苯甲醇,4-(二丁基氨基)- | 131719-64-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯甲醇,4-(二丁基氨基)-
• 英文名称: 4-dibutyl-amino-benzyl alcohol
• 英文别名: [4-(Dibutylamino)phenyl]methanol
• CAS: 131719-64-7
• 化学式: C₁₅H₂₅NO
• mdl: MFCD06202781
• 分子量: 235.37
• InChiKey: QYWIGVVZXFVCAL-UHFFFAOYSA-N

物化性质

• 沸点：
  365.5±17.0 °C(Predicted)
• 密度：
  0.979±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  苯甲醇,4-(二丁基氨基)- 在 sodium hydroxide 、 溶剂黄146 、 potassium iodide 作用下， 以 1,4-二氧六环 、 氯仿 、 水 为溶剂， 反应 82.25h， 生成 3-{4-[2-(4-dibutylaminophenyl)vinyl]phenyl}-1-(4-[2,2';6',2"]terpyridin-4'-ylbenzyl)-3H-imidazol-1-ium bromide
  参考文献：
  名称：

  A highly selective colorimetric chemosensor for detecting the respective amounts of iron(ii) and iron(iii) ions in water

  摘要：

  合成了一种新型的颜色计化学传感器，该传感器含有三吡啶。它在中性水溶液中对Fe(II)和Fe(III)离子表现出高选择性和灵敏度，尽管存在Cd2+、Cr3+、Zn2+、Co2+、Ni2+、Cu2+、Pb2+、Na+、Ca2+、Mg2+、K+和Ag+等其他金属离子。当加入Fe2+或Fe3+时，传感器在其吸收光谱中显示出一个独特的新峰，约在567 nm处，并且溶液的颜色从浅黄色变为浅洋红色。特别是，可以使用光吸收比变化法（LARVA）来检测溶液中Fe(II)和Fe(III)离子的各自含量。

  DOI：

  10.1039/b701201m
• 作为产物：
  描述：

  ethyl 4-butyramidobenzoate 在 lithium aluminium tetrahydride 、 sodium hydride 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 28.0h， 生成 苯甲醇,4-(二丁基氨基)-
  参考文献：
  名称：

  Bellucci; Gualtieri; Scapecchi, Il Farmaco, 1989, vol. 44, # 12, p. 1167 - 1191

  摘要：

  DOI：

文献信息

• A convergent synthesis of (diphenylvinyl)benzene (DPVB) star-shaped compounds with tunable redox, photo- and electroluminescent properties
  作者：Rafael Gómez、Dirk Veldman、Bea M. W. Langeveld、José L. Segura、René A. J. Janssen

  DOI：10.1039/b707496d

  日期：——

  In this paper we describe a convenient and convergent approach to the synthesis of novel and highly luminescent (diphenylvinyl)benzene (DPVB)-based conjugated star-shaped molecules, which can be used as emitting dyes in doped OLEDs. The versatility of this synthetic route allows tuning of the HOMO–LUMO energy levels of the materials by means of the introduction of different electroactive peripheral groups. Two related star-shaped dyes have been prepared, one with amine and one with alkoxy end groups, and have been characterized using optical spectroscopy and cyclic voltammetry. The energy levels of the dyes are found to lie within the band gap of a polyfluorene (PF) derivative such that energy transfer from the photoexcited PF to the dyes takes place. In OLEDs that contain 1 wt% of dye in PF, the emission is predominantly from the dye. Although the EL spectra are similar for the two dyes, other device characteristics differ greatly. OLEDs using the amine-terminated dye have a luminance that is a few orders of magnitude lower than that based on the alkoxy-terminated dye. The differences are explained by the positioning of the HOMO and LUMO levels of the two dyes compared to those of PF. The dye with the amine end group can act as a deep trap for holes, reducing charge transport in the film.

  本文描述了一种方便且收敛的方法来合成新型且高发光的（二苯乙烯基）苯（DPVB）基共轭星形分子，这些分子可作为掺杂OLED中的发光染料。该合成路线的多功能性允许通过引入不同的电活性周边基团来调节材料的HOMO-LUMO能级。制备了两种相关的星形染料，一种带有胺端基，另一种带有烷氧基端基，并利用光谱学和循环伏安法进行了表征。发现这些染料的能级位于聚芴（PF）衍生物的带隙内，使得从光激发的PF到染料的能量转移得以进行。在含有1 wt%染料的PF的OLED中，发射主要来自染料。尽管两种染料的EL光谱相似，但其他器件特性差异很大。使用胺端基染料的OLED的亮度比基于烷氧基端基染料的OLED低几个数量级。这些差异可以通过两种染料的HOMO和LUMO能级相对于PF的能级位置来解释。带有胺端基的染料可以作为深阱捕获空穴，减少了薄膜中的电荷传输。
• 5-Aryl-1.3.3.-trimethyl-2-methylene-indoline derivatives and salts thereof, methods for the production and use of said compounds for the temporary coloration of fibres
  申请人：——

