2-isocamphylphenol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-isocamphylphenol
• 英文别名: ortho-isocamphylphenol；2-(5,5,6-Trimethylbicyclo[2.2.1]hept-2-yl)phenol；2-(5,5,6-trimethyl-2-bicyclo[2.2.1]heptanyl)phenol
• 化学式: C₁₆H₂₂O
• 分子量: 230.35
• InChiKey: RJZHQMOKFMOSQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  莰烯 、 苯酚 在 H₃PW₁₂O₄₀/TiO₂ 作用下， 反应 2.0h， 生成 ortho-isobornylphenol 、 2-isocamphylphenol
  参考文献：
  名称：

  Alkylation of phenol with camphene in the presence of heteropolyacids supported on metal oxides

  摘要：

  Alkylation of phenol with camphene in the presence of supported heteropolyacids is studied. The main reaction products are found to be phenyl isobornyl ether, 2-isobornylphenol and 2-isocamphylphenol, the ratio between them being determined by the nature of heteropolyacid and carrier (ZrO2 or TiO2).

  DOI：

  10.1134/s0036024413020246

文献信息

• Unusual direction in the alkylation of 1-naphthol with camphene in the presence of aluminum phenoxide and isopropoxide
  作者：I. Yu. Chukicheva、O. A. Shumova、K. Yu. Suponitskii、A. V. Kutchin

  DOI：10.1007/s11172-011-0079-x

  日期：2011.3

  Alkylation of 1-naphthol with camphene in the presence of aluminum phenoxide gives 2-isocamphyl-1-naphthol as a major product, while in the case of aluminum isopropoxide 2-isobornyl-1-naphthol is mainly formed and the content of 4-terpenyl-1-naphthols increases.

  在酚铝存在下，1-萘酚与莰烯的烷基化得到 2-isocamphyl-1-naphthol 作为主要产物，而在异丙醇铝的情况下，主要形成 2-isobornyl-1-naphthol 和 4-terpenyl 的含量-1-萘酚增加。
• Alkylation of phenol by β-pinene in the presence of aluminum phenolate
  作者：I. Yu. Chukicheva、O. A. Shumova、A. V. Kuchin

  DOI：10.1007/s10600-012-0154-z

  日期：2012.3

  The alkylation of phenol by β-pinene using Al(OPh)3 as a catalyst was studied. It was found that the composition of the products depended on the ratio of starting materials. The principal products were chromane-type ethers with an equimolar ratio of starting materials and an excess of phenol. ortho-Alkylated phenol and an ether with a terpene substituent of bornyl structure were formed with a two-fold

  以Al(OPh)3为催化剂，研究了β-蒎烯对苯酚的烷基化反应。发现产品的组成取决于原料的比例。主要产品是具有等摩尔比的起始原料和过量苯酚的色烷型醚。邻烷基化苯酚和具有冰片基结构萜烯取代基的醚与两倍过量的β-蒎烯形成。
• Sulfated Zirconia-catalyzed Alkylation of Phenol with Camphene and Isomerization of n-butane
  作者：Svetlana A. Popova、Irina Yu. Chukicheva、Alexander V. Kutchin、Andrei L. Tarasov、Leonid M. Kustov

  DOI：10.1016/j.mencom.2014.03.011

  日期：2014.3

  Sulfated zirconia modified with polyvalent cations is capable of catalyzing alkylation of phenol with camphene and isomerization of n-butane into isobutane.
• Rearrangement of bornyl phenyl ether
  作者：I. Yu. Chukicheva、O. A. Shumova、A. V. Kutchin

  DOI：10.1134/s1070428013070233

  日期：2013.7
• URETHANE ADHESIVE COMPOSITION
  申请人：The Yokohama Rubber Co., LTD.

  公开号：US20220002599A1

  公开（公告）日：2022-01-06

  An object of the present invention is to provide a urethane adhesive composition excellent in adhesion durability for an olefin resin. The present invention is a urethane adhesive composition containing a urethane prepolymer having an isocyanate group, an isocyanurate compound of pentamethylene diisocyanate and/or hexamethylene diisocyanate, and a secondary aminosilane compound.