3,5-bis[3-(tert-butyldimethylsilyloxy)propyloxy]benzyl alcohol | 247122-94-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,5-bis[3-(tert-butyldimethylsilyloxy)propyloxy]benzyl alcohol
• 英文别名: [3,5-bis[3-[tert-butyl(dimethyl)silyl]oxypropoxy]phenyl]methanol
• CAS: 247122-94-7
• 化学式: C₂₅H₄₈O₅Si₂
• 分子量: 484.824
• InChiKey: XLLXTZXFYRNSHA-UHFFFAOYSA-N

物化性质

• 沸点：
  512.2±50.0 °C(Predicted)
• 密度：
  0.970±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.76
• 重原子数：
  32
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  57.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3,5-bis[3-(tert-butyldimethylsilyloxy)propyloxy]benzyl alcohol 在 18-冠醚-6 、 potassium carbonate 、 三乙胺 、 lithium bromide 作用下， 以 四氢呋喃 、 二氯甲烷 、 丙酮 为溶剂， 反应 24.0h， 生成 Methanesulfonic acid 3,5-bis-{3,5-bis-[3-(tert-butyl-dimethyl-silanyloxy)-propoxy]-benzyloxy}-benzyl ester
  参考文献：
  名称：

  Dendrimeric Catalysts for the Activation of Hydrogen Peroxide. Increasing Activity per Catalytic Phenylseleno Group in Successive Generations

  摘要：

  [GRAPHICS]Dendrimeric polyphenylselenides are prepared in high yield using propyloxy spacers to connect the phenyseleno groups to the dendrimeric core. The selenides catalyze the oxidation of bromide with hydrogen peroxide to give positive bromine species that can be captured by cyclohexene in two-phase systems. The increase in the rate of catalysis exceeds statistical contributions for the first few generations with 3, 6, and 12 phenylseleno groups.

  DOI：

  10.1021/ol990836a
• 作为产物：
  描述：

  3,5-二羟基苯甲醇 、 (3-溴丙氧基)叔丁基二甲基硅烷 在 18-冠醚-6 、 potassium carbonate 作用下， 生成 3,5-bis[3-(tert-butyldimethylsilyloxy)propyloxy]benzyl alcohol
  参考文献：
  名称：

  Dendrimeric Catalysts for the Activation of Hydrogen Peroxide. Increasing Activity per Catalytic Phenylseleno Group in Successive Generations

  摘要：

  [GRAPHICS]Dendrimeric polyphenylselenides are prepared in high yield using propyloxy spacers to connect the phenyseleno groups to the dendrimeric core. The selenides catalyze the oxidation of bromide with hydrogen peroxide to give positive bromine species that can be captured by cyclohexene in two-phase systems. The increase in the rate of catalysis exceeds statistical contributions for the first few generations with 3, 6, and 12 phenylseleno groups.

  DOI：

  10.1021/ol990836a

文献信息

• HYBRID ANTI-FOULING COATING COMPOSITIONS AND METHODS FOR PREVENTING THE FOULING OF SURFACES SUBJECTED TO A MARINE ENVIRONMENT
  申请人：Detty R. Michael

  公开号：US20080026027A1

  公开（公告）日：2008-01-31

  The present invention relates to a coating composition including a sol-gel matrix and a dendrimeric organochalcogeno derivative and a system including the coating composition and a substrate. The present invention also relates to a method of preventing fouling of surfaces subjected to a marine environment.

  本发明涉及一种包括溶胶-凝胶基体和树状有机硫属衍生物的涂层组合物，以及包括该涂层组合物和基底的系统。本发明还涉及一种防止海洋环境下表面污垢的方法。
• Dendrimeric Organochalcogen Catalysts for the Activation of Hydrogen Peroxide:  Improved Catalytic Activity through Statistical Effects and Cooperativity in Successive Generations
  作者：Charles Francavilla、Michael D. Drake、Frank V. Bright、Michael R. Detty

  DOI：10.1021/ja002649+

  日期：2001.1.1

  Dendrimeric polyphenylsulfides, -selenides, and -tellurides are prepared in high yield using propyloxy spacers to connect the phenylchalcogeno groups to the dendrimeric core. The selenides and tellurides catalyze the oxidation of bromide with hydrogen peroxide to give positive bromine species that can be captured by cyclohexene in two-phase systems. The corresponding sulfides show no catalytic activity. The increase in the rate of catalysis followed statistical effects for 1, 6, and 12 phenyltelluro groups. However, the increase in the rate of catalysis exceeds statistical contributions for the first few generations with 1, 3, 6, and 12 phenylseleno groups and suggested cooperativity among phenylseleno groups. The increase in catalytic rate was lost upon replacing all but one phenylseleno group with phenoxy groups. On the basis of H2O2 consumed, the dendrimer with 12 phenylseleno groups has a turnover number of >60 000 mol of H2O2 consumed per mole of catalyst.