2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecan-1-oxy)-6-allyloxy-s-tetrazine

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecan-1-oxy)-6-allyloxy-s-tetrazine
• 英文别名: 3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecoxy)-6-prop-2-enoxy-1,2,4,5-tetrazine；3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecoxy)-6-prop-2-enoxy-1,2,4,5-tetrazine
• 化学式: C₁₅H₉F₁₇N₄O₂
• 分子量: 600.235
• InChiKey: CBMWBIWORVDUKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  38
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  70
• 氢给体数：
  0
• 氢受体数：
  23

反应信息

• 作为产物：
  描述：

  1H,1H,2H,2H-全氟-1-癸醇 、 2-chloro-6-allyloxy-s-tetrazine 在 2,4,6-三甲基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以58%的产率得到2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecan-1-oxy)-6-allyloxy-s-tetrazine
  参考文献：
  名称：

  Synthesis and characterization of new fluorinated tetrazines displaying a high fluorescence yield

  摘要：

  New tetrazines substituted with perfluorinated alkyl chains have been synthesized and their electrochemical and photophysical properties investigated under various conditions. Their fluorescence quantum yields in dichloromethane appear to be interestingly slightly higher than with classical tetrazines, placing these new derivatives among the most fluorescent tetrazines characterized to date. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.03.031

文献信息

• Synthesis and characterization of new fluorinated tetrazines displaying a high fluorescence yield
  作者：Radhia Ben Châabane、Refka Guermazi、Gilles Clavier、Pierre Audebert、Ahmed Hedhli

  DOI：10.1016/j.dyepig.2014.03.031

  日期：2014.9

  New tetrazines substituted with perfluorinated alkyl chains have been synthesized and their electrochemical and photophysical properties investigated under various conditions. Their fluorescence quantum yields in dichloromethane appear to be interestingly slightly higher than with classical tetrazines, placing these new derivatives among the most fluorescent tetrazines characterized to date. (C) 2014 Elsevier Ltd. All rights reserved.