bis-(4-methylsulfanyl-phenyl)-ether | 35370-99-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(4-methylsulfanyl-phenyl)-ether
• 英文别名: Bis-(4-methylmercapto-phenyl)-aether；4,4'-Bis(methylthio)diphenylether；1-(Methylsulfanyl)-4-[4-(methylsulfanyl)phenoxy]benzene；1-methylsulfanyl-4-(4-methylsulfanylphenoxy)benzene
• CAS: 35370-99-1
• 化学式: C₁₄H₁₄OS₂
• 分子量: 262.397
• InChiKey: JRDVJUWGULNZLR-UHFFFAOYSA-N

物化性质

• 沸点：
  382.6±27.0 °C(Predicted)
• 密度：
  1.21±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis-(4-methylsulfanyl-phenyl)-ether 、 C₁₁H₁₁NO 在 1-(3-aminopropyl)-3-methylimidazolium bromide 、 NHC-Pd(II)-Im 作用下， 反应 12.0h， 以81%的产率得到5-methyl-4-(4-(methylthio)phenyl)-3-phenylisoxazole
  参考文献：
  名称：

  NHC-钯催化离子液体加速炔烃与二芳基醚的区域选择性氧化芳基化

  摘要：

  第一次 NHC 钯催化的肟醚在特定任务的离子液体中通过C(sp 3 )-O 和 C(sp 2 )-O 键裂解两种不同类型的醚进行区域选择性氧芳基化，用于组装结构多样的 4描述了-芳基异恶唑。碱性离子液体 [C 3 NH 2 mim]Br 和 NHC-Pd 催化剂 IPr-Pd-Im-Cl 2在这一转变中发挥了重要作用。值得注意的是，这种新方法提供了一种实用且直接的途径，可以以良好的收率和出色的区域选择性获得广泛的特权 4-芳基异恶唑结构。值得注意的是，这种催化系统可以循环使用多达八次，而不会显着降低催化活性。

  DOI：

  10.1039/d1gc04556c
• 作为产物：
  描述：

  双(4-氯磺酰苯基)醚 在 盐酸 、 sodium hydroxide 、 溶剂黄146 、 tin(ll) chloride 作用下， 生成 bis-(4-methylsulfanyl-phenyl)-ether
  参考文献：
  名称：

  Studies in the Phenyl Ether Series. IV. Phenoxybenzene-4,4'-dithiol and Related Compounds

  摘要：

  DOI：

  10.1021/ja01292a015

文献信息

• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• OXIME ESTER COMPOUND AND PHOTOPOLYMERIZATION INITIATOR CONTAINING SAID COMPOUND
  申请人：ADEKA CORPORATION

  公开号：US20170166575A1

  公开（公告）日：2017-06-15

  The present invention provides oxime ester compounds represented by general formula (I), a photopolymerization initiator using said compound, and a photosensitive composition, alkali-developable photosensitive resin composition, and colored alkali-developable photosensitive resin composition containing same, and cured products thereof. The compounds of the present invention have excellent stability and low sublimability, and are useful as highly sensitive photopolymerization initiators that are activated by efficiently absorbing near ultraviolet light of 365 nm, etc. (I) (See the Specification for the definitions of R 1 -R 8 in the formula. n represents 0 or 1.)

  本发明提供了一种由通用式（I）表示的肟酯化合物，使用该化合物的光聚合引发剂，以及包含相同化合物的光敏组合物、可碱开发的光敏树脂组合物和着色的可碱开发的光敏树脂组合物及其固化产品。本发明的化合物具有优异的稳定性和低升华性，并且可作为高灵敏度的光聚合引发剂，通过高效吸收365纳米等近紫外光激活。（I）（有关R1-R8在式中的定义，请参见说明书。n代表0或1。）
• NOVEL COMPOUND HAVING alpha-CYANOACRYLATE STRUCTURE, DYE, AND COLORED PHOTOSENSITIVE COMPOSITION
  申请人：Maeda Yosuke

  公开号：US20140005292A1

  公开（公告）日：2014-01-02

  A compound represented by the following general formula (1). In the formula, A represents a benzene ring, a naphthalene ring and the like, wherein these rings may be substituted with a halogen atom and the like, R 1 represents a hydrogen atom and the like, R 2 represents a C 1-35 hydrocarbon group having or not having at least one group selected from an epoxy group, 4-vinylphenyl group and a (meth)acryloyloxy group, or a hydrogen atom, wherein at least one of R 2 with n occurrences is a C 3-35 hydrocarbon group having at least one group selected from an epoxy group, a 4-vinylphenyl group and a (meth)acryloyloxy group, n represents an integer of 1 to 6, and X represents a nitrogen atom, an oxygen atom, a sulfur atom, a phosphorus atom, or an n-valent organic group having 35 or less carbon atoms.

  以下为通式（1）所代表的化合物。其中，A代表苯环、萘环等，这些环可能被卤素等取代，R1代表氢原子等，R2代表具有或不具有环氧基团、4-乙烯基苯基团和（甲基）丙烯酰氧基团中至少一种基团的C1-35碳氢基团或氢原子，其中R2中至少有一个出现n次的基团是具有至少一种环氧基团、4-乙烯基苯基团和（甲基）丙烯酰氧基团中的一种的C3-35碳氢基团，n表示1到6的整数，X表示氮原子、氧原子、硫原子、磷原子或具有35个或更少碳原子的n价有机基团。
• DYE AND COLORING PHOTOSENSITIVE COMPOSITION
  申请人：Maeda Yosuke

  公开号：US20130041062A1

  公开（公告）日：2013-02-14

  The present invention provides a dye that is excellent in solubility and excellent in heat resistance and a novel compound that is preferable for the dye, and specifically provides a yellow dye having a wavelength of maximum absorption in the region of 400 to 450 nm, and also provides a coloring (alkali-developable) photosensitive composition using the above-mentioned dye, and an optical filter using the above-mentioned coloring (alkali-developable) photosensitive composition, specifically a color filter that does not decrease luminance and thus is preferable for image display devices such as liquid crystal display panels. Specifically, a compound represented by the following general formula (1) is used as the dye. The content of the above-mentioned general formula (1) is as described in the description.

  本发明提供了一种溶解性和耐热性均优异的染料以及一种优选用于该染料的新化合物，具体提供了在400至450 nm最大吸收波长区域具有黄色染料，并提供了使用上述染料的着色（碱可显影）光敏组合物和使用上述着色（碱可显影）光敏组合物的光学滤光片，具体为不降低亮度的彩色滤光片，因此非常适用于液晶显示面板等图像显示设备。具体来说，将下列通式（1）所表示的化合物用作染料。上述通式（1）的内容如说明书所述。
• 2,3-Dihydro-1H-phenalene-2-amino compounds as anti-psychotic drugs
  申请人：THE UPJOHN COMPANY

  公开号：EP0234113A1

  公开（公告）日：1987-09-02

  2-3-Dihydro-1H-phenalene-2-amino compounds of the formula some of which are new, e.g., 2-3-dihydro-2-(N,N-di-n-propylamino)-1H-phenalen-5-ol, and pharmaceutically acceptable salts of such compounds have been found to be useful anti-psychotic drug compounds.

  已发现 2-3-二氢-1H-苯丙烯-2-氨基化合物（其中一些是新式化合物，如 2-3-二氢-2-（N,N-二正丙基氨基）-1H-苯丙烯-5-醇）以及此类化合物的药学上可接受的盐类是有用的抗精神病药物化合物。