dimethyl[bis(2-methylprop-2-en-1-yl)]silane | 17906-60-4

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: dimethyl[bis(2-methylprop-2-en-1-yl)]silane
• 英文别名: di(2-methylallyl)-dimethylsilane；bis(methallyl)dimethylsilane；dimethyl-bis-(2-methyl-allyl)-silane；dimethallyl-dimethyl-silane；Dimethallyl-dimethyl-silan；Dimethyl-dimethallyl-silan；Dimethylbis(2-methylprop-2-en-1-yl)silane；dimethyl-bis(2-methylprop-2-enyl)silane
• CAS: 17906-60-4
• 化学式: C₁₀H₂₀Si
• 分子量: 168.354
• InChiKey: HWGHQQLCXFZXDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.85
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dimethyl[bis(2-methylprop-2-en-1-yl)]silane 生成 1,7-Dimercapto-2,4,4,6-tetramethyl-4-sila-heptan
  参考文献：
  名称：

  The Preparation of Certain Carbon-functional Silathiols and Silathio Esters

  摘要：

  DOI：

  10.1021/jo01049a512
• 作为产物：
  描述：

  二氯二甲基硅烷 以 not given 为溶剂， 以46%的产率得到dimethyl[bis(2-methylprop-2-en-1-yl)]silane
  参考文献：
  名称：

  Petrov, A. D.; Nikishin, G. I., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya

  摘要：

  DOI：

文献信息

• Synthesis of Heterofunctionalised Diamines and Triamines by Hydroaminomethylation of Diallyl Ethers, -silanes, or -amines
  作者：Peter Eilbracht、Christian Ludger Kranemann、Lars Bärfacker

  DOI：10.1002/(sici)1099-0690(199908)1999:8<1907::aid-ejoc1907>3.0.co;2-s

  日期：1999.8

  Starting from diallyl ethers, -silanes, or -amines various di- or triamines with potential biological activity are obtainable in one step by RhI-catalysed hydroaminomethylation of the alkene moieties in the presence of synthesis gas.

  从二烯丙基醚，-silanes开始，或-胺各种二-或具有潜在生物活性三胺在一个步骤中获得的由铑我在合成气体的存在-催化的烯烃部分的hydroaminomethylation。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 16, page 48 - 53
  作者：

  DOI：——

  日期：——
• All-Carbon-Substituted Vinylsilane Stable to TBAF:  Synthesis of Allyldimethylvinylsilane and Its Pd-Catalyzed Cross-Coupling under Mild Conditions
  作者：Lianhai Li、Neenah Navasero

  DOI：10.1021/ol061288l

  日期：2006.8.1

  Allyldimethylvinylsilanes 3 are easily synthesized by the reaction of silylallylmetals, generated from 1 by n-BuLi/t-BuOK, with carbonyl compounds in the absence or presence of metal halides. They can tolerate 2 equiv of TBAF in THF at room temperature for at least 6 h but can be easily activated in the presence of a palladium catalyst and TBAF to perform the cross-coupling reaction with aryl iodides at room temperature.
• Catalytic Synthesis of Linear Oligosiloxanes and Germasiloxanes Mediated by Scandium Trifluoromethanesulfonate
  作者：Grzegorz Hreczycho、Krzysztof Kuciński、Piotr Pawluć、Bogdan Marciniec

  DOI：10.1021/om400581g

  日期：2013.9.9

  Sc(OTf)(3)-catalyzed coupling reaction of silanediols with 2-methylallylsilanes and germanes leading to SiO-Si or SiO-Ge bond formation with the evolution of isobutylene is described. Diisopropyl-substituted silanediols of the general formula HO(i-Pr)(2)Si[OSi(i-Pr)(2)](n)OH (n = 0,1) have been successfully functionalized by using 2-methylallylsilanes or 2-methylallylgermanes in the presence of scandium trifluoromethanesulfonate to yield new linear tri- and tetrasiloxanes or germasiloxanes under mild conditions. The reaction can be readily extended to the synthesis of high molecular weight polysiloxanes by using di(methylallyl)silane as a metalating agent. Unsaturated oligosiloxane products have been used as substrates for further functionalization via catalytic silylative coupling and hydrosilylation reactions:
• Studies in Organosilicon Chemistry. XXXV. Preparation of Certain Olefinic and Alkylsilanes
  作者：LEONARD D. NASIAK、HOWARD W. POST

  DOI：10.1021/jo01086a012

  日期：1959.4