ortho-isobornylphenol | 4518-00-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ortho-isobornylphenol
• 英文别名: 2-isobornylphenol；ortho-isobornyl-phenol；O-isobornylphenol；2-Isobornyl-phenol；2-(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)phenol
• CAS: 4518-00-7；51317-52-3；23658-96-0
• 化学式: C₁₆H₂₂O
• 分子量: 230.35
• InChiKey: XBIZMMUVXBULNU-UHFFFAOYSA-N

物化性质

• 熔点：
  77.8-78.6 °C
• 沸点：
  142-145 °C(Press: 1 Torr)
• 密度：
  1.042±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 ortho-isobornylphenol 在 三乙胺 作用下， 以 甲苯 为溶剂， 反应 15.0h， 以60%的产率得到2-hydroxy-3-(1,7,7-trimethylbiyclo[2.2.1]hept-exo-2-yl)benzaldehyde
  参考文献：
  名称：

  Separation of racemic salycylaldehydes containing isobornyl substituent using (R)-1-phenylethylamine

  摘要：

  Racemic salicylaldehydes containing isobornyl substituent were separated by their conversion into diastereomers by the reaction with (R)-1-phenylethylamine. The absolute configuration of the intermediate Schiff bases and separated aldehyde eneatiomers was established by XRD analysis.

  DOI：

  10.1134/s1070428010050088
• 作为产物：
  描述：

  莰烯 、 苯酚 在 H₃PW₁₂O₄₀/TiO₂ 作用下， 反应 2.0h， 生成 ortho-isobornylphenol 、 2-isocamphylphenol
  参考文献：
  名称：

  Alkylation of phenol with camphene in the presence of heteropolyacids supported on metal oxides

  摘要：

  Alkylation of phenol with camphene in the presence of supported heteropolyacids is studied. The main reaction products are found to be phenyl isobornyl ether, 2-isobornylphenol and 2-isocamphylphenol, the ratio between them being determined by the nature of heteropolyacid and carrier (ZrO2 or TiO2).

  DOI：

  10.1134/s0036024413020246

文献信息

• Structure—hemolytic activity relationship in isobornylphenol derivatives
  作者：O. G. Shevchenko、S. N. Plyusnina、E. V. Buravlev、I. Yu. Chukicheva、I. V. Fedorova、O. V. Shchukina、A. V. Kutchin

  DOI：10.1007/s11172-017-1962-x

  日期：2017.10

  A structure — hemolytic activity relationship in isobornylphenol derivatives was analysed. The morphological transformation of erythrocytes under the influence of some representatives of this class of compounds was demonstrated by scanning electron microscopy. The hemolytic activity of the test compounds can vary within wide limits, depending on the structure and position of substituents determining

  分析了异冰片基酚衍生物的结构-溶血活性关系。通过扫描电子显微镜证实了在此类化合物的一些代表的影响下红细胞的形态转变。受试化合物的溶血活性可以在很宽的范围内变化，这取决于决定化合物与细胞膜相互作用性质的取代基的结构和位置。
• Terpenophenols
  申请人：Societe Anonyme dite: MAR-PHA, Societe d'Etude et d'Exploitation de

  公开号：US04067899A1

  公开（公告）日：1978-01-10

  New terpenophenols of the general formula: ##STR1## wherein R is a 2-isobornyl, 5-camphyl or 2-norbornyl group of exo or endo configuration and in the ortho, meta or para position with respect to the OH group; R.sub.1, R.sub.2 may each be a hydrogen atom or halogen atom (Cl, Br, F, I) or a lower alkyl or lower alkoxy radical having a straight or branched chain of 1 to 4 carbon atoms or a nitro or cyano group.

