O¹,O²,O³,O⁶-Tetramethacryloyl-O⁴-(tetra-O-methacryloyl-α-D-glucopyranosyl)-ξ-D-glucopyranose

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: O¹,O²,O³,O⁶-Tetramethacryloyl-O⁴-(tetra-O-methacryloyl-α-D-glucopyranosyl)-ξ-D-glucopyranose
• 英文别名: [(2R,3R,4S,5R)-4,5,6-tris(2-methylprop-2-enoyloxy)-3-[(2R,3R,4S,5R,6R)-3,4,5-tris(2-methylprop-2-enoyloxy)-6-(2-methylprop-2-enoyloxymethyl)oxan-2-yl]oxyoxan-2-yl]methyl 2-methylprop-2-enoate
• 化学式: C₄₄H₅₄O₁₉
• 分子量: 886.901
• InChiKey: KCQCEFXLUGLPCG-JGWJAVCQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  63
• 可旋转键数：
  28
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  238
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  12-(benzyloxy)dodecan-1-ol 、 O¹,O²,O³,O⁶-Tetramethacryloyl-O⁴-(tetra-O-methacryloyl-α-D-glucopyranosyl)-ξ-D-glucopyranose 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 生成 C₅₉H₈₀O₁₉ 、 C₅₉H₈₀O₁₉
  参考文献：
  名称：

  Permethacrylated carbohydrates: synthesis and reactivity in glycosidation reaction

  摘要：

  The synthesis of various permethacrylated mono- and disaccharides in acceptable yields is reported. The reactivity of these unusual polymerizable compounds has been investigated in diverse glycosidation reaction conditions. New original polymerizable donor sugars have been prepared successfully in good to excellent yields. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.08.083
• 作为产物：
  描述：

  甲基丙烯酸酐 、 D-(+)-纤维二糖 在 吡啶 作用下， 生成 O¹,O²,O³,O⁶-Tetramethacryloyl-O⁴-(tetra-O-methacryloyl-α-D-glucopyranosyl)-ξ-D-glucopyranose
  参考文献：
  名称：

  Methacrylic Esters of Glucose and Other Carbohydrates¹

  摘要：

  DOI：

  10.1021/ja01222a508

文献信息

• Permethacrylated carbohydrates: synthesis and reactivity in glycosidation reaction
  作者：Christelle Zandanel、Charles Mioskowski、Rachid Baati、Alain Wagner

  DOI：10.1016/j.tet.2009.08.083

  日期：2009.11

  The synthesis of various permethacrylated mono- and disaccharides in acceptable yields is reported. The reactivity of these unusual polymerizable compounds has been investigated in diverse glycosidation reaction conditions. New original polymerizable donor sugars have been prepared successfully in good to excellent yields. (c) 2009 Elsevier Ltd. All rights reserved.
• Methacrylic Esters of Glucose and Other Carbohydrates¹
  作者：R. H. Treadway、E. Yanovsky

  DOI：10.1021/ja01222a508

  日期：1945.6