2,2'-[1,6-己烷二基二(氧基)]二苯甲醛 | 77355-02-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2,2'-[1,6-己烷二基二(氧基)]二苯甲醛
• 英文名称: 1,6-bis(4'-formylphenoxy)-n-hexane
• 英文别名: 4,4'-(hexane-1,6-diylbis(oxy))dibenzaldehyde；hexamethylene-1,6-bis(4-oxybenzaldehyde)；4,4′-(hexane-1,6-diylbis(oxy))dibenzaldehyde；4-[6-(4-Formylphenoxy)hexoxy]benzaldehyde
• CAS: 77355-02-3
• 化学式: C₂₀H₂₂O₄
• 分子量: 326.392
• InChiKey: ZSIVOFNVHLOMBY-UHFFFAOYSA-N

物化性质

• 熔点：
  106-107 °C
• 沸点：
  513.1±35.0 °C(Predicted)
• 密度：
  1.134±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2912299000

反应信息

• 作为反应物：
  描述：

  2,2'-[1,6-己烷二基二(氧基)]二苯甲醛 在 哌啶 、 sodium hydroxide 、 氨 、 乙酸酐 、 溶剂黄146 作用下， 以 苯 为溶剂， 反应 51.0h， 生成 4,4'-(α,ψ-Hexylenedioxy)diphenylsuccinimide
  参考文献：
  名称：

  Relationship between chemical structure and anticonvulsive activity in 4,4′-(α, ω-alkylenedioxy)diphenylsuccinimides

  摘要：

  DOI：

  10.1007/bf00765771
• 作为产物：
  描述：

  对羟基苯甲醛 以73%的产率得到
  参考文献：
  名称：

  NESUNTS, N. S.;AVETISYAN, S. A.;DZHAGATSPANYAN, I. A.;AKOPYAN, N. E.;MNDZ+, XIM.-FARMATS. ZH., 1983, 17, N 7, 801-806

  摘要：

  DOI：

文献信息

• New bispyrazoline derivatives built around aliphatic chains: Synthesis, characterization and antimicrobial studies
  作者：MOHAMAD YUSUF、PAYAL JAIN

  DOI：10.1007/s12039-012-0355-9

  日期：2013.1

  Aspergillius janus, Aspergillus niger and Pencillium glabrum, respectively. The antimicrobial behaviour of the bispyrazolines 3a–3h is found to be dependent on the length of internal spacer unit. Synthesis and antimicrobial behaviour of the bispyrazolines built around the aliphatic chains have been described. The antimicrobial behaviour of these bisheterocyclic compounds is found to be dependent on the

  双吡唑啉3a - 3h围绕不同长度的烷基链构建，是由比沙可康烯与苯基肼的环化反应合成的。从苯乙酮与各种双醛1a - 1h的Claisen-Schmidt反应中获得了Bischalcones 2a - 2h。通过IR，1 H-NMR，13 C-NMR，质量（ESI）和元素分析来表征中间的双缩水锥和最终的双杂环化合物。还评估了合成化合物的抗细菌和抗真菌活性，对肺炎克氏杆菌，铜绿假单胞菌，大肠埃希菌，金黄色葡萄球菌，枯草芽孢杆菌和janjan曲霉，黑曲霉和延寿草。发现双吡唑啉3a – 3h的抗菌性能取决于内部间隔单元的长度。 已经描述了围绕脂族链构建的双吡唑啉的合成和抗菌性能。发现这些双杂环化合物的抗微生物行为取决于内部间隔单元的长度。
• Symmetrical molecules of low band gap with a central spacer connected via ether bond with terminal 4-nitro-α-cyanostilbene units: Synthesis and application for bulk heterojunction solar cells
  作者：J.A. Mikroyannidis、A.N. Kabanakis、S.S. Sharma、Anil Kumar、G.D. Sharma

  DOI：10.1016/j.orgel.2010.07.010

  日期：2010.10

  742 nm which corresponds to an optical band gap of 1.67 eV. We have fabricated bulk heterojunction (BHJ) photovoltaic devices using these molecules as donor and PCBM as acceptor. We have investigated the solvent vapor treatment effect of these blends on their morphology and photovoltaic properties. We found that the overall power conversion efficiency (PCE) for the devices based on the solvent vapor

