2-丁基十二酸 | 25354-95-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-丁基十二酸
• 英文名称: 2-Butyl-dodecansaeure
• 英文别名: 2-butyldodecanoic acid
• CAS: 25354-95-4
• 化学式: C₁₆H₃₂O₂
• 分子量: 256.429
• InChiKey: NELJNBHLVVOMLC-UHFFFAOYSA-N

物化性质

• 沸点：
  172-174 °C(Press: 2 Torr)
• 密度：
  0.8821 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-丁基十二酸 在 [Ir(dF(CF₃)ppy)₂(dtbbpy)](PF₆) 、 caesium carbonate 、 溴代丙二酸二乙酯 作用下， 以 氯苯 为溶剂， 反应 4.0h， 以90%的产率得到5-bromopentadecane
  参考文献：
  名称：

  通过可见光促进的脱羧卤化作用催化接触到烷基溴化物，氯化物和碘化物

  摘要：

  本文报道了脂肪族羧酸的催化，可见光促进的脱羧卤化（溴化，氯化和碘化）。该操作简单的反应可耐受一定范围的官能团，可在室温下进行，并且是氧化还原中性的。通过与铱原子源一起使用铱光催化剂，可以避免使用化学计量的金属，例如银，汞，th和铅。该反应使人们能够从大量廉价的，容易获得的羧酸中获得有价值的合成构件。

  DOI：

  10.1002/chem.201602251
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 2-丁基十二酸
  参考文献：
  名称：

  Stanley; Jay; Adams, Journal of the American Chemical Society, 1929, vol. 51, p. 1266

  摘要：

  DOI：

文献信息

• Ester Compounds, Lubricating Oil Compositions Containing Same and Processes for Making Same
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20190100710A1

  公开（公告）日：2019-04-04

  This disclosure relates to ester compounds derived from neo-alcohol, lubricating oil base stocks comprising such ester compounds, lubricating oil compositions comprising such ester compounds, and method for making such compounds and/or base stocks. The lubricating oil base stocks comprising the ester compounds exhibit desirable lubricating properties such as polarity and oxidation stability.

  本公开涉及从新醇衍生的酯化合物、包含这种酯化合物的润滑油基础油、包含这种酯化合物的润滑油组合物，以及制备这种化合物和/或基础油的方法。包含这种酯化合物的润滑油基础油具有理想的润滑性能，如极性和氧化稳定性。
• Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids
  作者：Lisa Candish、Lena Pitzer、Adrián Gómez-Suárez、Frank Glorius

  DOI：10.1002/chem.201600421

  日期：2016.3.24

  decarboxylative di‐ and trifluoromethylthiolation of alkyl carboxylic acids promoted by visible light. This approach enables the synthesis of biologically relevant alkyl SCF2H and SCF3 compounds from cheap and abundant carboxylic acids. The method is operationally simple, using irradiation from household light sources, and its mild reaction conditions make it tolerant of a range of functional groups

  本文描述了一种新的，直接的，可见光促进的烷基羧酸的脱羧二和三氟甲基硫醇化反应。这种方法能够从廉价和丰富的羧酸合成生物学上相关的烷基SCF 2 H和SCF 3化合物。该方法操作简单，使用家用光源照射，反应条件温和，可耐受各种官能团。该策略使用了亲电子邻苯二甲酰亚胺衍生的二氟和三氟甲基硫醇化试剂，并利用了亚胺基自由基携带自由基链的能力。
• PROCESSES FOR PREPARING VINYLIDENE DIMER DERIVATIVES
  申请人：ExxonMobil Research and Engineering Company

  公开号：US20180086682A1

  公开（公告）日：2018-03-29

  This disclosure provides a process for producing vinylidene dimer derivatives by subjecting one or more vinylidene dimers and one or more carbonyl-containing compounds to a carbonyl-ene reaction, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure also provides a process for producing vinylidene dimer derivatives by reacting one or more vinylidene dimers with one or more carbonyl-containing compounds, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure further provides vinylidene dimer derivatives (e.g., vinylidene dimer derived alcohols and esters) produced by these processes. This disclosure still further provides for hydrogenating/reacting the vinylidene dimer derived alcohols with acids or anhydrides to produce vinylidene dimer derived esters. This disclosure yet further relates to lubricating ester oil base stocks, and lubricating oils containing the lubricating ester oil base stocks.

