2-perfluorohexylethyl ether | 78522-74-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-perfluorohexylethyl ether
• 英文别名: BIS(1,1,2,2-tetrahydroperfluorooctyl) ether；1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctoxy)octane
• CAS: 78522-74-4
• 化学式: C₁₆H₈F₂₆O
• 分子量: 710.197
• InChiKey: LMDVXEYWUKBXOF-UHFFFAOYSA-N

物化性质

• 沸点：
  266.1±40.0 °C(Predicted)
• 密度：
  1.609±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  43
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  27

反应信息

• 作为产物：
  描述：

  1-碘-1H,1H,2H,2H-全氟辛烷 在 solution aqueuse de soude 10 N 作用下， 反应 0.25h， 生成 2-perfluorohexylethyl ether
  参考文献：
  名称：

  全氟烷磺酸的氧化阳极碘氟氟烷。制备去新贵酯sulfoniques totalement fluoresř ˚F SO 3 R” ˚F一个longues CHAINES

  摘要：

  全氟化磺酸酯[R ˚F SO 3 R ' ˚F和fluorosulphates FSO 3 R' ˚F，很容易被iodoperfluoroalkanes的阳极氧化得到的R” ˚F我在全氟链烷磺酸类R ˚F SO 3 H（R ˚F CF 3，C 2 ˚F 5，C 4 F 9）和氟代硫酸。使用二碘化合物I（CF 2）4 I，可以选择性地获得单和二酯。这些酯的碱水解产生全氟化的羧酸化合物。多氟碘化物R'F CH 2 CH 2 I在类似条件下也会被氧化。讨论了电解反应的机理。

  DOI：

  10.1016/s0040-4020(01)92420-2

文献信息

• Methods for Making Functionalized Fluorinated Monomers, Fluorinated Monomers, and Compositions for Making the Same
  申请人：Etna-TEC, Ltd.

  公开号：US20180334417A1

  公开（公告）日：2018-11-22

  A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon,

  一种制备用于制备寡聚物和聚合物的官能化氟化单体的方法，可用于改善聚合物衍生系统（如涂层）的表面性能。制备官能化氟化单体的方法包括将至少一种氟化亲核试剂（如氟化醇）与至少一种含有至少一个环氧基团的化合物反应。其他方法包括将氟化醇与环状羧酸酐反应。在另一实施例中，一种方法包括将氟化甲磺酸酯、对甲苯磺酸酯或三氟甲烷磺酸酯与胺、烷氧基或苯氧基反应。在其他实施例中，该方法包括将氟化醇与烷基卤化物反应，或将氟化烷基卤化物与胺反应。这些官能化氟化单体可用作中间体，并可反应以修改其上的官能基团。此外，这些官能化氟化单体可用于与聚合物或寡聚物反应，或与具有官能基团的聚合物或寡聚物反应，通过其上的官能基团修改聚合物或寡聚物。
• Pattern forming method as well as production methods for processed substrate, optical component, circuit board, electronic component and imprint mold
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10829644B2

  公开（公告）日：2020-11-10

  A pattern is formed on a substrate with forming a layer of a curable composition (A1) containing a component (a1) serving as a polymerizable compound and a component (e1) on a surface of the substrate, then dispensing droplets of a curable composition (A2) containing at least a component (a2) serving as a polymerizable compound dropwise discretely onto the layer of the curable composition (A1), subsequently sandwiching a mixture layer of the curable composition (A1) and the curable composition (A2) between a mold and the substrate, then irradiating the mixture layer with light to cure the layer, and releasing the mold from the mixture layer after the curing, a surface tension of a composition of components of the curable composition (A1) except a solvent being higher than a surface tension a composition of components of the curable composition (A2) except a solvent.

  在基底上形成图案的方法是：在基底表面形成一层含有可聚合化合物成分（a1）和成分（e1）的可固化组合物（A1），然后将至少含有可聚合化合物成分（a2）的可固化组合物（A2）液滴分散地滴在可固化组合物（A1）层上、随后将可固化组合物（A1）和可固化组合物（A2）的混合物层夹在模具和基底之间，然后用光照射混合物层以固化该层，固化后将模具从混合物层中取出，可固化组合物（A1）中除溶剂外的成分的表面张力高于可固化组合物（A2）中除溶剂外的成分的表面张力。
• PATTERN FORMING METHOD AS WELL AS PRODUCTION METHODS FOR PROCESSED SUBSTRATE, OPTICAL COMPONENT, CIRCUIT BOARD, ELECTRONIC COMPONENT AND IMPRINT MOLD
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170283620A1

  公开（公告）日：2017-10-05

  A pattern is formed on a substrate with forming a layer of a curable composition (A1) containing a component (a1) serving as a polymerizable compound and a component (e1) on a surface of the substrate, then dispensing droplets of a curable composition (A2) containing at least a component (a2) serving as a polymerizable compound dropwise discretely onto the layer of the curable composition (A1), subsequently sandwiching a mixture layer of the curable composition (A1) and the curable composition (A2) between a mold and the substrate, then irradiating the mixture layer with light to cure the layer, and releasing the mold from the mixture layer after the curing, a surface tension of a composition of components of the curable composition (A1) except a solvent being higher than a surface tension a composition of components of the curable composition (A2) except a solvent.
• US6039766A
  申请人：——

  公开号：US6039766A

  公开（公告）日：2000-03-21
• Oxydation anodique de iodoperfluoroalcanes dans les acides perfluoroalcanesulfoniques. Preparation de nouveaux esters sulfoniques totalement fluores RFSO3R'F a longues chaines
  作者：A. Germain、A. Commeyras

  DOI：10.1016/s0040-4020(01)92420-2

  日期：1981.1

  perfluoroalkane sulphonic acids RFSO3H (RF  CF3, C2F5, C4F9) and fluorosulphuric acid. With di-iodo compound I(CF2)4I, the mono and the diester can be selectively obtained. The alkaline hydrolysis of these esters produces perfluorinated carboxylic compounds. Polyfluorinated iodide R'FCH2CH2I are also oxidized in similar conditions. The mechanism of the electrolytic reaction is discussed.

  全氟化磺酸酯[R ˚F SO 3 R ' ˚F和fluorosulphates FSO 3 R' ˚F，很容易被iodoperfluoroalkanes的阳极氧化得到的R” ˚F我在全氟链烷磺酸类R ˚F SO 3 H（R ˚F CF 3，C 2 ˚F 5，C 4 F 9）和氟代硫酸。使用二碘化合物I（CF 2）4 I，可以选择性地获得单和二酯。这些酯的碱水解产生全氟化的羧酸化合物。多氟碘化物R'F CH 2 CH 2 I在类似条件下也会被氧化。讨论了电解反应的机理。