5,6-二甲基-1,3-二苯基-2-苯并呋喃 | 27720-47-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异苯并呋喃
• 中文名称: 5,6-二甲基-1,3-二苯基-2-苯并呋喃
• 英文名称: 5,6-dimethyl-1,3-diphenyl-isobenzofuran
• 英文别名: 1,3-Diphenyl-5,6-dimethyl-isobenzofuran；1,3-Diphenyl-5,6-dimethylisobenzofuran；5,6-Dimethyl-1,3-diphenyl-2-benzofuran
• CAS: 27720-47-4
• 化学式: C₂₂H₁₈O
• 分子量: 298.384
• InChiKey: LBASRTOKVSTSJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5,6-二甲基-1,3-二苯基-2-苯并呋喃 在 马来酸酐 、 乙醇 、 溶剂黄146 、 锌 作用下， 生成 6,7-dimethyl-1,4,9,10-tetraphenyl-1,2,3,4,9,10-hexahydro-1,4;9,10-diepoxido-anthracene-2,3-dicarboxylic acid
  参考文献：
  名称：

  An Instance of the Diene Synthesis with an Isobenzothiophene

  摘要：

  DOI：

  10.1021/ja01247a009
• 作为产物：
  描述：

  (+/-)-5r,6t-dibromo-5,6c-dimethyl-1,3-diphenyl-4,5,6,7-tetrahydro-isobenzofuran 在 sodium acetate 、 乙酸酐 、 溶剂黄146 作用下， 生成 5,6-二甲基-1,3-二苯基-2-苯并呋喃
  参考文献：
  名称：

  The Synthesis of 1,3-Diphenyldihydroisobenzofurans, 1,3-Diphenylisobenzofurans and o-Dibenzoylbenzenes from the Diene Addition Products to Dibenzoylethylene

  摘要：

  DOI：

  10.1021/ja01858a012

文献信息

• A new access to the anthracene core
  作者：C. Schmitz、J.M. Aubry、J. Rigaudy

  DOI：10.1016/0040-4020(82)80224-x

  日期：1982.1

  Two water soluble1O2 traps: dipotassium 1,3 - diphenylisobenzofuran - 5,6 - dicar☐ylate and tetrapotassium 9,10 - diphenylanthracene - 2,3,6,7 - tetracar☐ylate have been prepared in good yields and a new access to the anthracene skeleton is described. The key-step of this synthesis consists of a cycloaddition between 1,3 - diphenylisobenzofurans and dimethyl 7 - oxabicyclo[2.2.1] - 5 - heptene - 2

  制备了两个水溶性1 O 2捕集阱：1,3-二苯基异苯并呋喃-5-钾-5,6-二羧酸☐酯和9,10-二苯基蒽-2,3,6,7-四羧酸☐酯的高产率制备了一种新的描述了对蒽骨架的访问。该合成的关键步骤包括1，3-二苯基异苯并呋喃与二甲基7-氧杂双环[2.2.1] -5-庚烯-2，3-二甲叉基羧酸酯之间的环加成；这样得到的加合物经过脱水得到相应的蒽。
• Photopolymerization sensitizer composition
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US11352450B2

  公开（公告）日：2022-06-07

  The purpose of the present invention is to provide a photopolymerizable composition which can act as a photopolymerization sensitizer that is active against light having a wavelength falling within a wavelength range of from 300 to 500 nm, and which has such a property that coloring of a cured product produced by polymerizing a photopolymerizable composition containing the photopolymerization sensitizer is less. A photopolymerization sensitizer composition characterized by comprising a photopolymerization sensitizer containing an alkoxyanthracene compound represented by the formula (1) and a singlet oxygen quencher; and a photopolymerizable composition containing the photopolymerization sensitizer composition: in the formula (1), n represents an integer of 1 or 2; R represents a C1-12 alkyl group; and X represents a hydrogen atom or a C1-8 alkyl group.

  本发明的目的是提供一种可光聚合组合物，该组合物可作为光聚合敏化剂，对波长在300至500纳米范围内的光具有活性，并且具有这样一种特性，即通过聚合含有该光聚合敏化剂的可光聚合组合物而生产的固化产品着色较少。 一种光聚合增感剂组合物，其特征在于包括含有式（1）表示的烷氧蒽化合物和单线态氧淬灭剂的光聚合增感剂；以及含有该光聚合增感剂组合物的可光聚合组合物： 式（1）中，n 代表 1 或 2 的整数；R 代表 C1-12 烷基；X 代表氢原子或 C1-8 烷基。
• Friedrichsen, Willy; Roehe, Meike; Debaerdemaeker, Tony, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 5, p. 632 - 643
  作者：Friedrichsen, Willy、Roehe, Meike、Debaerdemaeker, Tony

  DOI：——

  日期：——
• THE DIENE SYNTHESIS WITH β-NITROSTYRENE
  作者：C. F. H. ALLEN、A. BELL、J. W. GATES

  DOI：10.1021/jo01192a011

  日期：1943.7
• Photophysical, Electrochemical, and Electrogenerated Chemiluminescent Properties of 9,10-Dimethyl-7,12-diphenylbenzo[<i>k</i>]fluoranthene and 9,10-Dimethylsulfone-7,12-diphenylbenzo[<i>k</i>]fluoranthene
  作者：Eve F. Fabrizio、Andrew Payne、Neil E. Westlund、Allen J. Bard、Philip P. Magnus

  DOI：10.1021/jp012012s

  日期：2002.3.1

  A newly synthesized light emitting compound 9,10-dimethylsulfone-7,12-diphenylbenzo[k]fluoranthene (DSDPBF) and its synthetic intermediate 9, 10-dimethyl-7,12-diphenylbenzo[k] fluoranthene (DMDPBF) were studied to evaluate how the addition of weak electron donating methyl groups and the subsequent addition of an electron withdrawing sulfone group affect the photophysical and electrochemical properties as well as the rate of radical cation coupling of the parent compound, 7,12-diphenylbenzo[k]fluoranthene (DPBF). Although the photochemical and electrochemical properties of DSDPBF were more similar to the unsubstituted DPBF than to the DMDPBF, there was a substantial decrease in the quantum efficiency upon addition of the electron-rich sulfone group which was not observed upon addition of the methyl groups. On the other hand, the rate of radical cation coupling or dimerization observed upon electrochemical oxidation varied significantly. The addition of the electron donating methyl groups decreased the reactivity of the radical cation resulting in a 40 times slower rate of dimerization than that observed for the unsubstituted benzo[k]fluoranthene, whereas the addition of the electron withdrawing sulfone group to the methyl groups increased the radical cation reactivity resulting in a rate of dimerization that was 3 times faster than the unsubstituted parent compound. As a result, the electrogenerated chemiluininescence emission spectrum obtained from the annihilation reaction between the radical anion and radical cations of DSDPBF was dominated by emission from the dimer at 589 and 621 nm instead of emission from the monomer at ca. 485 nm.