  本公开提供了一种通过将一个或多个乙烯二聚体和一个或多个含羰基化合物置于羰基-烯反应中，可选地在催化剂的存在下，生产一个或多个乙烯二聚体衍生醇的过程。本公开还提供了一种通过将一个或多个乙烯二聚体与一个或多个含羰基化合物反应，可选地在催化剂的存在下，生产一个或多个乙烯二聚体衍生醇的过程。本公开进一步提供了通过这些过程生产的乙烯二聚体衍生物（例如，乙烯二聚体衍生醇和酯）。本公开还提供了将乙烯二聚体衍生醇与酸或酐氧化/反应以生产乙烯二聚体衍生酯的方法。本公开还涉及润滑酯油基础油和含有润滑酯油基础油的润滑油。
• Immiscible displacement of oil with surfactant system
  申请人：Phillips Petroleum Company

  公开号：US04556495A1

  公开（公告）日：1985-12-03

  In accordance with the present invention it has been found that improved recovery of oil from a subsurface earth formation can be attained by injecting into the formation a surfactant system comprising a carboxylate surfactant, a cosurfactant and an electrolyte in concentrations and proportions to form an immiscible three-phase system with the reservoir oil comprising a predominantly oil phase, a microemulsion phase and an aqueous phase. The carboxylate surfactant is preferably selected from the group consisting of branched aliphatic carboxylates and mononuclear aromatic carboxylates. Where aliphatic carboxylates are utilized as a surfactant, it is preferred that the polar organic material utilized as a cosurfactant have a solubility in water less than about ten grams per hundred grams of water at about 20.degree. C. and, when an aromatic carboxylate is utilized as a surfactant, it is preferred that the polar organic material utilized as a cosurfactant have a water solubility greater than about ten grams per hundred grams of water at about 20.degree. C. In accordance with another aspect of the present invention, it has been found that surfactant systems containing carboxylate surfactants will recover optimum amounts of oil when a base is added to the surfactant system to adjust the pH to a value at which the surfactant system results in optimum oil recovery.

  根据本发明，发现通过向地下地层注入包含羧酸盐表面活性剂、共表面活性剂和电解质的表面活性剂体系，可以实现从地下地层中改善油的回收。这些物质的浓度和比例可形成与储层油不相混的三相系统，其中包括主要为油相、微乳液相和水相。羧酸盐表面活性剂优选从支链脂肪酸盐和单核芳香族羧酸盐组成的群体中选择。当脂肪酸盐被用作表面活性剂时，优选的极性有机物作为共表面活性剂在约20℃时水中的溶解度小于约10克/100克水。当芳香族羧酸盐被用作表面活性剂时，优选的极性有机物作为共表面活性剂在约20℃时水中的溶解度大于约10克/100克水。根据本发明的另一个方面，发现含有羧酸盐表面活性剂的表面活性剂体系，当碱被添加到表面活性剂体系中以调整pH值到使表面活性剂体系达到最佳油回收时，将回收最佳量的油。
• Water-soluble viscosity increasing agent and detergent composition containing the same
  申请人：Kao Corporation

  公开号：EP0260640A2

  公开（公告）日：1988-03-23

  A water-soluble viscosity increasing agent consisting essentially of: (i) an ester of a 40 to 400 moles ethylene oxide adduct of polyhydric alcohol and a C8-36 branched fatty acid, (ii) an ester of polyethylene glycol having average molecular weight of 2,000 to 20,000 and a C8-36 branched fatty acid, and (iii) a 40 to 400 mole ethylene oxide adduct of an ester of a polyhydric alcohol and a C8-36 branched fatty acid. The viscosity increasing agent can increase the viscosity of solutions of various surface active agents, while maintaining their stability and solubility in the solutions. When it is formulated to a detergent suitable for washing textiles, tablewares, human skins, hairs and the like, it can provide a detergent composition with a proper viscosity as well as a good detergency.

  一种水溶性增粘剂，其主要成分为：(i) 40 至 400 摩尔环氧乙烷加合物的多元醇和 C8-36 脂肪酸支链的酯，(ii) 平均分子量为 2,000 至 20,000 的聚乙二醇和 C8-36 脂肪酸支链的酯，以及 (iii) 40 至 400 摩尔环氧乙烷加合物的多元醇和 C8-36 脂肪酸支链的酯。 该增粘剂可以增加各种表面活性剂溶液的粘度，同时保持它们在溶液中的稳定性和溶解性。 当它配制成适用于洗涤纺织品、餐具、人的皮肤、毛发等的洗涤剂时，可以提供具有适当粘度和良好去污力的洗涤剂组合物。