2-tert-butyl-9,10-bis[4-(9-carbazolyl)phenyl]anthracene

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2-tert-butyl-9,10-bis[4-(9-carbazolyl)phenyl]anthracene
• 英文别名: 2-t-butyl-9,10-bis(4-(N-carbazolyl)phenyl) anthracene；9-[4-[2-Tert-butyl-10-(4-carbazol-9-ylphenyl)anthracen-9-yl]phenyl]carbazole
• 化学式: C₅₄H₄₀N₂
• 分子量: 716.925
• InChiKey: LQSLGUFCWYVGAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  56
• 可旋转键数：
  5
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9,10-双(4-溴苯基)-2-叔丁基蒽 、 咔唑 在 三叔丁基膦 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以45%的产率得到2-tert-butyl-9,10-bis[4-(9-carbazolyl)phenyl]anthracene
  参考文献：
  名称：

  WO2006/104221

  摘要：

  公开号：

文献信息

• Anthracene Derivative, Material for Light Emitting Element, Light Emitting Element, Light Emitting Device, and Electronic Device
  申请人：Kawakami Sachiko

  公开号：US20090015140A1

  公开（公告）日：2009-01-15

  It is an object of the present invention to provide a novel material capable of realizing excellent color purity of blue, and a light emitting element and a light emitting device using the novel material. Further, it is an object of the present invention to provide which is highly reliable, and a light emitting element and a light emitting device using the novel material. The structure for solving the above problems in accordance with the present invention is an anthracene derivative simultaneously having a diphenylanthracene structure and a carbazole skeleton in a molecule as represented by structural formula ( 1 ):

  本发明的目的是提供一种新型材料，能够实现优异的蓝色纯度，以及使用该新型材料的发光元件和发光装置。此外，本发明的另一个目的是提供一种高度可靠的，使用该新型材料的发光元件和发光装置。本发明解决上述问题的结构是一种蒽衍生物，其分子同时具有二苯基蒽结构和咔唑骨架，如结构式（1）所示：
• Efficient non-doped blue light emitting diodes based on novel carbazole-substituted anthracene derivatives
  作者：Ying-Hsiao Chen、Shin-Lei Lin、Yu-Chen Chang、Yung-Chung Chen、Jiann-Tsuen Lin、Rong-Ho Lee、Wen-Jang Kuo、Ru-Jong Jeng

  DOI：10.1016/j.orgel.2011.10.004

  日期：2012.1

  In this study, we synthesized three anthracene derivatives featuring carbazole moieties as side groups -2-tert-butyl-9,10-bis[4-(9-carbazolyl)phenyl]anthracene (Cz(9)PhAnt), 2-tert-butyl-9,10-bis4-[3,6-di-tert-butyl-(9-carbazolyl)]phenyl}anthracene (tCz(9)PhAnt), and 2-tert-butyl-9,10-bis4'-[3,6-di-tert-butyl-(9-carbazolyl)]biphenyl-4-yl}anthracene (tCz(9)Ph(2) Ant) - for use in blue organic light emitting devices (OLEDs). The anthracene derivatives presenting rigid and bulky tert-butyl-substituted carbazole units possessed high glass-transition temperatures (220 degrees C). Moreover, the three anthracene derivatives exhibited strong blue emissions in solution, with high quantum efficiencies (91%). We studied the electroluminescence (EL) properties of non-doped OLEDs incorporating these anthracene derivatives, with and without a hole-transporting layer (HTL). OLEDs incorporating an HTL provided superior EL performance than did those lacking the HTL. The highest brightness (6821 cd/m(2)) was that for the tCz(9)PhAnt-based device; the greatest current efficiency (2.1 cd/A) was that for the tCz(9)Ph(2)Ant-based device. The devices based on these carbazole-substituted anthracene derivatives also exhibited high color purity. (C) 2011 Elsevier B. V. All rights reserved.
• ANTHRACENE DERIVATIVE, MATERIAL FOR LIGHT EMITTING ELEMENT, LIGHT EMITTING ELEMENT, LIGHT EMITTING DEVICE, AND ELECTRONIC DEVICE
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP1896413B1

  公开（公告）日：2015-04-22
• Anthracene Derivative, Material For Light Emitting Element, Light Emitting Element, Light Emitting Device, And Electronic Device
  申请人：KAWAKAMI Sachiko

  公开号：US20130005067A1

  公开（公告）日：2013-01-03

  It is an object of the present invention to provide a novel material capable of realizing excellent color purity of blue, and a light emitting element and a light emitting device using the novel material. Further, it is an object of the present invention to provide which is highly reliable, and a light emitting element and a light emitting device using the novel material. The structure for solving the above problems in accordance with the present invention is an anthracene derivative simultaneously having a diphenylanthracene structure and a carbazole skeleton in a molecule as represented by structural formula (1):
• US8039122B2
  申请人：——

  公开号：US8039122B2

  公开（公告）日：2011-10-18