羟铵氟化物 | 17256-78-9

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 中文名称: 羟铵氟化物
• 英文名称: hydroxylammonium fluoride
• 英文别名: hydron;hydroxylamine;fluoride
• CAS: 17256-78-9
• 化学式: F*H₄NO
• 分子量: 53.0363
• InChiKey: UNFDKMXBKPSFIJ-UHFFFAOYSA-N

物化性质

• 熔点：
  90 °C (decomp)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.51
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.2
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  铀(VI)氟化物 、 羟铵氟化物 以 氢氟酸 为溶剂， 生成
  参考文献：
  名称：

  Hydrazinium (+2) and hydroxylammonium hexafluorouranates (v)

  摘要：

  DOI：

  10.1021/ic50058a023
• 作为产物：
  描述：

  氢氟酸 、 盐酸羟胺 在 sodium ethanolate 作用下， 以 水 为溶剂， 生成 羟铵氟化物
  参考文献：
  名称：

  Dojer, Brina; Kristl, Matja; Jaglicic, Zvonko, Acta Chimica Slovenica, 2012, vol. 59, # 4, p. 789 - 794

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.C8, 5.2.3, page 219 - 240
  作者：

  DOI：——

  日期：——
• Titova, K. V.; Loginova, E. N., Russian Journal of Inorganic Chemistry, 1995, vol. 40, p. 1714 - 1720
  作者：Titova, K. V.、Loginova, E. N.

  DOI：——

  日期：——
• Titova, K. V.; Kolmakova, E. I.; Rosolovskii, V. Ya., Russian Journal of Inorganic Chemistry, 1978, vol. 23, p. 634 - 636
  作者：Titova, K. V.、Kolmakova, E. I.、Rosolovskii, V. Ya.

  DOI：——

  日期：——
• Synthesis and characterization of new hydroxylammonium fluoromanganates and fluoroscandates
  作者：Matjaž Kristl、Brina Dojer、Nuša Hojnik、Amalija Golobič

  DOI：10.1016/j.jfluchem.2014.07.006

  日期：2014.10

  New hydroxylammonium fluorometallates of manganese and scandium, with the formulas (NH3OH)(2)MnF4 and (NH3OH)(3)ScF6, were prepared by the reactions of hydroxylammonium fluoride with solutions of manganese or scandium in aqueous HF. (NH3OH)(2)MnF4 crystallizes monoclinic, P2(1)/c, the structure consisting of MnF6 octahedra sharing four of its vertices, resulting in [MnF42-](n) anionic layers perpendicular to a axis. (NH3OH)(3)ScF6 crystallizes trigonal, R3c, and the structure is made up of isolated ScF6 octahedra, stacked in columns along c axis and surrounded by a cylinder of hydroxylammonium cations. Both title compounds decompose during thermal analysis in several steps, yielding corresponding fluorides (MnF2 and ScF3) at temperatures between 300 and 400 degrees C and oxides/oxofluorides at higher temperatures. (C) 2014 Elsevier B.V. All rights reserved.
• Hydroxylammonium fluorogermanates
  作者：Irena Ban、Matjaž Kristl、Miha Drofenik、Arkadij Popovič

  DOI：10.1016/j.tca.2004.02.016

  日期：2004.9

  A new hydroxylammonium compound (NH3OH)(2)GeF6, has been synthesized by the addition of solid NH3OHF to a solution of GeO2 dissolved in 20% HE The compound was characterized by chemical analysis and X-ray powder diffraction, the thermal decomposition was studied by thermal analysis and mass spectrometry. (NH3OH)(2)GeF6 crystallizes monoclinic. Two endothermic and two exothermic peaks have been observed on the DSC curve, the decomposition product at 500 degreesC is GeO2. (C) 2004 Elsevier B.V. All rights reserved.