2,10-二氨基-6-[4-(2-氨基-2-羧基乙基)-1H-咪唑-1-基]-5-{[(5-氨基-5-羧基-2-羟基戊基)氨基]甲基}十一烷二酸(non-preferredname) | 51346-64-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 2,10-二氨基-6-[4-(2-氨基-2-羧基乙基)-1H-咪唑-1-基]-5-{[(5-氨基-5-羧基-2-羟基戊基)氨基]甲基}十一烷二酸(non-preferredname)
• 英文名称: CF3CClFCHF2
• 英文别名: HCFC-226ba；2-Chloro-1,1,1,2,3,3-hexafluoropropane
• CAS: 51346-64-6
• 化学式: C₃HClF₆
• 分子量: 186.484
• InChiKey: SCDLWHGUKGDYQD-UHFFFAOYSA-N

物化性质

• 沸点：
  16.74°C (rough estimate)
• 密度：
  1.2904 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3,3,3-三氟丙烯 在 氢氟酸 、 氯 作用下， 生成 1H-七氟丙烷 、 2,10-二氨基-6-[4-(2-氨基-2-羧基乙基)-1H-咪唑-1-基]-5-{[(5-氨基-5-羧基-2-羟基戊基)氨基]甲基}十一烷二酸(non-preferredname)
  参考文献：
  名称：

  Compositions

  摘要：

  公开号：

  EP2634165B1

文献信息

• Reaction of hexafluoropropene with halogenoalkanes
  作者：Robert N. Haszeldine、Ronald Rowland、Anthony E. Tipping、Geoffrey Tyrrell

  DOI：10.1016/s0022-1139(00)81246-4

  日期：1982.10

  Insertion of hexafluoropropene under thermal and/ or photochemical conditions occurs into C-H bonds of the halogenomethanes MeCl, CH2Cl2, CHCl3, MeF, CH2F2 and CHF2Cl and the fluoroethanes EtF, MeCHF2 and MeCF3, into CH and CCl bonds of the monochloroalkanes EtCl, MeCHFCl, prnCl, priCl, ButCl and BuiCl and into CCl bonds of allyl chloride and the chloroalkanes CH2ClCH2Cl, MeCHCl2, CH2ClCHCl2 and

  在热和/或光化学条件下，六氟丙烯插入卤代甲烷MeCl，CH 2 Cl 2，CHCl 3，MeF，CH 2 F 2和CHF 2 Cl的CH键中，以及氟代乙烷EtF，MeCHF 2和MeCF 3插入C中。在monochloroalkanes ETCL，MeCHFCl，PR的H和CCl键ñ氯，PR我氯，卜吨Cl和卜我Cl和成烯丙基氯CCl的键和氯代CH 2 CLCH 2氯，MeCHCl 2，CH 2 ClCHCl 2和MeCCl 3。
• [EN] PROCESS FOR THE PREPARATION OF 1,1,1,3,3,3-HEXAFLUOROPROPANE AND AT LEAST ONE OF 1,1,1,2,3,3-HEXAFLUOROPROPANE AND 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE<br/>[FR] PROCEDE POUR PREPARER DU 1,1,1,3,3,3-HEXAFLUOROPROPANE, DU 1,1,1,2,3,3-HEXAFLUOROPROPANE ET/OU DU 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE
  申请人：DU PONT

  公开号：WO2005037742A1

  公开（公告）日：2005-04-28

  A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and at least one 1,1,1,2,3,3-hexafluoropropane (HFC-236ea) and 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea). The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCl=CX2 (where each X is independently F or Cl) to produce a product including both CF3CCl2CF3 and CF3CClFCClF2; (b) reacting CF3CCl2CF3 and CF3CClFCClF2 produced in (a) with hydrogen to produce a product comprising CF3CH2CF3 and at least one compound selected from the group consisting of CHF2CHFCF3, and CF3CHFCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one compound selected from the group consisting of CHF2CHFCF3 and CF3CHFCF3. In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including a ZnCr2O4/crystalline α-chromium oxide composition, a ZnCr2O4/crystalline α-chromium oxide composition which has been treated with a fluorinating agent, a zinc halide/α-chromium oxide composition and/or a zinc halide/α-chromium oxide composition which has been treated with a fluorinating agent.

