nonyloxy-ethene | 10160-48-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: nonyloxy-ethene
• 英文别名: nonyl-vinyl ether；Nonyl-vinyl-aether；vinyl nonyl ether；n-Nonylvinylaether；n-Nonylvinylether；Nonane, 1-(ethenyloxy)-；1-ethenoxynonane
• CAS: 10160-48-2
• 化学式: C₁₁H₂₂O
• 分子量: 170.295
• InChiKey: MIMKRVLJPMYKID-UHFFFAOYSA-N

物化性质

• 沸点：
  206.1-207.0 °C
• 密度：
  0.8089 g/cm3(Temp: 420 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  12
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  nonyloxy-ethene 在 盐酸 、 air 作用下， 以 甲醇 为溶剂， 生成 2-nonyloxy-ethanethiol
  参考文献：
  名称：

  Prilezhaeva,E.N. et al., Doklady Chemistry, 1964, vol. 154, p. 33 - 36

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯基乙醚 、 1-壬醇 在 mercury(II) diacetate 作用下， 反应 18.0h， 生成 nonyloxy-ethene
  参考文献：
  名称：

  从伯醇中简便地一锅法合成对称和不对称乙醛缩醛

  摘要：

  摘要 在乙酸汞 (11) 存在下用乙基乙烯基醚处理伯醇 1，然后在对甲苯磺酸存在下用相同或不同的醇处理，初步形成乙烯基醚 2，得到对称和不对称乙醛缩醛 3 的总产率良好。该方法很容易扩大规模，并代表了对当前可用程序的显着改进。

  DOI：

  10.1080/00397919208019270

文献信息

• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• Nucleophilic Addition to Acetylenes in Superbasic Catalytic Systems: XIII. Fluoride Cesium Containing Systems, Efficient Catalysts for Alkanols Vinylation
  作者：L. A. Oparina、S. I. Shaikhudinova、L. N. Parshina、O. V. Vysotskaya、Th. Preiss、J. Henkelmann、B. A. Trofimov

  DOI：10.1007/s11178-005-0222-y

  日期：2005.5

  New catalytic systems CsF-MOH (M = Li, Na) were developed for the synthesis of alkyl vinyl ethers comparable in efficiency to cesium alcoholates. The addition of primary and secondary alcohols to acetylene occurs in the presence of these systems at the atmospheric (DMSO, 100°C) or at enhanced (without solvent, 135–140°C) acetylene pressure and affords alkyl vinyl ethers in up to 93% yield.

  新开发了用于合成烷基乙烯基醚的催化体系CsF-MOH（M = Li，Na），其效率可与铯醇盐相媲美。在常压（DMSO，100℃）或增强压力（无溶剂，135-140℃）下，在乙炔存在下，这些体系可使伯醇和仲醇加成到乙炔上，生成高达93％收率的烷基乙烯基醚。
• COPOLYMERS AND COMPOSITIONS WITH ANTI-ADHESIVE AND ANTIMICROBIAL PROPERTIES
  申请人：BASF SE

  公开号：US20160235062A1

  公开（公告）日：2016-08-18

  The invention relates to a copolymer exhibiting both antimicrobial and anti-adhesive properties as well as to a hydrogel. Said hydrogel is obtained from the inventive copolymer and a substrate. Another part of the invention is a process for making the hydrogel, as well as different uses of the inventive copolymer as well as of the hydrogel.

  该发明涉及一种既具有抗菌和抗粘附性能的共聚物，又涉及一种水凝胶。所述水凝胶是由该创新共聚物和基质制得的。该发明的另一部分是制备水凝胶的方法，以及该创新共聚物和水凝胶的不同用途。
• PROCESS FOR PRODUCTION OF HIGH-PURITY VINYL ETHER
  申请人：TENJIMBAYASHI Ryuichi

  公开号：US20100249465A1

  公开（公告）日：2010-09-30

  A process for producing a high-purity vinyl ether, which comprises: a step of subjecting an alcohol represented by the general formula (1) R—O—H  (1) to a vinyl ether formation reaction in the presence of a catalyst to synthesize a vinyl ether represented by the general formula (2), R—O—CH═CH 2 (2) a step of removing the catalyst from the reaction mixture obtained in the above step to obtain a crude vinyl ether containing the vinyl ether and the unreacted raw material alcohol, a step of reacting the unreacted raw material alcohol in the crude vinyl ether, with the vinyl ether in the presence of an acid catalyst, to convert the alcohol into an acetal represented by the general formula (3), and a step of subjecting a crude vinyl ether containing the acetal (III) to distillation to obtain a high-purity vinyl ether.

  生产高纯度乙烯醚的方法，包括：在催化剂存在下，将通式（1）R—O—H代表的醇进行乙烯醚形成反应，合成通式（2）R—O—CH═CH2代表的乙烯醚的步骤；从上述步骤得到的反应混合物中去除催化剂，得到含有乙烯醚和未反应原料醇的粗乙烯醚的步骤；在酸催化剂存在下，将粗乙烯醚中的未反应原料醇与乙烯醚反应，将醇转化为通式（3）代表的缩醛的步骤；将含有缩醛（III）的粗乙烯醚经过蒸馏，得到高纯度乙烯醚的步骤。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。