒性明显较小。为了实现这一目标，需要在一个异相溶液体系中，在含有元素周期表第 6 族金属化合物的催化剂存在下，使油性脂环醇与过氧化氢水溶液发生反应。
• (ALKYLPHENYL)ALKYLCYCLOHEXANE AND METHOD FOR PRODUCING (ALKYLPHENYL)ALKYLCYCLOHEXANE OR ALKYLBIPHENYL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1908743A1

  公开（公告）日：2008-04-09

  The invention provides a method for producing an (alkylphenyl)alkylcyclohexane, including a step of condensing an alkylbenzene with an alkylcyclohexene or an alkylcyclohexanol in the presence of an acid catalyst, and (alkylphenyl)alkylcyclohexane represented by formula (8). The (alkylphenyl)alkylcyclohexane produced through the production method can be transformed into an alkylbiphenyl, a biphenylpolycarboxylic acid, or a biphenylpolycarboxylic anhydride. Through the production method, an (alkylphenyl)alkylcyclohexane and an alkylbiphenyl of interest can be readily and selectively produced. (wherein R1 represents a C1-C4 alkyl group; R2 represents a C1-C4 alkyl group; m is an integer of 0 to 2; n' is an integer of 2 to 5; other conditions are the same as defined in claim 18.)

  本发明提供了一种生产(烷基苯基)烷基环己烷的方法，包括在酸催化剂存在下将烷基苯与烷基环己烯或烷基环己醇缩合的步骤，以及式(8)代表的(烷基苯基)烷基环己烷。通过该生产方法生产的（烷基苯）烷基环己烷可转化为烷基联苯、联苯聚羧酸或联苯聚羧酸酐。通过该生产方法，可以很容易地、有选择地生产出一种（烷基苯）烷基环己烷和一种烷基联苯。 (其中 R1 代表 C1-C4 烷基；R2 代表 C1-C4 烷基；m 为 0 至 2 的整数；n'为 2 至 5 的整数；其他条件与权利要求 18 中定义的相同)。
• FLUORINE COATING COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2075294A1

  公开（公告）日：2009-07-01

  Disclosed is a two-pack fluorine coating composition which comprises a combination of: a base component comprising a fluorinated copolymer having a hydroxyl group which can be dissolved in a low-polar weak solvent even at a low temperature and; a curing agent comprising a polyisocyanate compound. Specifically disclosed is a fluorine coating composition comprising:; (A) a base component which comprises a fluorinated copolymer of a fluoroolefin and a monomer having a double bond copolymerizable with the fluoroolefin and which has a fluorine content of 10 mass% or more, wherein 5 to 30 mol% of the monomer has a hydroxyl group and 10 to 50 mol% of the monomer has a branched alkyl group having 3 or more carbon atoms; and (B) a curing agent comprising a polyisocyanate compound which is produced by the reaction between at least one diisocyanate selected from an aliphatic diisocyanate and a alicyclic diisocyanate and a monoalcohol having 1 to 20 carbon atoms and which has an [(allophanate group)/(isocyanurate group)] ratio of 90/10 to 81/19 by mole.

  本发明公开了一种双组分氟涂料组合物，该组合物由以下成分组合而成：基础成分，包括具有羟基的氟化共聚物，该共聚物在低温下也能溶解在低极性弱溶剂中；固化剂，包括多异氰酸酯化合物。具体公开了一种含氟涂料组合物，包括(A) 基础组分，包括氟烯烃和具有可与氟烯烃共聚的双键的单体的氟化共聚物，其氟含量为 10 质量％或以上，其中 5 至 30 摩尔％的单体具有羟基，10 至 50 摩尔％的单体具有 3 个或更多碳原子的支链烷基；(B) 包含多异氰酸酯化合物的固化剂，该化合物由至少一种选自脂肪族二异氰酸酯和脂环族二异氰酸酯的二异氰酸酯与具有 1 至 20 个碳原子的一元醇反应生成，其[（异丙酸酯基）/（异氰尿酸酯基）]比率为 90/10 至 81/19（以摩尔计）。
• POLYURETHANE RESIN COMPOSITION FOR ELECTRICAL INSULATION
  申请人：Sanyu Rec Co., Ltd.

  公开号：EP2767983A1

  公开（公告）日：2014-08-20

  The invention provides a polyurethane resin composition for electrical insulation that has excellent compatibility between an isocyanate component and a polyol component, and that exhibits excellent heat resistance, moisture resistance, and insulation properties. The polyurethane resin composition for electrical insulation comprises (1) Part A comprising a polyisocyanate component obtained from at least one member selected from the group consisting of aliphatic diisocyanates and alicyclic diisocyanates, and containing one or more isocyanurate groups and one or more allophanate groups; and (2) Part B comprising a polyol component, wherein the polyisocyanate component has a molar ratio, (a)/(b), of isocyanurate groups (a) to allophanate groups (b) of 85/15 to 15/85.

  本发明提供了一种用于电气绝缘的聚氨酯树脂组合物，该组合物的异氰酸酯组分和多元醇组分之间具有极佳的相容性，并且具有优异的耐热性、防潮性和绝缘性。 用于电气绝缘的聚氨酯树脂组合物包括：(1) A 部分，包含多异氰酸酯组分，该组分至少取自脂肪族二异氰酸酯和脂环族二异氰酸酯中的一种，并含有一个或多个异氰脲酸酯基团和一个或多个异烷酸酯基团；以及 (2) B 部分，包含多异氰酸酯组分，该组分至少取自脂肪族二异氰酸酯和脂环族二异氰酸酯中的一种，并含有一个或多个异氰脲酸酯基团和一个或多个异烷酸酯基团；(2) B 部分包括多元醇组分，其中多异氰酸酯组分的异氰脲酸酯基团(a)与异 氨酸基团(b)的摩尔比(a)/(b)为 85/15 至 15/85。
• Polyisocyanate composition and method of manufacturing the same, blocked polyisocyanate composition and method of manufacturing the same, resin composition, curable resin composition and hardened material
  申请人：ASAHI KASEI CHEMICALS CORPORATION

  公开号：US10301416B2

  公开（公告）日：2019-05-28

  A polyisocyanate composition having a polyisocyanate, which is a reaction product of: a polyisocyanate precursor formed of a dimer or a multimer of at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate; and a polycarbonate diol, which is obtained by copolymerizing at least one diol selected from the group consisting of a diol having 2 to 20 carbon atoms and a carbonate compound, in which the polyisocyanate precursor has an isocyanurate group and an allophanate group, and the isocyanurate group and the allophanate group are present in a molar ratio (the isocyanurate group/the allophanate group) of 80:20 or more and 99:1 or less.

  一种多异氰酸酯组合物，其中的多异氰酸酯是下列物质的反应产物： 由至少一种二异氰酸酯的二聚体或多聚体形成的多异氰酸酯前体，该二异氰酸酯 前体选自由脂肪族二异氰酸酯和脂环族二异氰酸酯组成的组；以及 聚碳酸酯二元醇，由至少一种选自具有 2 至 20 个碳原子的二元醇和碳 酸化合物组的二元醇共聚而得，其中 聚异氰酸酯前体具有一个异氰脲酸酯基团和一个异han酸酯基团，以及 异氰尿酸酯基团和异烷酸酯基团的摩尔比（异氰尿酸酯基团/异烷酸酯基团）为 80:20 或以上，99:1 或以下。