DAP树脂 | 1087-21-4

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: DAP树脂
• 中文别名: 间苯二甲酸丙烯酯；间苯二酸二烯丙酯树脂；异苯二甲酸二烯丙酯；间酞酸二烯丙酯；间苯二甲酸二烯丙酯；1,2-苯二甲酸二-2-丙烯酯；异酞酸二烯丙酯
• 英文名称: diallyl isophthalate
• 英文别名: diprop-2-en-1-yl benzene-1,3-dicarboxylate；metadiallyl phthalate；diallyl m-phthalate；isophthalic acid diallyl ester；Isophthalsaeure-diallylester；bis(prop-2-enyl) benzene-1,3-dicarboxylate
• CAS: 1087-21-4；25035-78-3
• 化学式: C₁₄H₁₄O₄
• mdl: MFCD00048174
• 分子量: 246.263
• InChiKey: OOORLLSLMPBSPT-UHFFFAOYSA-N

物化性质

• 熔点：
  -3℃
• 沸点：
  176-177°C 5mm
• 密度：
  1.13
• 闪点：
  163 °C
• LogP：
  3.36 at 25℃
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.142
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2917399090
• RTECS号：
  CZ4230000

制备方法与用途

1,2-苯二甲酸二-2-丙烯酯是一种羧酸酯类的有机化合物，主要用于作为医药中间体。

反应信息

• 作为反应物：
  描述：

  DAP树脂 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 、 titanium(IV) isopropylate 作用下， 以 甲苯 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  异丙醇钛促进串联自交叉和闭环复分解方法合成大四内酯

  摘要：

  展示了一种通过烯烃复分解反应合成大环四内酯的新方法，使用 Grubbs 的第二代催化剂和异丙醇钛作为助催化剂。该研究展示了一种串联的自交叉和闭环复分解方法，以形成具有优异 (E) 选择性的大环系统。该反应在官能团、催化剂、溶剂、路易斯酸、浓度和温度方面进行了优化。

  DOI：

  10.1002/ejoc.201301239
• 作为产物：
  描述：

  3-氯丙烯 生成 DAP树脂
  参考文献：
  名称：

  DZUMEDZEJ, N. V.;KAKOVKINA, R. M.;ALEKSEEV, N. N.;SHOLOGIN, I. M.;KUSTOV,+

  摘要：

  DOI：

文献信息

• SUBSTITUTED OR UNSUBSTITUTED ALLYL GROUP-CONTAINING MALEIMIDE COMPOUND, PRODUCTION METHOD THEREFOR, AND COMPOSITION AND CURED PRODUCT USING SAID COMPOUND
  申请人：DIC CORPORATION

  公开号：US20200325101A1

  公开（公告）日：2020-10-15

  Bismaleimides (BMI) exhibit excellent heat resistance (high Tg and high resistance to thermal decomposition) compared to epoxy resins and phenolic resins, and therefore, in recent years, more attention is paid to bismaleimides as a resin material for the next-generation devices represented by SiC power semiconductors, in addition to the investigation on the use of bismaleimides for electronic material applications. As such, conventional BMI's are known as highly heat-resistant resins; however, there is a demand for a resin having higher heat resistance for advanced material applications and the like. Thus, an object of the invention is to provide a novel maleimide compound having superior heat resistance. Disclosed is a substituted or unsubstituted allyl group-containing maleimide compound having a structure with three or more benzene rings, having one or more groups each having a substituted or unsubstituted allyl group, and having one or more maleimide groups.