  新的萜类酚化合物的通式为： ##STR1## 其中R是外向或内向构型的2-异邦基、5-樟脑基或2-去氢环己基，且在OH基的邻、间或对位；R.sub.1、R.sub.2可以是氢原子或卤素原子（Cl、Br、F、I）或1至4个碳原子的直链或支链低烷基或低烷氧基，或是硝基或氰基。
• Alkylation of phenol by β-pinene in the presence of aluminum phenolate
  作者：I. Yu. Chukicheva、O. A. Shumova、A. V. Kuchin

  DOI：10.1007/s10600-012-0154-z

  日期：2012.3

  The alkylation of phenol by β-pinene using Al(OPh)3 as a catalyst was studied. It was found that the composition of the products depended on the ratio of starting materials. The principal products were chromane-type ethers with an equimolar ratio of starting materials and an excess of phenol. ortho-Alkylated phenol and an ether with a terpene substituent of bornyl structure were formed with a two-fold

  以Al(OPh)3为催化剂，研究了β-蒎烯对苯酚的烷基化反应。发现产品的组成取决于原料的比例。主要产品是具有等摩尔比的起始原料和过量苯酚的色烷型醚。邻烷基化苯酚和具有冰片基结构萜烯取代基的醚与两倍过量的β-蒎烯形成。
• MODIFIED NANOCELLULOSE, AND RESIN COMPOSITION CONTAINING MODIFIED NANOCELLULOSE
  申请人：DIC CORPORATION

  公开号：US20150376298A1

  公开（公告）日：2015-12-31

  The present invention provides a novel modified nanocellulose suitable for surface modification of nanocellulose or introduction of functional groups into nanocellulose, and a resin composition comprising the modified nanocellulose. More specifically, the present invention provides a modified nanocellulose in which a portion of the hydroxyl groups of cellulose constituting nanocellulose is substituted with at least one substituent represented by formula (1), and a resin composition comprising the modified nanocellulose and a resin.

  本发明提供了一种新型的改性纳米纤维素，适用于表面改性纳米纤维素或将功能基团引入纳米纤维素，并包括改性纳米纤维素的树脂组成物。更具体地说，本发明提供了一种改性纳米纤维素，其中构成纳米纤维素的纤维素的一部分羟基被至少一个由式（1）表示的取代基所取代，以及包括改性纳米纤维素和树脂的树脂组成物。
• TRANSPARENT CONDUCTIVE INK, AND METHOD FOR PRODUCING TRANSPARENT CONDUCTIVE PATTERN
  申请人：Osaka University

  公开号：EP2843667A2

  公开（公告）日：2015-03-04

  Provided is a transparent conductive ink which contains metal nanowires and/or metal nanotubes as a conductive component and can form a coating film which has good conductivity and a high light transmittance property, and also provided is a transparent conductive pattern forming method wherein this transparent conductive ink is used for forming a transparent conductive pattern by simple production steps, to thereby suppress the production cost and environmental load. At least one of metal nanowires and metal nanotubes are dispersed in a dispersion medium containing a shape-holding material which contains an organic compound having a molecular weight in the range of 150 to 500 and which has a viscosity of 1.0×103 to 2.0×106 mPa·s at 25°C, to prepare a transparent conductive ink. A transparent conductive pattern is formed by printing a pattern having an arbitrary shape on a substrate using this transparent conductive ink, subjecting the pattern to a heating treatment to dry the pattern, and subjecting the pattern which has been dried to pulsed light irradiation.

  本发明提供了一种透明导电墨水，该墨水含有金属纳米线和/或金属纳米管作为导电成分，可形成具有良好导电性和高透光性的涂膜；还提供了一种透明导电图案形成方法，其中使用该透明导电墨水可通过简单的生产步骤形成透明导电图案，从而降低生产成本和环境负荷。将金属纳米线和金属纳米管中的至少一种分散在含有形状保持材料的分散介质中，该形状保持材料含有一种有机化合物，其分子量在 150 至 500 之间，在 25°C 时的粘度为 1.0×103 至 2.0×106 mPa-s，以制备透明导电墨水。使用这种透明导电油墨在基板上印刷任意形状的图案，然后对图案进行加热处理使其干燥，再对干燥后的图案进行脉冲光照射，从而形成透明导电图案。