  合成了两个新的具有低带隙的具有中心间隔基的可溶性和对称分子M1和M2，该中心间隔基在两侧通过醚键与末端4-硝基-α-氰基苯乙烯单元相连。M1和M2的间隔基由二己氧基苯撑和n-己烯。它们的长波吸收最大值在590–640 nm。两个分子的薄膜吸收起始点位于742nm处，这对应于1.67eV的光学带隙。我们已经制造了使用这些分子作为施主和PCBM作为受主的体异质结（BHJ）光伏器件。我们已经研究了这些共混物的溶剂蒸气处理对其形态和光电性能的影响。我们发现基于溶剂蒸汽处理的M1：PCBM和M2的设备的整体功率转换效率（PCE）：PCBM混合物分别比原始混合物高3.05％和1.90％。PCE的增加归因于共混物表面粗糙度的增加和电荷传输的更好平衡。通过热退火的溶剂处理过的M1：PCBM和M2：PCBM共混物，PCE进一步提高到3.57％和2.42％。PCE的增加可能归因于共混物结晶度的提高和空间电荷效
• A New Route to Hyperbranched Macromolecules:  Syntheses of Photosensitive Poly(aroylarylene)s via 1,3,5-Regioselective Polycyclotrimerization of Bis(aroylacetylene)s
  作者：Hongchen Dong、Ronghua Zheng、Jacky W. Y. Lam、Matthias Häussler、Anjun Qin、Ben Zhong Tang

  DOI：10.1021/ma050342v

  日期：2005.7.26

  A new synthetic route to hyperbranched polymers is developed. Polycyclotrimerizations of functional diynes 1−3 initiated by a simple base of piperidine lead to the formation of hyperbranched poly(aroylarylene)s P1−P3 with perfect 1,3,5-regioregularity and high degree of branching (up to 100%) in high yields (up to 99%). The polymers show high photosensitivities and can be readily photo-cross-linked

  开发了一种新的合成超支化聚合物的途径。官能二炔的Polycyclotrimerizations 1 - 3通过的哌啶引线的简单碱启动以形成超支化聚（aroylarylene）类P的1 -P 3具有完美1,3,5-区域规整和高的支化度（高达100％）高产（高达99％）。该聚合物显示出高的光敏性，并且可以容易地进行光交联以产生具有纳米分辨率的光致抗蚀剂图案。
• Photochromic behavior of several new synthesized bis-1,3-diazabicyclo[3.1.0]hex-3-enes
  作者：H. Kiyani、N. O. Mahmoodi、K. Tabatabaeian、M. Zanjanchi

  DOI：10.1002/poc.1550

  日期：2009.5

  Photochromic compounds (1–6) are synthesized and characterized and the results of their spectra are presented. The structure–photochromic behavior relationship (SPBR) of the synthesized compounds has been analyzed. Copyright © 2009 John Wiley & Sons, Ltd.

  合成并表征了光致变色化合物（1-6），并给出了其光谱结果。分析了合成化合物的结构-光致变色行为关系（SPBR）。版权所有©2009 John Wiley＆Sons，Ltd.
• Mesomorphic Behavior of Symmetric Azomethine Dimers Containing Different Chromophore Groups
  作者：Elena Perju、Luminita Marin

  DOI：10.3390/molecules26082183

  日期：——

  A series of new azomethine dimers was synthesized by the condensation reaction of flexible bis-benzaldehydes with four aromatic amines containing phenyl, naphthyl, anthracene and pyrene groups. Their right structure was confirmed by FTIR and 1H-NMR spectroscopy and their thermal properties were investigated by thermogravimetric analysis, differential scanning calorimetry and polarized light optical microscopy. A view on their photophysical behavior was gained by UV-vis and photoluminescence spectroscopy. The dimers containing pyrene and anthracene presented liquid crystalline behavior, while the other dimers were crystalline compounds. Two dimers containing pyrene moieties formed mesomorphic glasses and had intense luminescence, promising properties for applications in building optoelectronic devices.

  一系列新的偶氮亚甲基二聚体通过柔性双苯甲醛与含有苯基、萘基、蒽基和芘基的四种芳香胺的缩合反应合成。它们的正确结构经过傅立叶红外光谱和1H-NMR光谱确认，它们的热性质通过热重分析、差示扫描量热法和偏光光学显微镜进行研究。通过紫外-可见光谱和光致发光光谱获得了它们的光物理行为。含有芘和蒽的二聚体呈现液晶行为，而其他二聚体是结晶化合物。含有芘基团的两个二聚体形成了介晶玻璃，并具有强烈的发光，这些性质有望应用于光电子器件的制造。