3,3,5,5,8,8,10,10-Octamethyl-4,9,14-trioxa-3,5,8,10-tetrasilatetracyclo[10.3.0.02,6.07,11]pentadeca-1(15),2(6),7(11),12-tetraene | 887503-72-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异苯并呋喃
• 英文名称: 3,3,5,5,8,8,10,10-Octamethyl-4,9,14-trioxa-3,5,8,10-tetrasilatetracyclo[10.3.0.02,6.07,11]pentadeca-1(15),2(6),7(11),12-tetraene
• CAS: 887503-72-2
• 化学式: C₁₆H₂₆O₃Si₄
• 分子量: 378.723
• InChiKey: DEWIZWSCHMXFEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.14
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  31.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,3,5,5,8,8,10,10-Octamethyl-4,9,14-trioxa-3,5,8,10-tetrasilatetracyclo[10.3.0.02,6.07,11]pentadeca-1(15),2(6),7(11),12-tetraene 在 lithium aluminium tetrahydride 、 正丁基锂 、 四氯化钛 、 三乙胺 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 反应 31.0h， 生成 1,1,3,3,4,4,6,6-Octamethyl-1,3,4,6-tetrahydro-2,5-dioxa-1,3,4,6-tetrasila-dicyclopenta[a,c]anthracene
  参考文献：
  名称：

  Oxadisilole-Fused Isobenzofurans. Synthesis and Characterization of Oxadisilole-Substituted Acenes

  摘要：

  Mono- and bis-oxadisilole-fused isobenzofurans were first synthesized and isolated. A series of mono-, bis-, and tris-oxadisilole-substituted acenes were then synthesized by benzyne Diels-Alder reactions with the isobenzofurans. The photophysical, redox, and thermal properties of these new acenes were characterized.

  DOI：

  10.1021/jo060099d
• 作为产物：
  描述：

  在 3,6-二-2-吡啶基-1,2,4,5-四嗪 作用下， 以 氯仿 为溶剂， 生成 3,3,5,5,8,8,10,10-Octamethyl-4,9,14-trioxa-3,5,8,10-tetrasilatetracyclo[10.3.0.02,6.07,11]pentadeca-1(15),2(6),7(11),12-tetraene
  参考文献：
  名称：

  Oxadisilole fused pentacenequinones and heptacenequinones

  摘要：

  Stable, organic solvent soluble bis- and tetrakis-oxadisilole fused pentacenequinones (5a - b) and heptacenequinones (11a - b) were synthesized. Double Diels - Alder and fourfold aldol-condensation approaches were used. Absorption, emission and fluorescence quantum yield of the previously unknown acenequinones 5a and 11a were characterized. The role of the oxadisilole substituent on the photophysical properties was addressed. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.11.164

文献信息

• Oxadisilole Fused Triptycene and Extended Triptycene: Precursors of Triptycyne and Extended Triptycyne
  作者：Bao-Jian Pei、Wing-Hong Chan、Albert W. M. Lee

  DOI：10.1021/jo1016025

  日期：2010.11.5

  With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene Sand extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series or triptycene derivatives Were synthesized.
• Oxadisilole fused pentacenequinones and heptacenequinones
  作者：Ya-Li Chen、Wai-Yeung Wong、Albert W.M. Lee

  DOI：10.1016/j.tetlet.2007.11.164

  日期：2008.2

  Stable, organic solvent soluble bis- and tetrakis-oxadisilole fused pentacenequinones (5a - b) and heptacenequinones (11a - b) were synthesized. Double Diels - Alder and fourfold aldol-condensation approaches were used. Absorption, emission and fluorescence quantum yield of the previously unknown acenequinones 5a and 11a were characterized. The role of the oxadisilole substituent on the photophysical properties was addressed. (c) 2007 Elsevier Ltd. All rights reserved.
• Oxadisilole-Fused Isobenzofurans. Synthesis and Characterization of Oxadisilole-Substituted Acenes
  作者：Ya-Li Chen、Chun-Kit Hau、Hao Wang、Hao He、Man-Shing Wong、Albert W. M. Lee

  DOI：10.1021/jo060099d

  日期：2006.4.1

  Mono- and bis-oxadisilole-fused isobenzofurans were first synthesized and isolated. A series of mono-, bis-, and tris-oxadisilole-substituted acenes were then synthesized by benzyne Diels-Alder reactions with the isobenzofurans. The photophysical, redox, and thermal properties of these new acenes were characterized.