  公开号：US20030213071A1

  公开（公告）日：2003-11-20

  A method for the synthesis of 5-aryl-1,3,3,-trimethyl-2-methylene-indoline derivatives of Formula (I) or its salts of Formula (Ia) 1 wherein 1 mole of a 5-aryl-2,3,3-trimethyl-3H-indole derivative of Formula (VII) is reacted for 1 to 44 hours at a temperature of 20° to 180° C. in an apolar, aprotic or polar, protic or polar aprotic solvent with 1 to 50 moles of a compound of Formula R1-A; new compounds of Formulas (I)/(Ia) and (V), obtainable by this method 2 as well as an agent containing at least one compound of Formula (I)/(Ia) and a carbonyl/inune compound for dyeing keratinic fibers and a method for temporarily dyeing keratin fibers, for which the keratin fiber is dyed with the aforementioned agent and the dyeing, so obtained, is removed again at any later time by a sulfite preparation.

  一种合成式(I)的5-芳基-1,3,3-三甲基-2-亚甲基吲哚衍生物或式(Ia)的盐的方法，其中1摩尔的式(VII)的5-芳基-2,3,3-三甲基-3H-吲哚衍生物在无极性，无质子或极性，质子或极性无质子溶剂中与1至50摩尔的式R1-A的化合物在20℃至180℃的温度下反应1至44小时；通过该方法获得的新化合物包括式(I)/(Ia)和(V)；以及一种含有至少一种式(I)/(Ia)化合物和用于染色角质纤维的羰基/不饱和化合物的制剂和一种暂时染色角质纤维的方法，其中将角质纤维染色剂染色，所得的染色可以在以后的任何时候通过亚硫酸盐制剂去除。
• Synthesis, Electronic Characterisation and Significant Second‐Order Non‐Linear Optical Responses of <i>meso</i> ‐Tetraphenylporphyrins and Their Zn ^II Complexes Carrying a Push or Pull Group in the β Pyrrolic Position
  作者：Elisabetta Annoni、Maddalena Pizzotti、Renato Ugo、Silvio Quici、Tamara Morotti、Maurizio Bruschi、Patrizia Mussini

  DOI：10.1002/ejic.200500292

  日期：2005.10

  the synthesis and characterisation by electronic absorption spectroscopy, cyclic voltammetry and by a solvatochromic investigation of meso-tetraphenylporphyrins and their ZnII complexes substituted at the β pyrrolic position by a pseudo-linear, π-delocalised organic linker carrying either an electron-withdrawing (pull) or electron-donating (push) group. The second-order NLO response of these push-pull

  这项工作描述了通过电子吸收光谱、循环伏安法和溶剂化变色研究中四苯基卟啉及其 ZnII 配合物的合成和表征，这些配合物在 β 吡咯位置被带有吸电子的假线性、π-离域有机连接体取代。 （拉）或给电子（推）组。这些推挽卟啉发色团的二阶 NLO 响应已通过 EFISH 技术研究，其非共振入射波长为 1.907 µ;m。在 β 吡咯位置被电子受体 π 系统取代的卟啉环表现为重要的供体基团，与二茂铁基团或酞菁相当。不料，在 β 吡咯位置被电子供体 π 系统取代的卟啉环显示出更大且显着的二阶 NLO 响应。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
• Materials, methods, and uses for photochemical generation of acids and/or radical species
  申请人：Marder Seth

  公开号：US20050173683A1

  公开（公告）日：2005-08-11

  The present invention provides compounds and compositions, which include: at least one chromophore having strong simultaneous two-photon or multi-photon absorptivity; at least one acid- or radical-generator in close proximity to the chromophore; such that the single- or multi-photon excitation of the chromophore results in the generation of an acid and/or redical that is capable of activating chemistry; and such that compositions of matter based on the componds and compositions of the invention can be photo-patterned by one- or multiphoton excitation.

  本发明提供了化合物和组合物，其中包括：至少一种具有强烈的同时双光子或多光子吸收性的色团；至少一个与色团相邻的酸或自由基发生剂；这样，色团的单光子或多光子激发会产生能够激活化学反应的酸和/或自由基；并且基于该发明的化合物和组合物的物质组成可以通过单光子或多光子激发进行光图案化。
• Materials, methods and uses for photochemical generation of acids and/or radical species
  申请人：The Arizona Board of Regents on behalf of the University of Arizona

  公开号：EP2236488A1

  公开（公告）日：2010-10-06

  The present invention provides compounds and compositions, including a selenonium or sulfonium group, which include; at least one chromophore having strong simultaneous two-photon or multi-photon absorptivity; at least one acid- or radical-generator in close proximity to the chromophore; such that the single- or multi-photon excitation of the chromophore results in the generation of an acid and/or radical that is capable of activating chemistry; and such that compositions of matter based on the compounds and compositions of the invention can be photo-patterned by one- or multi-photon excitation.

  本发明提供了包括硒基或锍基团的化合物和组合物，其中包括：至少一个具有强同步双光子或多光子吸收性的发色团；至少一个靠近发色团的酸或自由基发生器；这样，发色团的单光子或多光子激发会导致产生能够激活化学反应的酸和/或自由基；并且，基于本发明化合物和组合物的物质组合物可以通过单光子或多光子激发进行光图案化。