1,1-dibenzyloxy-3,3,3-trifluoropropane | 932395-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-dibenzyloxy-3,3,3-trifluoropropane
• 英文别名: 1,1,1-trifluoro-3,3-dibenzyloxypropane；(3,3,3-trifluoro-1-phenylmethoxypropoxy)methylbenzene
• CAS: 932395-41-0
• 化学式: C₁₇H₁₇F₃O₂
• 分子量: 310.316
• InChiKey: MDDCICFFIPRNBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (1Z)-1-benzyloxy-3,3,3-trifluoropropene 、 (E)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene 、 1,1-dibenzyloxy-3,3,3-trifluoropropane 在 硫酸 水 作用下， 以86.8%的产率得到3,3,3-三氟丙醛
  参考文献：
  名称：

  PROCESS FOR PRODUCING 3,3,3-TRIFLUOROPROPIONIC ACID

  摘要：

  公开号：

  EP1950191B1
• 作为产物：
  描述：

  3,3,3-三氟丙烯 、 苯甲醇 在 palladium on activated charcoal 、 氧气 、 copper dichloride 作用下， 120.0 ℃ 、1.0 MPa 条件下， 反应 8.0h， 以23%的产率得到1,1-dibenzyloxy-3,3,3-trifluoropropane
  参考文献：
  名称：

  通过Pd / C催化3,3,3-三氟丙烯的缩醛化反应以原子经济方式合成3,3,3-三氟丙醛二烷基缩醛

  摘要：

  已经开发了一种简便有效的方法，可以从容易获得的3,3,3-三氟戊烯（TFP）一步合成3,3,3-三氟丙醛二烷基缩醛。该催化剂可以循环使用四次，而不会明显地...

  DOI：

  10.1039/c6ra03208g

文献信息

• Process for Producing 3,3,3-Trifluoropropionaldehyde
  申请人：Komata Takeo

  公开号：US20090105506A1

  公开（公告）日：2009-04-23

  There is provided a process for producing 3,3,3-trifluoropropionaldehyde, including the step of hydrolyzing a benzyl vinyl ether of the formula [1] in the presence of a catalyst selected from the group consisting of Arrhenius acids and Lewis acids, where R represents phenyl or phenyl having a substituent R 1 selected from the group consisting of alkyl groups, alkoxy groups, halogen atoms, nitro groups and amino groups.

  提供了一种制备3,3,3-三氟丙醛的方法，包括在阿伦尼乌斯酸和路易斯酸所选的催化剂存在下水解公式[1]的苄基乙烯醚的步骤，其中R代表苯基或具有从烷基，烷氧基，卤素原子，硝基和氨基组成的取代基R1的苯基。
• WO2007/37119
  申请人：——

  公开号：——

  公开（公告）日：——
• PROCESS FOR PRODUCING 3,3,3-TRIFLUOROPROPIONALDEHYDE
  申请人：Central Glass Co., Ltd.

  公开号：EP1930310B1

  公开（公告）日：2011-11-16
• Process For Producing 3,3,3-Trifluoropropionic Acid
  申请人：Komata Takeo

  公开号：US20090247786A1

  公开（公告）日：2009-10-01

  A benzyl vinyl ether represented by the following formula is hydrolyzed in the presence of a catalyst selected among Arrhenius acids and Lewis acids to obtain 3,3,3-trifluoropropionaldehyde. Subsequently, the 3,3,3-trifluoropropionaldehyde is oxidized with an oxidizing agent. Thus, 3,3,3-trifluoropropionic acid can be more advantageously produced than in conventional techniques from an inexpensive starting material.
• ENDOSCOPE DESIGNS AND METHODS OF MANUFACTURE
  申请人：Wright George

  公开号：US20110263941A1

  公开（公告）日：2011-10-27

  Various embodiments of the present invention comprise endoscopes for viewing inside a cavity of a body such as a vessel like a vein or artery. These endoscopes may include at least one solid state emitter such as a light emitting diode (LED) that is inserted into the body cavity to provide illumination therein. Certain embodiments of the invention comprise disposable endoscopes that can be fabricated relatively inexpensively such that discarding these endoscopses after a single use is cost-effective. The endoscope may comprise a lens holder on a distal end of the endoscope for collection of light reflected from surfaces within the body in which the endoscope is inserted. This lens holder may have an inner cavity through which light passes along an optical path. Reflective surfaces on sidewalls of the inner cavity may direct light along this optical path. The endoscope may further comprise an elongated support structure for supporting a plurality of lenses disposed along the optical path. This optical path may lead to a detector onto which images are formed.