  揭示了一种用于制造1,1,1,3,3,3-六氟丙烷（HFC-236fa）和至少一种1,1,1,2,3,3-六氟丙烷（HFC-236ea）以及1,1,1,2,3,3,3-七氟丙烷（HFC-227ea）的工艺。该工艺涉及(a)反应HF、Cl2和至少一种具有分子式CX3CCl=CX2的卤代丙烯，其中每个X独立地为F或Cl，以产生包括CF3CCl2CF3和CF3CClFCClF2在内的产物；(b)将(a)中产生的CF3CCl2CF3和CF3CClFCClF2与氢反应，以产生包括CF3CH2CF3和从CHF2CHFCF3和CF3CHFCF3组成的至少一种化合物的产物；(c)从(b)中产生的产物中回收CF3CH2CF3和从CHF2CHFCF3和CF3CHFCF3组成的至少一种化合物。在(a)中，CF3CCl2CF3和CF3CClFCClF2在存在包括ZnCr2O4/结晶α-氧化铬组合物、经过氟化剂处理的ZnCr2O4/结晶α-氧化铬组合物、锌卤化合物/α-氧化铬组合物和/或经过氟化剂处理的锌卤化合物/α-氧化铬组合物的氯氟化催化剂的情况下产生。
• Selective Reduction of Halopolyfluorocarbons by Organosilicon Hydrides
  作者：Viacheslav A. Petrov

  DOI：10.1021/jo9807363

  日期：1998.10.1

  It is demonstrated that silicon hydrides can be used for reduction of polyfluorinated halocarbons. For example, the reaction between CF(3)CCl(2)F and excess triethylsilane, catalyzed by benzoyl peroxide, leads to the formation of a mixture containing CF(3)CHClF (major), CF(3)CH(2)F, and ClSi(C(2)H(5))(3). On the other hand, the reaction of chlorofluoroalkanes, containing an internal -CCl(2)- group

  已证明氢化硅可用于还原多氟化卤代烃。例如，CF（3）CCl（2）F和过量的三乙基硅烷之间的反应（由过氧化苯甲酰催化）导致形成包含CF（3）CHClF（主要），CF（3）CH（2）F的混合物，和ClSi（C（2）H（5））（3）。另一方面，包含内部-CCl（2）-基团的氯氟烷烃的反应很容易同时还原两个氯，从而导致化合物如（CF（3））（2）CH（2）和CF（3） CH（2）C（2）F（5）。与氯氟烷烃相比，溴氟烷烃具有更高的反应活性，在没有催化剂的情况下，与氢硅烷的反应迅速进行，且温度较高。
• Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production
  申请人：Rao Velliyur Nott Mallikarjuna

  公开号：US20070265368A1

  公开（公告）日：2007-11-15

  A photochemical reaction apparatus including a reactor and a light source situated so that light from the light source is directed through a portion of the reactor wall is disclosed. The apparatus is characterized by the portion of the reaction wall comprising a functionalized copolymer of a terminally functionalized perfluoro(alkyl vinyl ether). Also described is a photochemical reaction process using said reactor. The functional group of the copolymer of the apparatus and the process is selected from —SO 2 F, —SO 2 CI, —SO 3 H, —CO 2 R (where R is H or C1-C3 alkyl), —PO 3 H 2 , and salts thereof. A process for increasing the flourine content of at least one compound selected from hydrocarbons and halohydrocarbons, comprising: (a) photochlorinating said at least one compound, and (b) reacting the halogenated hydrocarbon in (a) with HF. A process for producing an olefinic compound, comprising: (a) photochlorinating at least one compound selected from hydrocarbons and halohydrocarbons containing at least two carbon atoms and at least two hydrogen atoms to produce a halogenated hydrocarbon containing a hydrogen substituent and a chlorine substituent on adjacent carbon atoms; and (b) subjecting the halogenated hydrocarbon produced in (a) to dehydrohalogenation.

  公开了一种光化学反应装置，包括反应器和光源，使来自光源的光线通过反应器壁的一部分。该装置的特征在于反应壁的部分包括末端官能化的全氟（烷基乙烯基醚）共聚物。还描述了使用该反应器的光化学反应过程。该装置和过程的共聚物的官能团从以下中选择：—SO2F，—SO2CI，—SO3H，—CO2R（其中R为H或C1-C3烷基），—PO3H2和其盐。一种用于增加至少一种选择自碳氢化合物和卤代碳氢化合物的氟含量的过程，包括：（a）光氯化至少一种化合物，和（b）将（a）中的卤代碳氢化合物与HF反应。一种生产烯烃化合物的方法，包括：（a）光氯化至少一种选择自含有至少两个碳原子和至少两个氢原子的碳氢化合物和卤代碳氢化合物的化合物，以生成在相邻碳原子上具有氢取代基和氯取代基的卤代碳氢化合物;和（b）对（a）中产生的卤代碳氢化合物进行脱卤化。
• WO2008/54782
  申请人：——

  公开号：——

  公开（公告）日：——