乙烯基3-氯丙酸酯 | 5309-67-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 乙烯基3-氯丙酸酯
• 英文名称: vinyl β-chloropropionate
• 英文别名: β-Chlor-propionsaeure-vinylester；β-Chlorpropionsaeurevinylester；Ethenyl 3-chloropropanoate
• CAS: 5309-67-1
• 化学式: C₅H₇ClO₂
• mdl: MFCD19232662
• 分子量: 134.562
• InChiKey: YVELKSUQPQWUEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  乙烯基3-氯丙酸酯 在 sodium methylate 作用下， 以 甲醇 为溶剂， 以98%的产率得到丙烯酸乙烯酯
  参考文献：
  名称：

  Komarova, L. I.; Zhuravleva, E. I., Journal of Organic Chemistry USSR (English Translation), 1983, p. 455 - 457

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烯酸乙烯酯 在 盐酸 作用下， 以 乙醚 为溶剂， 反应 2.5h， 以83%的产率得到乙烯基3-氯丙酸酯
  参考文献：
  名称：

  Komarova, L. I.; Zhuravleva, E. I., Journal of Organic Chemistry USSR (English Translation), 1983, p. 455 - 457

  摘要：

  DOI：

文献信息

• PROCESSING AID COMPOSITION DERIVED FROM A SULFINATE-CONTAINING MOLECULE
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20140378594A1

  公开（公告）日：2014-12-25

  Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX 1 X 3 ═CX 2 —(R) p —CZ 1 Z 2 —SO 2 M Formula (I) (b) Formula (II); and (c) combinations thereof, wherein X 1 , X 2 , and X 3 are each independently selected from H, F, Cl, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R is a linking group; Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group; R 1 and R 2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.

  本文描述了一种可熔处理的聚合物组合物，包括：一种非氟可熔处理聚合物；以及由单体和含有磺酸盐分子聚合而成的氟聚合物，其中所述的磺酸盐分子选自以下组：（a）CX1X3═CX2—（R）p—CZ1Z2—SO2M式（I）；（b）式（II）；和（c）其组合物，其中X1、X2和X3各自独立选择自H、F、Cl、C1到C4烷基和C1到C4氟烷基；R是连结基；Z1和Z2各自独立选择自F、CF3和全氟烷基；R1和R2是末端基；p为0或1；m至少为2；M是阳离子。
• FLUORINE-CONTAINING POLYMER COMPOSITION
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160032087A1

  公开（公告）日：2016-02-04

  Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluorine-containing polymer comprising an end-group having a structures from group consisting of: and combinations thereof; wherein X 1 , X 2 , and X 3 are each independently selected from H, F, Cl, a C 1 to C 4 alkyl group, and a C 1 to C 4 fluorinated alkyl group; R 7 is a linking group comprising at least 2 or more catenary atoms; and Z 1 and Z 2 are independently selected from F, CF 3 , and a perfluoroalkyl group.

  这里描述了一种可熔性聚合物组合物，包括：一种非氟化可熔性聚合物；以及一种含氟聚合物，该聚合物包括具有以下结构的末端基团组合：其中X1、X2和X3各自独立地选自H、F、Cl、C1到C4烷基和C1到C4氟烷基；R7是至少包含2个或更多链原子的连接基团；Z1和Z2各自独立地选自F、CF3和全氟烷基。
• Modified monoolefin copolymer elastomer with improved heat and oil resistance
  申请人：UNIROYAL, INC.

  公开号：EP0015627A1

  公开（公告）日：1980-09-17

  An EPM or EPDM type of elastomer is modified by graft copolymerization with acrylic ester type of monomeric material whose homopolymer has a glass transition temperature of not greater than 6° C, in an amount sufficient to provide an ester group (-COO-) content of from 25 to 40% by weight, to yield a mixed copolymerizate vulcanizable to a heat and oil resistant elastomeric state.

  通过与丙烯酸酯类单体材料接枝共聚改性 EPM 或 EPDM 弹性体，其均聚物的玻璃化转变温度不高于 6 摄氏度，其用量足以使酯基（-COO-）含量达到 25% 至 40% （按重量计），从而得到可硫化成耐热耐油弹性体状态的混合共聚物。
• A mult-component copolymer rubber, a process for producing the same, and a rubber composition containing the multi-component copolymer rubber
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0160399A2

  公开（公告）日：1985-11-06

  A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyanosubstituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. These properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

  一种多组分共聚橡胶主要由以下物质组成：(A) 20 至 69.5%（按重量计）氰基取代的烷基（甲基）丙烯酸酯；(B) 30 至 79.5%（按重量计）丙烯酸烷基酯；(C) 0.5 至 10%（按重量计）可交联单体；(D) 0 至 10%（按重量计）可与(A)、(B)和(C)共聚的其他乙烯基不饱和单体，该橡胶具有优异的耐热性、耐臭氧性、耐酸汽油性和耐酸汽油醇性。通过在共聚橡胶中加入交联剂、金属盐、偏氟乙烯聚合物、氯乙烯树脂或其他多组分共聚橡胶，可进一步改善所述多组分共聚橡胶的上述性能。
• Vulcanizable rubber compositions and applications thereof
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0194030A2

  公开（公告）日：1986-09-10

  A vulcanizable rubber composition comprises (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin, (II) at least one acrylic rubber, a,p-unsaturated nitrile-conjugated diene copolymer rubber or hydride of an a,p-unsaturated nitrile-conjugated diene copolymer rubber, (III) another blendable polymer, wherein the weight ratio of (I)/[(II) + (III)] is from 5/95 to 60/ 40 and the weight ratio of (II)/(III) is from 100/0 to 50/50, and (2) from 0 to 40 by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further has good tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, it can be used in the fluid-contacting surface of a diaphragm or as an inner tube of a fuel hose.

  一种可硫化橡胶组合物包括 (1) 100 重量份的聚合物组合物，其中包括 (I) 亚乙烯基氟化树脂、 (II) 至少一种丙烯酸橡胶、a,p-不饱和腈-共轭二烯共聚物橡胶或 a,p-不饱和腈-共轭二烯共聚物橡胶的氢化物、 (III) 另一种可混合聚合物、 其中(I)/[(II)+(III)]的重量比为 5/95 至 60/40，(II)/(III)的重量比为 100/0 至 50/50，以及 (2) 增塑剂的重量比为 0 至 40。上述橡胶组合物不仅在耐热性、耐汽油性和耐酸汽油性方面表现出色，而且在耐煤气醇性和耐酸煤气醇性方面也表现出色，并具有良好的拉伸强度、伸长率以及耐汽油性和耐低温性之间的平衡。因此，它可用于隔膜的流体接触面或作为燃油软管的内管。

表征谱图