  亚苯基马来酰亚胺化合物，具有三个或更多苯环的结构，含有一个或多个取代或未取代的烯丙基团，以及一个或多个马来酰亚胺基团，具有卓越的耐热性。
• Photochromic Compound
  申请人：Yokoyama Yasushi

  公开号：US20090299080A1

  公开（公告）日：2009-12-03

  [Problem] To provide a photochromic compound that is rapidly colored upon irradiation with ultraviolet light, and is rapidly decolored rapidly upon heat application after termination of irradiation with ultraviolet light, and to provide a process for producing the same. [Means for Solving Problems] A photochromic compound represented by general formula (I). R 1 , R 2 and R 3 are each a hydrogen atom; a functional group containing an atom in groups 15-16 of the periodic table; a halogen atom; a hydrocarbon group optionally substituted with said functional group or a halogen atom; or an optionally substituted heterocyclic group. R 1 and R 2 as well as R 2 and R 3 may be bonded to each other to form an optionally substituted carbon or heterocyclic ring. Z is a polymantylidene group. W is a divalent organic group that forms an optionally substituted carbon aromatic or heterocyclic aromatic ring together with the carbon-carbon double bond to which it is bonded.

  提供一种光致变色化合物，该化合物在紫外光照射后迅速变色，并在紫外光照射终止后施加热量后迅速褪色的方法，以及提供其制备方法。解决问题的方法是提供一种由通式（I）表示的光致变色化合物。R1、R2和R3分别为氢原子；包含周期表第15-16族中的原子的官能团；卤素原子；可选择地用所述官能团或卤素原子取代的碳氢基团；或可选择地取代的杂环基团。R1和R2以及R2和R3可以相互连接以形成可选择地取代的碳环或杂环。Z为多曼特基团。W为二价有机基团，与其相结合的碳-碳双键形成可选择地取代的碳芳香或杂环芳香环。
• Method for separating substances
  申请人：Hiratsuka Atsunori

  公开号：US20060113189A1

  公开（公告）日：2006-06-01

  An objective of the present invention is to provide electrophoretic separation methods and devices that enable the various features of a substrate surface that comes in contact with an electrophoresis medium to be controlled. The present invention provides methods for electrophoresing substances, which comprises the steps of: (a) adding a substance to be analyzed to an electrophoresis medium retained in a substrate, whose surface that has come in contact with the electrophoresis medium has been coated with a polymer membrane; and (b) adding electrophoretic pressure to the electrophoresis medium. For example, the use of a plasma-polymerized membrane allows the formation of a membrane with homogeneous quality and thickness on the surface of an arbitrary shape. In addition, desired characteristics can be conferred on the surface through selection of monomeric substances. Protein adsorption onto micro-chips can be effectively prevented as well.

  本发明的一个目标是提供电泳分离方法和设备，使接触电泳介质的基板表面的各种特征可以被控制。本发明提供了一种电泳物质的方法，包括以下步骤：(a)将待分析的物质添加到保留在基板中的电泳介质中，该基板的表面与电泳介质接触，已被涂覆聚合物膜；和(b)向电泳介质施加电泳压力。例如，使用等离子体聚合膜可以在任意形状的表面上形成具有均匀质量和厚度的膜。此外，通过选择单体物质，可以赋予表面所需的特性。蛋白质吸附到微芯片上也可以被有效地防止。
• Photochromic composition
  申请人：——

  公开号：US20040173782A1

  公开（公告）日：2004-09-09

  A photochromic composition and a coating composition comprising a molecular compound of a chromene compound and an aromatic compound. The photochromic composition provides a photochromic optical material as a cured product and the coating composition is applied to a lens substrate and cured to provide a photochromic optical material. The above molecular compound is also provided.

  一种光致变色组合物和涂层组合物，包括一种色素化合物和一种芳香化合物的分子化合物。光致变色组合物提供一种光致变色光学材料作为固化产品，涂层组合物被应用于镜片基底并固化以提供光致变色光学材料。上述分子化合物也被提供。
• COMPOUND, RESIN, COMPOSITION AND PATTERN FORMATION METHOD
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20210070727A1

  公开（公告）日：2021-03-11

  The present invention provides a compound represented by following formula (0):

  本发明提供了以下式（0）表示的化合物。

表征谱图