12-crown-4 | 295-89-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 12-crown-4
• 英文别名: 16-crown-4；1,5,9,13-tetraoxa-cyclohexadecane；1,5,9,13-Tetraoxa-cyclohexadecan；1,5,9,13-Tetraoxacyclohexadecan；Tetraoxa-cyclohexadecan；1,5,9,13-Tetraoxacyclohexadecane
• CAS: 295-89-6
• 化学式: C₁₂H₂₄O₄
• 分子量: 232.32
• InChiKey: QNTPNTFBQZBRCK-UHFFFAOYSA-N

物化性质

• 沸点：
  357.1±27.0 °C(Predicted)
• 密度：
  0.936±0.06 g/cm3(Predicted)
• 熔点：
  70 °C

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三甲氧基酯 在 三氟化硼 作用下， 生成 12-crown-4
  参考文献：
  名称：

  111.氧杂环丁烷的阳离子聚合。第一部分

  摘要：

  DOI：

  10.1039/jr9560000542

文献信息

• Molecular Design of Crown Ethers. VII. Syntheses and Cation Selectivities of Unsubstituted 12- to 16-Crown-4
  作者：Yu Liu、Yoshihisa Inoue、Tadao Hakushi

  DOI：10.1246/bcsj.63.3044

  日期：1990.10

  Solvent extraction of aqueous alkali and some heavy metal picrates with the title compounds showed that, with most cations except for Li+, Na+, and Ag+, the extractability decreases monotonically as the ring size increases from 12 to 16. However, 14-crown-4 showed the highest extractability and selectivity for Li+ over the larger alkali metals, while 15-crown-4 exhibited the highest Ag+/TI+ selectivity

  用标题化合物对碱水溶液和一些重金属苦味酸盐进行溶剂萃取表明，对于除 Li+、Na+ 和 Ag+ 外的大多数阳离子，随着环尺寸从 12 增加到 16，萃取率单调下降。 然而，14-crown-4与较大的碱金属相比，Li+ 的可萃取性和选择性最高，而 15-crown-4 的 Ag+/TI+ 选择性最高。
• 1,5,9-Trioxacyclododecane and 3,3,7,7,11,11-hexamethyl-1,5,9-trioxacyclododecane: novel lithium cation complexing agents
  作者：Johannes Dale、Jan Eggestad、Siw B. Fredriksen、Per Groth

  DOI：10.1039/c39870001391

  日期：——

  derivative, obtained in good yield from oxetane and from 3,3-dimethyloxetane, give stronger complexation than the corresponding 16-crown-4 ligands, and the high selectivity for lithium as compared with sodium and magnesium is retained for Me6-12-crown-3, but is lost for 12-crown-3 owing to the formation of sandwich complexes; X-ray crystal structures are reported for 12-crown-3·LiNCS, Me6-12-crown-3·LiClO4

  由氧杂环丁烷和3,3-二甲基氧杂环丁烷获得的高收率的12-Crown-3及其六甲基衍生物比相应的16-Crown-4配体具有更强的络合性，与钠和镁相比，对锂的高选择性为保留给我6 -12-crown-3，但由于形成三明治复合物而失去给12-crown-3；报告了12-冠-3·LiNCS，Me 6 -12-冠-3·LiClO 4和Me 6 -12-冠-3的X射线晶体结构。
• Cyclic compounds and their use as complex ligands
  申请人：Tauer Erich

  公开号：US20050159596A1

  公开（公告）日：2005-07-21

  A cyclic compound of the general formula (I) where X-Y-Z is N═C—O, NH—C═N or N═C—NH and R 1 , R 2 and R 3 are each H or C 1-6 -alkyl and of the general formula (III) where X-Y-Z is N═C—O and R 1 , R 2 and R 3 are each H or C 1-6 -alkyl, may be used as complexing ligands.

  通式为(I)的环状化合物，其中X-Y-Z为N═C—O、NH—C═N或N═C—NH，且R1、R2和R3均为H或C1-6-烷基；以及通式为(III)的化合物，其中X-Y-Z为N═C—O，且R1、R2和R3均为H或C1-6-烷基，可以用作配位配体。
• Dale, Johannes; Fredriksen, Siw B., Acta Chemica Scandinavica, 1991, vol. 45, # 1, p. 82 - 91
  作者：Dale, Johannes、Fredriksen, Siw B.

  DOI：——

  日期：——
• PATTERN FORMING METHOD, COMPOSITION FOR FORMING PROTECTIVE FILM, METHOD FOR MANUFACTURING ELECTRONIC DEVICE, AND ELECTRONIC DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20170176862A1

  公开（公告）日：2017-06-22

  A pattern forming method includes coating an actinic ray-sensitive or radiation-sensitive resin composition onto a substrate to form an actinic ray-sensitive or radiation-sensitive film, coating a composition for forming a protective film onto the actinic ray-sensitive or radiation-sensitive film to form a protective film, exposing the actinic ray-sensitive or radiation-sensitive film covered with the protective film, and developing the exposed actinic ray-sensitive or radiation-sensitive film using a developer containing an organic solvent, in which the protective film contains a compound (A) including at least one group or bond selected from the group consisting of an ether bond, a thioether bond, a hydroxyl group, a thiol group, a carbonyl bond, and an ester bond, and a resin (X).