氯磷酰腈 | 1832-07-1

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 中文名称: 氯磷酰腈
• 中文别名: 氯二氧磷基腈
• 英文名称: poly(dichlorophosphazene)
• 英文别名: (NPCl2)n；[NPCl2]n；phosphonitrile dichloride；Phosphonitrile chloride；azanylidyne(dichloro)-λ5-phosphane
• CAS: 1832-07-1
• 化学式: Cl₂NP
• 分子量: 115.886
• InChiKey: UXJHQBVRZUANLK-UHFFFAOYSA-N

物化性质

• 沸点：
  135-140 °C(Press: 17 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  2.26
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  triethylamine tris(hydrogen fluoride) 、 氯磷酰腈 在 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到poly(difluorophosphazene)
  参考文献：
  名称：

  Loewe, C.; Riesel, L., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  六氯环三磷腈 在 [N3P3Cl6SiEt3][HCB11H5Br6] Et₃Si(CHB₁₁H₅Br₆) 作用下， 以 further solvent(s) 为溶剂， 生成 氯磷酰腈
  参考文献：
  名称：

  甲硅烷基离子催化的环氯磷腈三聚体[N（3）P（3）Cl（6）]的环境温度开环聚合（ROP）。

  摘要：

  通过使用三烷基甲硅烷基碳硼烷[R（3）Si（CHB（11）X（11）]作为催化剂，可以大大降低环N（3）P（3）Cl（6）开环聚合所需的温度。

  DOI：

  10.1039/b713933k

文献信息

• Synthesis and spectroscopic characterization of cyclic and polymeric phosphazenes bearing phosphine complexes
  作者：Gabino A Carriedo、Francisco J Garcı́a Alonso、Pedro A González、Carlos Dı́az Valenzuela、Nicolás Yutronic Sáez

  DOI：10.1016/s0277-5387(02)01233-0

  日期：2002.12

  The reactions of the cyclic phosphazenes [N3P3Cl6] and [N3P3(O2Cl2H8)(2)Cl-2] (O2Cl2H8 = 2,2'-dioxybiphenyl) with the diphenylphosphine phenol complex Mn(CO)(2)(eta(5)-C5H4Me)[PPh2(C6H4-OH)]} (1) and Cs2CO3 in refluxing acetone gave, respectively the phosphazenc-phosphine complexes N3P3[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](6)} (2) and N3P3(o(2)Cl(2)H(8))(2)[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](2)} (3). in good yields. The analogous reaction of the partially substituted clorophosphazene polymer [NP(O2Cl2H8)](0.6)[NPCl2](0.4)}(n) in THF gave the polymeric complex [NP(O2Cl2H8)}(0.6)NP[OC6H4PPh2-Mn(CO)(2)(eta(5)- C5H4Me)](2)}(0.4)-0.5[OC4H8](n) (4). Different spectroscopic data are provided for the new compounds that may be useful for the characterization of other more complex polymeric materials. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Direct synthesis of cyclic and polymeric phosphazenes bearing diphenylphosphine groups and their complexes with [W(CO)5] fragments
  作者：Gabino A. Carriedo、Francisco J. Garcı́a Alonso、Pedro A. González、Paloma Gómez-Elipe

  DOI：10.1016/s0277-5387(99)00194-1

  日期：1999.9

  The reactions of the cyclotriphosphazenes [N3P3Cl6] or [N3P3(O2C12H8)(2)Cl-2] with the phenolic phosphine PPh2(C6H4-OH) in the presence of Cs2CO3 give, respectively, the cyclic phosphazene phosphines [N3P3(OC6H4PPh2)(6)] (1) and [N3P3(O2C12H8)(2)(OC6H4PPh2)(2)] (2), very pure and in high yield. The similar reaction with the linear polyphosphazene [NP(O2C12H8)](0.65) [NPCl2](0.35)}(n) in THF gives the diphenylphosphine polymer [NP(O2C12H8)](0.65)[NP(OC6H4PPh2)(2)]0.35}(n) (3). The phenolic tungsten pentacarbonyl complex W(CO)(5)[PPh2(C6H4-OH)]} reacts in the same way with those cyclic and polymeric phosphazenes to give the corresponding complexes N3P3[OC6H4PPh2-W(CO)(5)](6)} (4), [N3P3(O2C12H8)(2)(OC6H4PPh2-W(CO)(5))(2)] (5), and [NP(O2C12H8)](0.65)[NP(OC6H4PPh2-W(CO)(5))(2)](0.35)}(n) (6). (C) 1999 Elsevier Science Ltd. All rights reserved.
• Blackstone, Vivienne; Lough, Alan J.; Murray, Martin, Journal of the American Chemical Society, 2009, vol. 131, p. 3658 - 3667
  作者：Blackstone, Vivienne、Lough, Alan J.、Murray, Martin、Manners, Ian

  DOI：——

  日期：——
• Effect of a neighboring group in alcoholysis reactions of polydichlorophosphazene
  作者：D. R. Tur、V. V. Korshak、S. V. Vinogradova、N. P. Provotorova、P. V. Petrovskii

  DOI：10.1007/bf00962001

  日期：1987.10
• Allcock, Harry R.; Desorcie, James L.; Steven Rutt, Organometallics, 1988, vol. 7, # 3, p. 612 - 619
  作者：Allcock, Harry R.、Desorcie, James L.、Steven Rutt

  DOI：——

  日期：——