N,N-二丁基-2-甲基丙烯酰胺 | 22240-86-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: N,N-二丁基-2-甲基丙烯酰胺
• 英文名称: N,N-Di-n-butylmethacrylamid
• 英文别名: Dibutylmethacrylamid；N,N-DI-N-Butylmethacrylamide；N,N-dibutyl-2-methylprop-2-enamide
• CAS: 22240-86-4
• 化学式: C₁₂H₂₃NO
• mdl: MFCD00080467
• 分子量: 197.321
• InChiKey: LZMQMUZCPILQGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2924199090

反应信息

• 作为反应物：
  描述：

  N,N-二丁基-2-甲基丙烯酰胺 以50%的产率得到
  参考文献：
  名称：

  MALXASYAN A. TS.; SUKIASYAN G. G.; GRIGORYAN R. T.; ENGOYAN A. P.; MARTIR+, AJKAKAN CCP TITUTYUNNERI AKADEMIA. ZEKUJTSNER, DOKL. AN ARMSSR, 1978, 66,+

  摘要：

  DOI：
• 作为产物：
  描述：

  丙二烯 、 一氧化碳 、 二正丁胺 在 十二羰基三钌 作用下， 以 1,4-二氧六环 为溶剂， 100.0 ℃ 、1.32 MPa 条件下， 反应 18.0h， 以68%的产率得到N,N-二丁基-2-甲基丙烯酰胺
  参考文献：
  名称：

  Ruthenium-catalyzed carbonylation of allene: direct synthesis of methacrylates and methacrylamides

  摘要：

  在温和的条件下，在钌羰基催化剂的存在下，醇和胺中的烯烃发生羰基化反应，分别生成甲基丙烯酸酯和甲基丙烯酸酰胺，产率良好，原子经济性达到 100%。

  DOI：

  10.1039/b205817k

文献信息

• [EN] NITROGEN-CONTAINING ORGANOSILICON COMPOUND, METHOD OF MANUFACTURE, AND METHOD OF TREATING SURFACES<br/>[FR] COMPOSE ORGANOSILICIE CONTENANT DE L'AZOTE, PROCEDE DE PRODUCTION ET PROCEDE DE TRAITEMENT DE SURFACES
  申请人：DOW CORNING TORAY SILICONE

  公开号：WO2004087719A1

  公开（公告）日：2004-10-14

  A new nitrogen-containing organosilicon compound contains tertiary amine groups and carbonyl groups wherein the tertiary amine groups are selected from R1R2N- (where R1 and R2 are the same or different univalent hydrocarbon groups of 1-15 carbon atoms), alicyclic amino groups, or heterocyclic amino groups containing in their rings one or more tertiary amine groups.

  一种新的含氮有机硅化合物包含三级胺基团和羰基团，其中三级胺基团选自R1R2N-（其中R1和R2是1-15个碳原子的相同或不同的一价碳氢基团）、脂环氨基团，或在其环中含有一个或多个三级胺基团的杂环氨基团。
• Inverse latex of anionic polyelectrolytes in silicone oils; cosmetic use thereof
  申请人：SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES, S.E.P.P.I.C.

  公开号：EP1932515A1

  公开（公告）日：2008-06-18

  Composition comprising an oil phase, an aqueous phase, at least one emulsifying system of water-in-oil (W/O) type, optionally at least one emulsifying system of oil-in-water (O/W) type, in the form of an inverse latex comprising from 10% to 80% by mass and preferably from 20% to 70% by mass and most preferably from 30% to 60% by mass, of a linear partially or totally salified anionic polyelectrolyte, with wherein in that said oil phase comprises a silicone oil or a mixture of silicone oils; its use to thicken and or to emulsify cosmetic, dermopharmaceutical or pharmaceutical compositions.

  包括油相、水相、至少一种水包油（W/O）型乳化系统、可选地至少一种油包水（O/W）型乳化系统的组合物，以反向乳胶的形式，包括质量百分含量为10%至80%，优选为20%至70%，最优选为30%至60%的线性部分或完全盐化的阴离子聚电解质；其中所述油相包括硅油或硅油混合物；其用途是用于增稠和/或乳化化妆品、皮肤药物或药用组合物。
• BLOCK POLYMER, COSMETIC COMPOSITION COMPRISING IT AND COSMETIC TREATMENT PROCESS
  申请人：FARCET Celine

  公开号：US20100021408A1

  公开（公告）日：2010-01-28

  A block polymer containing, in a block with a Tg greater than 20° C., at least one monomer of formula (I): The invention also relates to a cosmetic composition comprising the block polymer in a cosmetically acceptable medium, and also to a cosmetic process for treating keratin materials using the composition, and most particularly to a process for making up the lips.

  一种块状聚合物，其中包含至少一种式(I)的单体，该单体位于Tg大于20℃的块中。本发明还涉及一种含有该块状聚合物的美容组合物，以及使用该组合物处理角蛋白材料的美容过程，尤其是涂抹唇部的过程。
• Dispersion of polymer particles, composition comprising it and cosmetic treatment method
  申请人：Mougin Nathalie

  公开号：US20070081954A1

  公开（公告）日：2007-04-12

  The present patent application relates to novel dispersions of particles of a polymer which is stabilized at the surface, in a nonaqueous medium, in which dispersions the polymer exhibits a specific glass transition temperature. Another aspect of the present disclosure is a cosmetic or pharmaceutical composition comprising the said dispersion in a cosmetically or pharmaceutically acceptable medium. The present disclosure also relates to a method for the cosmetic treatment of keratinous substances employing the presently disclosed composition.

  本专利申请涉及一种新型聚合物颗粒分散体，该聚合物在非水介质中表面稳定，并在分散体中表现出特定的玻璃转移温度。本公开还涉及一种化妆品或药物组合物，该组合物包含所述分散体和化妆品或药学上可接受的介质。本公开还涉及一种使用所述组合物进行角质质物的美容治疗的方法。
• Preparation of carboxylic acid amides
  申请人：Rohm GmbH

  公开号：US04228102A1

  公开（公告）日：1980-10-14

  What is disclosed is a method for making amides of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, R.sub.3 is straight-chain or branched alkyl or unsubstituted or substituted aryl, and R.sub.4 is hydrogen or straight-chain or branched unsubstituted or substituted alkyl, which comprises reacting an ester of the formula ##STR2## wherein R.sub.2 is alkyl having 1 to 6 carbon atoms, with heating and under autogenous pressure, in a homogeneous phase, with an amine of the formula ##STR3## said amine being present in an amount which is stoichiometrically deficient up to an amount which is in small stoichiometric excess with respect to said ester.

  公开的是一种制备式为##STR1##的酰胺的方法，其中R.sub.1为氢或甲基，R.sub.3为直链或支链烷基或未取代或取代芳基，R.sub.4为氢或直链或支链未取代或取代烷基，该方法包括在均相相中，在加热和自发压力下，用式为##STR2##的酯与式为##STR3##的胺反应，所述胺的量在化学计量上不足，直到略微超量于所述酯。