5,5-dimethyl-3-N-(piperidine)cyclohex-2-en-1-one | 13358-76-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,5-dimethyl-3-N-(piperidine)cyclohex-2-en-1-one
• 英文别名: 5,5-dimethyl-3-(piperidin-1-yl)cyclohex-2-enone；3-piperidino-5,5-dimethylcyclohex-2-en-1-one；5,5-dimethyl-3-piperidino-2-cyclohexen-1-one；5,5-dimethyl-3-piperidinocyclohex-2-en-1-one；5,5-dimethyl-3-piperidin-1-yl-cyclohex-2-enone；5,5-Dimethyl-3-piperidinyl-cyclohex-2-en-1-one；5,5-Dimethyl-3-(piperidino)cyclohex-2-en-1-one；5,5-dimethyl-3-piperidin-1-ylcyclohex-2-en-1-one
• CAS: 13358-76-4
• 化学式: C₁₃H₂₁NO
• mdl: MFCD00551727
• 分子量: 207.316
• InChiKey: ZPOZHYJJQWTDJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.769
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 5,5-dimethyl-3-N-(piperidine)cyclohex-2-en-1-one 在 吗啉 、 盐酸 作用下， 以 甲醇 、 水 为溶剂， 反应 1.0h， 生成 3,3,6,6-tetramethyl-2,3,4,5,6,7,8,9-octahydro-1H-xanthene-1,8-dione
  参考文献：
  名称：

  Moehrle; Herbke, Pharmazie, 1980, vol. 35, # 5-6, p. 288 - 293

  摘要：

  DOI：
• 作为产物：
  描述：

  5,5-dimethyl-3-piperidino-2-trifluoroacetylcyclohex-2-en-1-one 在 三乙基硅烷 、 lithium perchlorate 作用下， 以 三氟乙酸 为溶剂， 反应 5.0h， 生成 5,5-dimethyl-3-N-(piperidine)cyclohex-2-en-1-one
  参考文献：
  名称：

  Regioselective reduction of 2-perfluoroalkanoylcyclohexane-1,3-diones and their enamino derivatives

  摘要：

  Ionic hydrogenation of 2-perfluoroalkanoylcyclohexane-1,3-diones and their endocyclic enamino derivatives containing a secondary amino group by the action of triethylsilane in trifluoroacetic acid in the presence of a catalytic amount of lithium perchlorate involved regioselective reduction of the side-chain carbonyl group to hydroxy with formation of the corresponding hydroxy diketones and hydroxy amino ketones, respectively. Under analogous conditions endocyclic enamino derivatives possessing a tertiary amino group underwent deacylation to give enamino ketones.

  DOI：

  10.1134/s1070363211040098

文献信息

• Synthesis, spectral and structural characterization of cobalt(III) dithiocarbamato complexes: Catalytic application for the solvent free enamination reaction
  作者：Pooja Bharati、A. Bharti、P. Nath、M.K. Bharty、R.J. Butcher、N.K. Singh

  DOI：10.1016/j.poly.2015.10.007

  日期：2015.12

  using 1–2 mol% of the above cobalt(III) complexes as catalysts and these have been characterized by NMR, GC–MS and X-ray crystallography. Complexes 1, 2 and 3 are stabilized by intermolecular C–H⋯S interactions, leading to the formation of supramolecular architectures. Thermogravimetric analysis of complexes 1 and 2 have been investigated by TG-DTA, which indicate that cobalt sulfide is formed as the

  一些新的钴（III）配合物[Co（mpcdt）3 ]（1），[Co（ppcdt）3 ]（2）和[Co（mppcdt）3 ]·0.25CHCl的合成，光谱，结构和催化性能参照图3（3），已经描述了衍生自4-甲基哌嗪-1-碳二硫酸酯（mpcdt），4-苯基哌嗪-1-碳二硫酸酯（ppcdt）和4-（2-甲氧基苯基）哌嗪-1-碳二硫代酸酯（mppcdt）。使用1–2 mol％的上述钴（III）配合物，通过β-酮酸酯和1,3-二酮与脂肪族和芳香族胺的反应，可以得到约90％的产率的一系列β-烯胺酯和β-烯酮。催化剂，并已通过NMR，GC-MS和X射线晶体学进行了表征。复合体1，2和3是通过分子间C-H⋯小号相互作用来稳定，导致超分子结构的形成。通过TG-DTA研究了配合物1和2的热重分析，结果表明形成了硫化钴作为最终产物。
• Polymerization process with living characteristics and polymers made therefrom
  申请人：——

  公开号：US20040024132A1

  公开（公告）日：2004-02-05

  A free radical polymerization process suitable for synthesizingpolymers is disclosed. The process utilizes novel sulfur based chain transfer agents and is widely compatible over a range of monomers and reaction conditions. Novel polymers having low polydispersity and predictable specific polymer architecture amd molecular weight are produced by the process. The polymers produced by the process are suitable for use as binders in automotive OEM and refinish coatings.

  本文披露了适用于合成聚合物的自由基聚合过程。该过程利用新型基于硫的链转移剂，并且在各种单体和反应条件下广泛兼容。该过程生产具有低聚分散度和可预测的特定聚合物结构和分子量的新型聚合物。该过程生产的聚合物适用于作为汽车OEM和修补涂料中的粘合剂。
• COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20220144769A1

  公开（公告）日：2022-05-12

  A compound represented by Formula (I) is provided: In Formula (I), R 3 , R 4 , and R 5 each independently represent an electron-withdrawing group; R 1 , R 2 , R 6 , and R 7 each independently represent a hydrogen atom, a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SCF 3 , —SF 5 , —SF 3 , —SO 3 H, —SO 2 H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent; and R 1 and R 2 , R 1 and R 6 , R 6 and R 7 , and R 4 and R 5 may be linked to each other to form a ring.

  提供一个由公式（I）表示的化合物： 在公式（I）中，R3，R4和R5分别代表一个电子吸引基团；R1，R2，R6和R7分别代表氢原子，杂环基团，卤素原子，硝基，氰基，羟基，硫醇基，羧基，-SCF3，-SF5，-SF3，-SO3H，-SO2H，具有1至25个碳原子的脂肪烃基团，可能具有取代基，或具有6至18个碳原子的芳香烃基团，可能具有取代基；R1和R2，R1和R6，R6和R7以及R4和R5可以相互连接形成环。
• Rao, T. Vedagiriswani; Ravishankar; Baskaran, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 6, p. 546 - 551
  作者：Rao, T. Vedagiriswani、Ravishankar、Baskaran、Trivedi

  DOI：——

  日期：——
• POLYMERIZATION PROCESS WITH LIVING CHARACTERISTICS AND POLYMERS MADE THEREFROM
  申请人：Commonwealth Scientific and Industrial Research Organisation

  公开号：EP1054906B2

  公开（公告）日：2013-04-10