1H,1H,1H,2H-tridecafluoro-2-methyl-octan-2-ol | 57241-98-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1H,1H,1H,2H-tridecafluoro-2-methyl-octan-2-ol
• 英文别名: 2-(Perfluor-n-hexyl)isopropanol；2-Methyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctane-2-ol；3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-2-methyloctan-2-ol
• CAS: 57241-98-2
• 化学式: C₉H₇F₁₃O
• 分子量: 378.133
• InChiKey: MKAFJONADSJASB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  甲基碘化镁 、 全氟庚酸甲酯 以6%的产率得到
  参考文献：
  名称：

  BATIZAT, D. V.;YAROSH, A. A.;IGNATENKO, A. V.;PONOMARENKO, V. A., IZV. AN CCCP. CEP. XIM.,(1988) N 5, 1163-1165

  摘要：

  DOI：

文献信息

• Reactions of perfluoroalkylcalcium derivatives with ketones and aldehydes
  作者：Georges Santini、Maurice Le Blanc、Jean G. Riess

  DOI：10.1016/s0022-328x(00)84390-9

  日期：1977.10

  Perfluoroalkyl iodides, RFI, react in ethers with aldehydes and ketones in the presence of calcium to give the alcohols RFC(OH)R1R2. The best yields (20–70%) were obtained with Ca/Hg amalgam in THF as solvent at −20 to −40°C. The new alcohols were characterized by 1H and 19F NMR and mass spectrometry. The results are interpreted in terms of the intermediate formation of an organocalcium species.

  全氟烷基碘化物R F I在醚中与醛和酮在钙存在下反应，得到醇R F C（OH）R1R2。在-20至-40°C的温度下，使用THF中的Ca / Hg汞齐作为溶剂可获得最佳收率（20–70％）。通过1 H和19 F NMR和质谱对新型醇进行表征。根据有机钙物质的中间形成来解释结果。
• Perfluoroalkyl calcium derivatives: reactions with carbonyl compounds
  作者：Georges Santini、Maurice Le Blanc、Jean G. Riess

  DOI：10.1039/c39750000678

  日期：——

  Perfluoroalkylcalcium derivatives, prepared by the action of perfluoroalkyl iodides on amalgamated calcium in ethers, react with aldehydes and ketones to give the expected alcohols in 20–70% yields.

  全氟烷基碘衍生物是通过全氟烷基碘化物作用于醚中的合并钙而制得的，可与醛和酮反应，以20-70％的收率得到预期的醇。
• COMPOSITION FOR ABSORPTION REFRIGERATOR
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0048281A1

  公开（公告）日：1982-03-31

  A composition for an absorption refrigerator, which contains at least one fluorinated alcohol refrigerant containing 2 to 10 carbon atoms, is liquid at ordinary temperature, and becomes volatile upon heating under ordinary or reduced pressure, and at least one absorbent having a higher boiling point than said refrigerant at ordinary pressure and being capable of absorbing said refrigerant; and an absorption-refrigerating system using said composition.

  一种用于吸收式制冷机的组合物，它包含至少一种含 2 至 10 个碳原子的氟化醇制冷剂，在常温下为液态，在常压或减压下加热时变为挥发性，以及至少一种吸收剂，在常压下其沸点高于所述制冷剂，并能吸收所述制冷剂；以及一种使用所述组合物的吸收式制冷系统。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.1, 2.3, page 27 - 27
  作者：

  DOI：——

  日期：——
• Synthesis and coordination chemistry of perfluoroalkyl-derivatised β-diketonates
  作者：Ben Croxtall、John Fawcett、Eric G. Hope、Alison M. Stuart

  DOI：10.1016/s0022-1139(02)00251-8

  日期：2003.1

  A series of fluorinated beta-diketones, RfC(O)CH2C(O)R-f, (R-f = C6F13, R-f, = CF3; R-f = R-f, = C6F13, C7F15), have been prepared in reasonable yields by a two-step synthesis. On reaction with appropriate metal substrates, deprotonation and concurrent coordination of the perfluoroalkyl-derivatised beta-diketonate ligands affords a range of fluorous metal complexes which have been characterised by elemental analysis, mass spectrometry, IR and NMR spectroscopies. The structures of [Cu(L-L)(2)(H2O)(2)] L-L= CF3C(O)CHC(O)C6F13, C6F13C(O)CHC(O)C6F13} and [Cu(PPh3)(2)C7F15C(O)CHC(O)C7F15}] have been determined by single-crystal X-ray diffraction. (C) 2002 Elsevier Science B.V. All rights reserved.