sec-butyl (Z)-7-tetradecenoate | 83005-39-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: sec-butyl (Z)-7-tetradecenoate
• 英文别名: sec.butyl (Z)-7-tetradecenoate；2-butyl (7Z)-tetradecenoate；butan-2-yl (Z)-tetradec-7-enoate
• CAS: 83005-39-4
• 化学式: C₁₈H₃₄O₂
• 分子量: 282.467
• InChiKey: RBSDKFRRNIJFNR-KHPPLWFESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  20
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sec-butyl (Z)-7-tetradecenoate 在 四氧化锇 、 硫化氢 作用下， 生成
  参考文献：
  名称：

  Sec-butyl (Z)-7-tetradecenoate. A novel sex pheromone component from the western grapeleaf skeletonizer, harrsina brillians.

  摘要：

  DOI：

  10.1016/s0040-4039(00)87450-x
• 作为产物：
  描述：

  6-溴正己醇 在 Lindlar's catalyst 吡啶 、 jones' reagent 、 草酰氯 、 氢气 、 氢气 、 N,N-二甲基甲酰胺 作用下， 以 甲醇 、 正己烷 、 二氯甲烷 、 丙酮 为溶剂， 生成 sec-butyl (Z)-7-tetradecenoate
  参考文献：
  名称：

  摘要：

  The sex pheromone of the vine bud moth, Theresimima ampellophaga, released at the 3rd-5th abdominal tergites, was identified by coupled GC-EAG, GC-MS, and synthesis as (2S)-butyl (7Z)-tetradecenoate. For the first time, full stereochemistry is unambiguously defined for the sex pheromone of a member of the Zygaenidae. The synthetic compound caught significant numbers of males in field-trapping experiments.

  DOI：

  10.1023/a:1022438717287

文献信息

• Sec-butyl (Z)-7-tetradecenoate and its use as a sex attractant for the
  申请人：The United States of America as represented by the Secretary of

  公开号：US04563348A1

  公开（公告）日：1986-01-07

  A pheromonal compound produced by the western grapeleaf skeletonizer has been identified as sec-butyl (Z)-7-tetradecenoate. The synthetically-prepared compound demonstrates activity toward both the western grapeleaf skeletonizer, Harrisina brillians Barnes and McDunnough and the grapeleaf skeletonizer, Harrisina americana (Guerin). By attracting adult moths to field traps, this compound offers a useful tool in monitoring and control of this pest.

  一种由西方葡萄叶骨架虫产生的信息素化合物已被鉴定为sec-butyl (Z)-7-tetradecenoate。这种合成制备的化合物对西方葡萄叶骨架虫和葡萄叶骨架虫都具有活性。通过吸引成虫到田间陷阱，这种化合物为监测和控制这种害虫提供了有用的工具。
• Subramanian, G. B. V.; Sharma, Rajiv, Synthetic Communications, 1989, vol. 19, # 7,8, p. 1197 - 1202
  作者：Subramanian, G. B. V.、Sharma, Rajiv

  DOI：——

  日期：——
• SUBRAMANIAN, G. B. V.;SHARMA, RAJIV, SYNTH. COMMUN., 19,(1989) N-8, C. 1197-1202
  作者：SUBRAMANIAN, G. B. V.、SHARMA, RAJIV

  DOI：——

  日期：——
• SODERSTROM, E. L.;HADDON, W. F.;MYERSON, J.
  作者：SODERSTROM, E. L.、HADDON, W. F.、MYERSON, J.

  DOI：——

  日期：——
• ——
  作者：M. Subchev、A. Harizanov、W. Francke、S. Franke、E. Plass、A. Reckziegel、F. Schröder、J. A. Pickett、L. J. Wadhams、C. M. Woodcock

  DOI：10.1023/a:1022438717287

  日期：——

  The sex pheromone of the vine bud moth, Theresimima ampellophaga, released at the 3rd-5th abdominal tergites, was identified by coupled GC-EAG, GC-MS, and synthesis as (2S)-butyl (7Z)-tetradecenoate. For the first time, full stereochemistry is unambiguously defined for the sex pheromone of a member of the Zygaenidae. The synthetic compound caught significant numbers of males in field-trapping experiments.