1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1,6-bis[(trifluoroethenyl)oxy]hexane | 69818-04-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1,6-bis[(trifluoroethenyl)oxy]hexane
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-1,6-bis(1,2,2-trifluoroethenoxy)hexane
• CAS: 69818-04-8
• 化学式: C₁₀F₁₈O₂
• 分子量: 494.08
• InChiKey: DQQSCDWHXLEEHU-UHFFFAOYSA-N

物化性质

• 沸点：
  219.3±40.0 °C(Predicted)
• 密度：
  1.697±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1,6-bis[(trifluoroethenyl)oxy]hexane 、 在 potassium carbonate 作用下， 以42.7 g的产率得到
  参考文献：
  名称：

  US2023/108820

  摘要：

  公开号：
• 作为产物：
  描述：

  1-氯-6H-十二氟己烷 在 potassium fluoride 、 chlorine fluorosulfate 、 双(氟磺酰基)过氧化物 、 五氟化锑 、 氟磺酸 、 potassium carbonate 作用下， 以 二乙二醇二甲醚 为溶剂， 生成 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1,6-bis[(trifluoroethenyl)oxy]hexane
  参考文献：
  名称：

  Rapkin, A. I.; Zabolot-skikh, V. F.; Kochanov, A. S., Russian Journal of Applied Chemistry, 1995, vol. 68, # 1part2, p. 133 - 134

  摘要：

  DOI：

文献信息

• Synthesis of perfluoroxaalkylenedivinyl ethers
  作者：A. A. Glazkov、A. V. Ignatenko、S. P. Krukovskii、V. A. Ponomarenko

  DOI：10.1007/bf00951708

  日期：1979.11
• IVANOVA T. L.; RYAZANOVA R. M.; SOKOLOV S. V., ZH. BCEC. XIM. O-BA IM. D. I. MENDELEEVA, 1979, 24, HO 6, 656-657
  作者：IVANOVA T. L.、 RYAZANOVA R. M.、 SOKOLOV S. V.

  DOI：——

  日期：——
• GLAZKOV A. A.; IGNATENKO A. V.; KRUKOVSKIJ S. P.; PONOMARENKO V. A., IZV. AN CCCP. CEP. XIM., 1976, HO 11, 2512-2515
  作者：GLAZKOV A. A.、 IGNATENKO A. V.、 KRUKOVSKIJ S. P.、 PONOMARENKO V. A.

  DOI：——

  日期：——
• NOVEL CROSSLINKABLE FLUORINE-CONTAINING ETHER COMPOUND
  申请人：ITO Takayuki

  公开号：US20080255337A1

  公开（公告）日：2008-10-16

  A crosslinkable fluorine-containing compound, which is an adduct compound having a crosslinkable group, wherein the adduct compound is an adduct of a fluorine-containing compound having, per molecule, 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom.
• NOVEL FLUORINE-CONTAINING POLYMER AND METHOD OF PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Ito Takayuki

  公开号：US20090318650A1

  公开（公告）日：2009-12-24

  A method of producing a fluorine-containing polymer, containing conducting an addition polymerization of a fluorine-containing compound having 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom per molecule, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom; and a fluorine-containing polymer comprising a repeating unit represented by formula (i): wherein Rf 1 represents a perfluoroalkylene group; each of Rf 2 and Rf 3 independently represents a fluorine atom, a perfluoroalkyl group or a perfluoroalkoxy group; at least two among Rf 1 , Rf 2 and Rf 3 may bond to each other to form a ring structure; X represents an oxygen atom or a sulfur atom; and L represents a divalent organic group.