4-(2-methylhex-1-en-1-yl)morpholine | 1424343-35-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 4-(2-methylhex-1-en-1-yl)morpholine
• CAS: 1424343-35-0
• 化学式: C₁₁H₂₁NO
• 分子量: 183.294
• InChiKey: ZTPQPMUXYWNSEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  13.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  12.47
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  吗啉 、 1-己烯 、 一氧化碳 在 氢气 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 4.0h， 生成 4-(庚-1-烯-1-基)吗啉 、 庚醛 、 蛋白酶K 、 3-己烯 、 4-(2-methylhex-1-en-1-yl)morpholine 、 2-己烯
  参考文献：
  名称：

  Rhodium complex encapsulated functionalized hexagonal mesoporous silica for heterogeneous hydroaminomethylation

  摘要：

  HRh(CO)(PPh3)(3) complex was encapsulated into the pores of amino functionalized hexagonal mesoporous silica. The catalyst was characterized by physico-chemical techniques like P-XRD, P-31-CPMAS NMR, FT-IR, SEM, ICP and N-2 adsorption analysis. The catalyst was active for hydroaminomethylation and a variety of alkenes and amines were used as reactants for hydroaminomethylation. The catalyst afforded to achieve 100% conversion with high (>95%) selectivity to corresponding amines. Parametric variations were performed by taking 1-hexene and morpholine as representative reactants for the study of catalyst amount, temperature, pressure and 1-hexene:morpholine ratio. Significant amounts of aldehydes and enamines were observed during the course of the reaction indicating that there could be two possible rate determining steps. The catalyst was effectively recycled up to five times without much loss in its activity and selectivity. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.12.021