isobutyl trifluoroacetate | 17355-83-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: isobutyl trifluoroacetate
• 英文别名: isobutyl triflate；Trifluoressigsaeure-isobutylester；Isobutyl-trifluoracetat；Isobutyltrifluoracetat；2-methylpropyl 2,2,2-trifluoroacetate
• CAS: 17355-83-8
• 化学式: C₆H₉F₃O₂
• 分子量: 170.131
• InChiKey: JNDIDDMPBOLGER-UHFFFAOYSA-N

物化性质

• 沸点：
  102.5±35.0 °C(Predicted)
• 密度：
  1.150±0.06 g/cm3(Predicted)
• 保留指数：
  625.4

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  isobutyl trifluoroacetate 在 三氟化溴 作用下， 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 2.0h， 以47%的产率得到2-fluoro-2-methylpropyl trifluoroaetate
  参考文献：
  名称：

  Boguslavskaya, L. S.; Kartashov, A. V.; Chuvatkin, N. N., Journal of Organic Chemistry USSR (English Translation), 1989, vol. 25, # 9.2, p. 1835 - 1836

  摘要：

  DOI：
• 作为产物：
  描述：

  异丁醇 、 三氟乙酸酐 生成 isobutyl trifluoroacetate
  参考文献：
  名称：

  Characterization of Functional Groups by Nuclear Magnetic Resonance. I. Classification of Alcohols from the Fluorine-19 Spectra of Trifluoroacetates¹

  摘要：

  DOI：

  10.1021/ja00958a046

文献信息

• Homogeneous catalytic oxidation of light alkanes: C-C bond cleavage under mild conditions
  作者：E. G. Chepaikin、A. P. Bezruchenko、G. N. Menchikova、N. I. Moiseeva、A. E. Gekhman

  DOI：10.1134/s0023158410050071

  日期：2010.10

  The combined oxidation of CO and C2–C4 alkanes (associated petroleum gas and natural gas components) under the action of oxygen in trifluoroacetic acid solutions in the presence of rhodium and copper chlorides was accompanied by the oxidative degradation of C-C bonds in a hydrocarbon chain with the formation of carbonyl compounds, alcohols, and esters. For butane and isobutane, the reaction path with

  在铑和氯化铜存在下，三氟乙酸溶液中的氧气作用下，CO和C 2 -C 4烷烃（伴生气的石油和天然气成分）的联合氧化伴随着烃中CC键的氧化降解与羰基化合物，醇和酯形成链。对于丁烷和异丁烷，具有CC键断裂的反应路径是主要的。异丁烷氧化产物的生成曲线（具有保留和链的降解）均为S形，并具有相同的诱导期。他们没有通过最大。提出了反应方案以反映O 2中发生的转化机理的主要特点/铑/铜/氯-氧化系统。
• COATING COMPOSITION AND PRODUCTION METHOD FOR SAME, AND FORMATION METHOD FOR COATING FILM USING SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP2559742A1

  公开（公告）日：2013-02-20

  To provide a coating composition containing a fluorinated copolymer having repeating units derived from ethylene and tetrafluoroethylene, which can be formed into a coating film by coating and which can be produced at a relatively low temperature, and a process for its production, and a process for forming a coating film of the fluorinated copolymer by using this composition, which can be carried out at a relatively low temperature. A coating composition comprising microparticles of a fluorinated copolymer (ETFE) having repeating units derived from ethylene and repeating units derived from tetrafluoroethylene, and a solvent capable of dissolving ETFE at a temperature of not higher than the melting point of ETFE, wherein the microparticles of ETFE are microparticles precipitated from a solution having ETFE dissolved in the solvent, and are dispersed in the solvent.

  提供一种含有含氟共聚物的涂层组合物，该共聚物具有来自乙烯和四氟乙烯的重复单元，可以通过涂覆形成涂膜，并且可以在相对较低的温度下生产，还提供一种生产该组合物的工艺，以及一种使用该组合物形成含氟共聚物涂膜的工艺，该工艺可以在相对较低的温度下进行。一种涂料组合物，它包含氟化共聚物（ETFE）的微粒，该共聚物具有来自乙烯的重复单元和来自四氟乙烯的重复单元，以及能够在不高于 ETFE 熔点的温度下溶解 ETFE 的溶剂，其中 ETFE 的微粒是从溶解有 ETFE 的溶液中析出的微粒，并分散在溶剂中。
• CHARGE RETENTION MEDIUM
  申请人：Asahi Glass Company, Limited

  公开号：EP2648196A1

  公开（公告）日：2013-10-09

  To provide a charge retention medium having a surface potential at a practical level, although it is obtained from a composition containing a fluorinated copolymer having repeating units based on tetrafluoroethylene and repeating units based on ethylene. A charge retention medium (electret 30) which is obtained from a composition containing a fluorinated copolymer (A) having repeating units based on tetrafluoroethylene and repeating units based on ethylene; and at least one charge aid (B) selected from the group consisting of a compound having at least one amino group and at least one reactive functional group (excluding an amino group) and a compound having at least two amino groups and having no reactive functional group (excluding an amino group).

  提供一种电荷保持介质，尽管它是由一种含有氟化共聚物的组合物获得的，该共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元，但它的表面电位达到实用水平。 一种电荷保持介质（驻极体 30），由含有氟化共聚物（A）的组合物获得，该共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元；以及至少一种电荷助剂（B），该助剂选自具有至少一个氨基和至少一个反应性官能团（不包括氨基）的化合物和具有至少两个氨基且不具有反应性官能团（不包括氨基）的化合物组成的组。
• METHOD FOR PRODUCING CHARGE RETENTION MEDIUM
  申请人：Asahi Glass Company, Limited

  公开号：EP2648197A1

  公开（公告）日：2013-10-09

  To provide a process for producing a charge retention medium, with which a coating film (precursor of a charge retention medium) containing a fluorinated copolymer having repeating units based on tetrafluoroethylene and repeating units based on ethylene can easily be formed on the surface of a substrate, even in a case where the surface of the substrate has a complicated shape. A process for producing a charge retention medium (electret 30), which comprises a step of applying a coating composition containing a fluorinated copolymer (A) having repeating units based on tetrafluoroethylene and repeating units based on ethylene, and an organic solvent (C), to a substrate (first substrate 10) to form a coating film.

  提供一种电荷保持介质的生产工艺，通过该工艺，即使在基材表面形状复杂的情况下，也能容易地在基材表面形成含有氟化共聚物的涂膜（电荷保持介质的前体），该氟化共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元。 一种电荷保持介质（驻极体 30）的生产工艺，包括将含有氟化共聚物（A）的涂层组合物（A）（A）具有基于四氟乙烯的重复单元和基于乙烯的重复单元）和有机溶剂（C）涂敷到基底（第一基底 10）上以形成涂膜的步骤。
• A new “one-pot” conversion of trifluoroacetic ester to α-fluoro-β-trifluoromethyl-β-alkoxy-vinylphosphonates
  作者：Yanchang Shen、Yuming Zhang

  DOI：10.1016/s0022-1139(00)00404-8

  日期：2001.3

  A new ''one-pot'' conversion of trifluoroacetic esters to alpha -fluoro-beta -trifluoromethyl-beta -alkoxy-vinylphosphonates can be achieved in a process of sequential transformations. (C) 2001 Elsevier Science B.V. All rights reserved.

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