Lavandulifolioside | 131903-54-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Lavandulifolioside
• 英文别名: lanandulifolioside；stachysoside A；ehrenoside；[(2R,3R,4R,5R,6R)-4-[(2S,3R,4R,5R,6S)-4,5-Dihydroxy-6-methyl-3-[(2S,3R,4S,5S)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-6-[2-(3,4-dihydroxyphenyl)ethoxy]-5-hydroxy-2-(hydroxymethyl)oxan-3-yl] (E)-3-(3,4-dihydroxyphenyl)prop-2-enoate
• CAS: 131903-54-3
• 化学式: C₃₄H₄₄O₁₉
• 分子量: 756.712
• InChiKey: UDHCHDJLZGYDDM-LVDCRSFESA-N

物化性质

• 沸点：
  1030.8±65.0 °C(Predicted)
• 密度：
  1.65±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2
• 重原子数：
  53
• 可旋转键数：
  13
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  304
• 氢给体数：
  11
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  Lavandulifolioside 在 盐酸 作用下， 反应 2.0h， 生成 毛蕊花糖苷 、 木通苯乙醇苷 A
  参考文献：
  名称：

  Nine phenethyl alcohol glycosides from Stachys sieboldii

  摘要：

  Three new phenethyl alcohol glycosides together with six known compounds have been isolated from the leaves of Stachys sieboldii. On the basis of chemical and spectral analyses, the structures of three new compounds named stachysosides A, B and C have been established as 2-(3,4-dihydroxyphenyl)ethyl O-alpha-L-arabinopyr-anosyl-(1-->2)-alpha-L-rhamnopyranosyl-(1-->3)-4-O-E-caffeoyl-beta-D-glucopyranoside, 2-(3,4-dihydroxyphenyl)ethyl O-alpha-L-arabinopyranosyl-(1-->2)-alpha-L-rhamnopyranosyl-(1-->3)-4-O-E-feruloyl-beta-D-glucopyranoside and 2-(3-hydroxy-4-methoxyphenyl)ethyl O-alpha-L-arabinopyranosyl-(1-->2)-alpha-L-rhamnopyranosyl-(1-->3)-4-O-E-feruloyl-beta-D-glucopyranoside, respectively.

  DOI：

  10.1016/0031-9422(91)85288-b

文献信息

• Lavandulifolioside: A New Phenylpropanoid Glycoside from<i>Stachys lavandulifolia</i>
  作者：Arif Ahmet Başaran、İhsan Çaliş、Clemens Anklin、Sansei Nishibe、Otto Sticher

  DOI：10.1002/hlca.19880710612

  日期：1988.9.28

  A new phenlypropanoid glycoside has been isolated from the methanolic extract of the aerial parts of Stachys lavandulifolia (Lamiaceae), lavandulifolioside (1). On the basis of chemical and spectral data the structure of the new compound 1 has been elucidated as β-(3,4-dihydroxyphenyl)ethyl O-α-L-arabinopyranosyl-(12)-α-L-rhamnopyranosyl-(13)-4-O-caffeoyl-β-D-glucopyranoside.

  一种新的糖苷phenlypropanoid已经从地上部分的甲醇提取物中分离水苏lavandulifolia（唇形科），lavandulifolioside （1） 。根据化学和光谱数据，新化合物1的结构已阐明为β-（3,4-二羟基苯基）乙基O -α-L-阿拉伯吡喃糖基-（12）-α-L-鼠李糖基-（13） -4 - O-咖啡酰-β-D-吡喃葡萄糖苷。
• CALIS, I.;BASARAN, A. A.;SARACOGLU, I.;STICHER, O.;RUEDI, P., PHYTOCHEMISTRY, 29,(1990) N, C. 1253-1257
  作者：CALIS, I.、BASARAN, A. A.、SARACOGLU, I.、STICHER, O.、RUEDI, P.

  DOI：——

  日期：——
• MIYASE, TOSHIO;UENO, AKIRA;KITANI, TETSUYA;KOBAYASHI, HIROMI;KAWAHARA, YU+, YAKUGAKU DZASSI, 110,(1990) N, S. 652-657
  作者：MIYASE, TOSHIO、UENO, AKIRA、KITANI, TETSUYA、KOBAYASHI, HIROMI、KAWAHARA, YU+

  DOI：——

  日期：——