Camphoronsaeure | 464-89-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Camphoronsaeure
• 英文别名: 1,2,2-trimethyl-3-oxo-cyclopentanecarboxylic acid；(+/-)-camphononic acid；1,2,2-Trimethyl-3-oxo-cyclopentancarbonsaeure；(+/-)-Camphononsaeure；(+/-)-3-Oxo-1.2.2-trimethyl-cyclopentan-carbonsaeure-(1)；Cyclopentanecarboxylicacid, 1,2,2-trimethyl-3-oxo-(8CI,9CI)；1,2,2-trimethyl-3-oxocyclopentane-1-carboxylic acid
• CAS: 464-89-1
• 化学式: C₉H₁₄O₃
• 分子量: 170.208
• InChiKey: LRGIELAZPCCUKY-UHFFFAOYSA-N

物化性质

• 沸点：
  282.7±33.0 °C(Predicted)
• 密度：
  1.103±0.06 g/cm3(Predicted)
• 熔点：
  229-230 °C

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Camphoronsaeure 生成 3-hydroxy-1,2,2-trimethyl-cyclopentanecarboxylic acid
  参考文献：
  名称：

  Bredt, Justus Liebigs Annalen der Chemie, 1909, vol. 366, p. 1,Anm. 2

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-dimethyl-3-oxo-cyclopentanecarboxylic acid ethyl ester 生成 Camphoronsaeure
  参考文献：
  名称：

  SYNTHETIC INVESTIGATIONS IN THE CAMPHOR SERIES. PART I A NEW SYNTHESIS OF CAMPHONONIC ACID.¹

  摘要：

  DOI：

  10.1021/jo01119a003

文献信息

• Noyes; Gorsline; Potter, Journal of the American Chemical Society, 1912, vol. 34, p. 66
  作者：Noyes、Gorsline、Potter

  DOI：——

  日期：——
• Noyes; Coss, Journal of the American Chemical Society, 1920, vol. 42, p. 1282
  作者：Noyes、Coss

  DOI：——

  日期：——
• Almandine megacrysts from Yingfengling Cenozoic basalt in Leizhou Peninsula and their parental magma origin
  作者：Jinhai Yu、S. Y. O’Reilly

  DOI：10.1007/bf02900606

  日期：2001.7

  The garnet megacrysts from Yingfengling basalts are characterized by high FeO (>20%), CaO (7.02% -8.16%) and low MgO (5.88%-10.87%). Significant composition variations are observed in these megacrysts, of which Ni, V, Sc, Co, and HREE are positively correlated with their Mg-#, and Zr, Hf, Ga, Y, Sr, Nb, Zn and LREE-MREE are negatively correlated with Mg-#. Megacryst parent magma is a highly evolved residual melt with strongl depletion in Ti, Sr, Hf, Nb and HREE. This parental magma was generated by more than 60% of crystallization fractionation of clinopyroxene, garnet, plagioclase and ilmenite from quartz tholeiitic magma. It has not erupted to the surface, but stayed at the upper mantle and formed the megacrystic cumulate. Megacrysts and their host basalt are in disequilibrium.
• Ganguly, Journal of the Indian Chemical Society, 1943, vol. 20, p. 101,104
  作者：Ganguly

  DOI：——

  日期：——
• Lapworth; Lenton, Journal of the Chemical Society, 1901, vol. 79, p. 1287
  作者：Lapworth、Lenton

  DOI：——

  日期：——