C18F37CH2CH2OCOCH=CH2 | 65104-64-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: C18F37CH2CH2OCOCH=CH2
• 英文别名: 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-heptatriacontafluoroeicosyl ester；3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-heptatriacontafluoroicosyl prop-2-enoate
• CAS: 65104-64-5
• 化学式: C₂₃H₇F₃₇O₂
• 分子量: 1018.25
• InChiKey: FXIGCVJVDAFVIC-UHFFFAOYSA-N

物化性质

• 沸点：
  374.5±42.0 °C(Predicted)
• 密度：
  1.671±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  62
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  39

反应信息

• 作为产物：
  描述：

  四氟乙烯 、 乙烯 、 五氟碘乙烷 、 丙烯酸钾 在 copper catalyst 4-甲氧基苯酚 、 对苯二酚 作用下， 以 叔丁醇 为溶剂， 80.0~190.0 ℃ 、300.01 kPa 条件下， 反应 9.0h， 生成 2-(全氟十二烷基)乙基丙烯酸酯 、 1H-氮杂卓,六氢-4-甲基-2-(2-吡啶基亚甲基)- 、 C14F29CH=CH2 、 C16F33CH=CH2 、 2-(全氟十四烷基)乙醇 、 二十九氟十六醇丙烯酸酯 、 三十三氟十八烷醇丙烯酸酯 、 C18F37CH2CH2OCOCH=CH2 、 1H,1H,2H,2H-全氟-1-十二醇 、 1H,1H,2H-全氟-1-癸烯 、 1,1,2,2-四氢全氟十四醇 、 1H,1H,2H,2H-全氟-1-癸醇 、 1H,1H,2H-全氟-1-十二烯 、 1H,1H,2H,2H-全氟癸基丙烯酸酯 、 1H,1H,2H,2H-全氟辛醇丙烯酸酯 、 2-全氟癸基丙烯酸乙酯
  参考文献：
  名称：

  EP1757574

  摘要：

  公开号：

文献信息

• Coating agents for producing rigid coatings resistant to scratching and soiling and rigid moulded bodies resistant to scratching and soiling and method for the production thereof
  申请人：Hasskerl Thomas

  公开号：US20060058458A1

  公开（公告）日：2006-03-16

  The invention relates to coating agents for producing rigid coatings resistant to scratching and soiling which contain: A) 1-30 mass % polymer produced by free radical polymerisation of a mixture containing A1) 1-10 weight parts of at least one sulphur compound containing at least 3 thiol groups and A2) 90-99 weight parts of alkylmethacrylate; B) 0.2-10% mass of at least one fluoralkyl(meth)acrylate having from 3 to 30 carbon atoms in an alcohol radical which comprises from 6 to 61 fluorine atoms; C) 20-80 mass % multifunctional (methyl)acrylate; D) 0.01-10 mass % of at least one initiator; E) 5-75 mass % of at least one solvent and F) 0-40 mass % ordinary additives. The rigid moulded bodies resistant to scratching and soiling and comprising a plastic substrate and scratching resistant coating are also disclosed.

  本发明涉及用于生产耐刮擦和耐脏硬质涂层的涂层剂，该涂层剂含有：A) 1-30 质量％的聚合物，由含有 A1) 1-10 重量份的至少一种含至少 3 个硫醇基团的硫化合物和 A2) 90-99 重量份的烷基甲基丙烯酸酯的混合物自由基聚合而成； B) 0.2-10%质量份的至少一种氟烷基（甲基）丙烯酸酯，其醇基中含有 3 至 30 个碳原子，其中包括 6 至 61 个氟原子；C) 20-80 质量份的多功能（甲基）丙烯酸酯；D) 0.01-10 质量份的至少一种引发剂；E) 5-75 质量份的至少一种溶剂和 F) 0-40 质量份的普通添加剂。此外，还公开了由塑料基材和抗划伤涂层组成的抗划伤和抗污硬模成型体。
• Coating Agents for Producing Formable, Scratch and Soiling-Resistant Coatings, Scratch-Resistant, Formable and Soiling-Resistant Shaped Bodies and a Method for the Production Thereof
  申请人：Becker Patrick

  公开号：US20080139690A1

  公开（公告）日：2008-06-12

  The present invention relates to coating compositions for producing formable scratchproof coatings with dirt repellency effect, comprising A) from 1% by weight to 30% by weight of a prepolymer obtainable by free-radically polymerizing a mixture comprising A1) from 1 to 10 parts by weight of at least one sulphur compound containing at least 3 thiol groups and A2) from 90 to 99 parts by weight of alkyl (meth)acrylates, B) from 0.2% by weight to 10% by weight of at least one fluoroalkyl (meth)acrylate having 6 to 60 carbon atoms in the alcohol residue and including 13 to 121 fluorine atoms, C) from 20% by weight to 80% by weight of polyfunctional (meth)acrylates, D) from 0.01% by weight to 10% by weight of at least one initiator E) from 2% by weight to 75% by weight of at least one diluent and F) from 0% by weight to 40% by weight of customary additives G) from 0.01% by weight to 10% by weight of 2,2,3,3-tetrafluoropropyl methacrylate. Additionally disclosed are scratchproof/formable and dirt-repellent mouldings comprising a polymeric substrate and a scratchproof coating.
• BINDER FOR SECONDARY BATTERY ELECTRODE, SECONDARY BATTERY ELECTRODE, AND SECONDARY BATTERY
  申请人：Fukumine Mayumi

  公开号：US20100112441A1

  公开（公告）日：2010-05-06

  The present invention aims at improving binding continuity, rate property, cycle property and short circuit ratio by lowering a inner resistance of electrode in a secondary battery. A binder for secondary battery electrode according to the present invention is comprised a polymer having weight-average molecular weight of 5000 to 2500000 formed by polymerizing a monomer composition including fluorine atom containing monomer represented by following formula (I). (R 1 is hydrogen or methyl group, R 2 is hydrocarbon group having carbon number 6 to 18 containing fluorine atom).
• US5418304A
  申请人：——

  公开号：US5418304A

  公开（公告）日：1995-05-23
• USRE36294E
  申请人：——

  公开号：USRE36294E

  公开（公告）日：1999-09-07