1,3-diundec-10-enoylpropanediol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,3-diundec-10-enoylpropanediol
• 英文别名: 1,3-propylene diundec-10-enoate；3-hydroxypropyl diundecylenoate；1,3-Diundec-10'-enoylpropanediol；3-undec-10-enoyloxypropyl undec-10-enoate
• 化学式: C₂₅H₄₄O₄
• 分子量: 408.622
• InChiKey: CHJHMAIVZJVJQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  29
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-diundec-10-enoylpropanediol 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以95.9%的产率得到
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a
• 作为产物：
  描述：

  10-烯酸甲酯 、 1,3-丙二醇 在 1,5,7-三氮杂双环[4.4.0]癸-5-烯 作用下， 反应 6.5h， 以73%的产率得到1,3-diundec-10-enoylpropanediol
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a

文献信息

• [EN] NEW PROCESS OF PREPARATION OF POLYOLS AND POLYAMINES, AND PRODUCTS AS OBTAINED<br/>[FR] NOUVEAU PROCÉDÉ DE PRÉPARATION DE POLYOLS ET DE POLYAMINES, ET PRODUITS OBTENUS
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2013072436A1

  公开（公告）日：2013-05-23

  The present invention relates to the use of a compound of formula (I) : wherein: - R represents –OH or –NH2;- A1 represents a divalent alkylene radical, straight or branched, having from 2 to 20 carbon atoms; - A2 represents a divalent alkylene radical, straight or branched, having from 1 to 20 carbon atoms; - X1 and X2 represent, independently of each other, –NH- or –O-;- A3 represents a divalent alkylene radical, straight or branched, having from 1 to 10 carbon atoms; - Z represents a hydrogen or a group of formula (A'): wherein A1, A3 and R are as defined above in formula (I), for the preparation of a polymer chosen among polyurethane, polyester and polyamide.

  本发明涉及使用公式（I）的化合物：其中：- R代表-OH或-NH2；- A1代表一个二价亚烷基基团，直链或支链，具有2到20个碳原子；- A2代表一个二价亚烷基基团，直链或支链，具有1到20个碳原子；- X1和X2分别独立地代表-NH-或-O-；- A3代表一个二价亚烷基基团，直链或支链，具有1到10个碳原子；- Z代表氢或公式（A'）的基团：其中A1、A3和R在公式（I）中如上定义，用于制备选自聚氨酯、聚酯和聚酰胺的聚合物。
• ADMET reactions in miniemulsion
  作者：Priscilla B. Cardoso、Anna Musyanovych、Katharina Landfester、Claudia Sayer、Pedro H. H. Araújo、Michael A. R. Meier

  DOI：10.1002/pola.27118

  日期：2014.5

  This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity in water if compared to the Ru‐benzylidene catalysts (Hoveyda Grubbs second generation and Grubbs first generation)

  这项工作研究水性细乳液中的无环二烯复分解（ADMET）聚合反应。评估了不同类型的钌基催化剂和不同的表面活性剂（阴离子，阳离子和非离子）。与Ru-亚苄基催化剂（Hoveyda Grubbs第二代和Grubbs第一代）相比，Ru-茚基催化剂（Umicore M2）在水中的活性更高。此外，催化剂活性受表面活性剂类型的影响。总而言之，发现Umicore M2催化剂和基于非离子聚环氧乙烷的表面活性剂Lutensol AT80是微乳液中最适合ADMET反应的组合，从而可以制备具有数均分子量（M n）达15 kDa。©2014 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2014，52，1300至1305年
• Structure and Origin of Artifacts in the Analysis of Plasmalogens
  作者：Angela Dudda、Gerhard Spiteller

  DOI：10.1002/(sici)1096-9888(199603)31:3<303::aid-jms304>3.0.co;2-5

  日期：1996.3
• Highly Selective Macrocycle Formations by Metathesis Catalysts Fixated in Nanopores
  作者：Joo-Eun Jee、Jian Liang Cheong、Jaehong Lim、Cheng Chen、Soon Hyeok Hong、Su Seong Lee

  DOI：10.1021/jo302823w

  日期：2013.4.5

  Ruthenium-based metathesis catalysts immobilized on mesocellular siliceous foam (MCF) bearing large nanopores proved highly efficient and selective for macrocyclic ring-closing metathesis (RCM). Kinetic studies revealed that the homogeneous counterpart exhibited far higher activity that accounted for more oligomerization pathways and resulted in less macrocyclization products. Meanwhile, the immobilized catalysts showed lower conversion rates leading to higher yields of macrocyclic products in a given reaction time, with conversion rates and yields dependent upon pore size, catalyst loading density, and linker length. The macrocycle formations via RCM were accelerated by increasing the pore size and decreasing the catalyst loading density while retaining the comparably high yield. The catalysts immobilized on MCF, of which silica surface is rigid and pores are relatively large, showed high conversion rates and yields compared with an analogue immobilized on TentaGel resins, of which backbone becomes flexible upon swelling in the reaction medium. It is noteworthy that the selectivity for the macrocyclic RCM can be significantly improved by tuning the catalyst initiation rates via immobilization onto the support materials in which well-defined three-dimentional network of large nanopores are deployed.
• NEW PROCESS OF PREPARATION OF POLYOLS AND POLYAMINES, AND PRODUCTS AS OBTAINED
  申请人：Centre National de la Recherche Scientifique (C.N.R.S.)

  公开号：EP2780320B1

  公开（公告）日：2017-05-17