4,4'-oxybispyridine | 53258-96-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4'-oxybispyridine
• 英文别名: di-[4]pyridyl ether；Di-[4]pyridyl-aether；4,4'-Dipyridylether；Pyridine, 4,4'-oxybis-；4-pyridin-4-yloxypyridine
• CAS: 53258-96-1
• 化学式: C₁₀H₈N₂O
• 分子量: 172.186
• InChiKey: VJVWXXJJQUKUPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  氟磺酸甲酯 、 4,4'-oxybispyridine 以 苯 为溶剂， 反应 1.0h， 以20%的产率得到1,1'-dimethyl-4,4'-oxybispyridinediium bis(fluorosulfonate)
  参考文献：
  名称：

  Rockley, Jean E.; Summers, Lindsay A., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1983, vol. 38, # 8, p. 1034

  摘要：

  DOI：
• 作为产物：
  描述：

  silver 4-pyridoxide 、 4-硝基吡啶 生成 4,4'-oxybispyridine
  参考文献：
  名称：

  ROCKLEY J. E.; SUMMERS L. A., CHEM. AND IND., 1981, NO 3, 97

  摘要：

  DOI：

文献信息

• NHC–palladium-catalyzed ionic liquid-accelerated regioselective oxyarylation of alkynes with diaryl ethers
  作者：Jianxiao Li、Dan He、Zidong Lin、Liying Cen、Wanqing Wu、Huanfeng Jiang

  DOI：10.1039/d1gc04556c

  日期：——

  task-specific ionic liquid via C(sp3)–O and C(sp2)–O bond cleavage of two different types of ethers for the assembly of structurally diverse 4-arylisoxazoles is described. Both the basic ionic liquid [C3NH2mim]Br and NHC–Pd catalyst IPr–Pd–Im–Cl2 played an important role in this transformation. Notably, this new approach provides a practical and straightforward route to access a broad range of privileged 4-arylisoxazole

  第一次 NHC 钯催化的肟醚在特定任务的离子液体中通过C(sp 3 )-O 和 C(sp 2 )-O 键裂解两种不同类型的醚进行区域选择性氧芳基化，用于组装结构多样的 4描述了-芳基异恶唑。碱性离子液体 [C 3 NH 2 mim]Br 和 NHC-Pd 催化剂 IPr-Pd-Im-Cl 2在这一转变中发挥了重要作用。值得注意的是，这种新方法提供了一种实用且直接的途径，可以以良好的收率和出色的区域选择性获得广泛的特权 4-芳基异恶唑结构。值得注意的是，这种催化系统可以循环使用多达八次，而不会显着降低催化活性。
• NOVEL DIHYDRAZIDES AS DOT-PROMOTING AGENTS IN PHOTOGRAPHIC IMAGE SYSTEMS
  申请人：INTERNATIONAL PAPER COMPANY

  公开号：EP0797789B1

  公开（公告）日：1998-11-25
• US3932388A
  申请人：——

  公开号：US3932388A

  公开（公告）日：1976-01-13
• US4698091A
  申请人：——

  公开号：US4698091A

  公开（公告）日：1987-10-06
• [EN] CONJUGATED POLYVIOLOGEN DERIVATIVES<br/>[FR] DÉRIVÉS CONJUGUÉS DE POLYVIOLOGÈNE
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2018021970A1

  公开（公告）日：2018-02-01

  The present invention relates to an acceptor-acceptor type conjugated polymer that is an n-type conducting polymer having the following Formula (I): wherein Q is a bond, an optionally substituted aryl or an optionally substituted heteroaryl; A1 and A2 are independently hydrogen, halogen or an optionally substituted alkyl, or any two A1 may optionally be taken together to form an optionally substituted aryl; Ar is an optionally substituted electron deficient aryl that is N-conjugated directly to the pyridyl group; Y is a counterion; and n is an integer ranging from 5 to 100. The polymer of Formula (I) has a low LUMO value, and a high electron conductivity and air or oxygen stability. The present invention also relates to a method of synthesizing said polymer, and the use of said polymer. In a preferred embodiment, 2,6-dibromo-N,N'-bis(2-ethylhexyl)-1,8:4,5- naphthalene tetracarboxdiimide was reacted with 4,4'-bipyridine to form a conjugated polyviologen derivative in which the viologen unit covalently linked directly to an aromatic electron acceptor via the nitrogen atoms.