1-甲氧基-甲醇 1-甲酸酯 | 4382-75-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1-甲氧基-甲醇 1-甲酸酯
• 中文别名: 1-甲氧基-甲醇1-甲酸酯
• 英文名称: methoxymethyl formate
• CAS: 4382-75-6
• 化学式: C₃H₆O₃
• 分子量: 90.0788
• InChiKey: VKWJMTLAAJULGF-UHFFFAOYSA-N

物化性质

• 沸点：
  102-103 °C
• 密度：
  1.1030 g/cm3(Temp: 0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  6
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2915120000

反应信息

• 作为反应物：
  描述：

  1-甲氧基-甲醇 1-甲酸酯 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Wedekind, Chemische Berichte, 1903, vol. 36, p. 1384

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲醇缩甲醛 在 敌稗 、 氯 作用下， 24.85 ℃ 、101.32 kPa 条件下， 生成 1-甲氧基-甲醇 1-甲酸酯 、 碳酸二甲酯
  参考文献：
  名称：

  Mechanisms for the chlorine atom initiated oxidation of dimethoxymethane and 1,2-dimethoxyethane in the presence of NOx

  摘要：

  The chlorine atom initiated gas-phase oxidations of dimethoxymethane and 1,2-dimethoxyethane, have been investigated in the presence of NOx. Methoxymethyl formate and dimethyl carbonate were identified as the oxidation products of dimethoxymethane with molar yields of 0.72 +/- 0.05 and 0.26 +/- 0.02 respectively. The oxidation products of 1,2-dimethoxyethane were methyl formate (1.51 +/- 0.16) and methoxyethyl formate (0.11 +/- 0.01). The results of these studies are used to elucidate simplified gas-phase atmospheric degradation schemes for the diethers and also provide valuable information on the atmospheric fate of the alkoxy radicals produced in these and similar reactions.

  DOI：

  10.1016/s0045-6535(98)00509-8

文献信息

• Some approaches to the synthesis of fluorinated alcohols and esters. I. Completely fluorinated esters from the hunsdiecker reaction of silver F-alkanoates with iodine
  作者：Neal O. Brace

  DOI：10.1016/s0022-1139(00)82668-8

  日期：1981.10

  A completely fluorinated ester of the type RFCO2CF2RF′ was obtained from reaction of silver 3,6,9-trioxa-F-undecanoate and iodine with a diluent at 130°. This new substance resembled closely the previously prepared 1,1-dichloro-F-alkyl esters and was hydrolytically and thermally labile. Substitution products, RFCOY (Y = nucleophile) and pyrolysis products, RFCOF and RF′COF were isolated and characterized

  由3,6,9-三氧杂-F-十一酸银和碘与稀释剂在130°C下反应制得R F CO 2 CF 2 R F '型的完全氟化酯。这种新物质非常类似于先前制备的1,1-二氯-F-烷基酯，并且水解和热不稳定。取代产物，R ˚F COY（Y =亲核）和热解产物，R ˚F COF和R ˚F 'COF进行分离和表征。似乎酰基次碘酸盐和碘代-F-烷烃通过S E i型过程反应生成了完全氟化的酯。
• Partially decomposed catalyst and hydrocarbon oxidation processes using the same
  申请人：Dakka Mohammed Jihad

  公开号：US20060293544A1

  公开（公告）日：2006-12-28

  The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof. The invention is also related to a process for manufacturing of a catalyst comprising mixing L-arginine, a Cu-based compound, water, and optionally another metal-based compound to form a solution; impregnating the solution onto a silica support to form a catalyst precursor; and partially decomposing the L-arginine to form the catalyst so that at least 5% of L-arginine remains in the catalyst.

  本发明涉及一种烃氧化过程。该过程包括将一个或多个烃与氧源在自由基引发剂和催化剂存在下接触。催化剂包括位于催化剂支撑物上的有机金属配合物，通过部分分解有机金属配合物获得。例如，该过程可用于从二甲氧甲烷生产二甲基碳酸酯。该发明还涉及一种部分分解的催化剂，该催化剂包括硅支撑物和有机金属配合物，其中催化剂中至少有5%的有机化合物残留。有机金属配合物包括有机化合物和基于金属的化合物，其中金属选自铜、镍和它们的组合。该发明还涉及一种催化剂制造方法，包括混合L-精氨酸、一种基于铜的化合物、水，以及可选的另一种基于金属的化合物以形成溶液；将溶液浸渍到硅支撑物上以形成催化剂前驱体；并部分分解L-精氨酸以形成催化剂，使催化剂中至少有5%的L-精氨酸残留。
• The Reaction of Olefins with Chloroalkoxyalkanes and Formic Acid in Ether
  作者：Kazuo Nishiura、Tsutomu Tagano、Yasuo Wada、Shigeo Tanimoto、Masaya Okano

  DOI：10.1246/bcsj.53.1376

  日期：1980.5

  The reaction of olefins with chloromethoxymethane (CMM) and excess formic acid in ether, in the presence of ZnCl2 or HgCl2, afforded mainly four products, 1-chloro- and 1-formyloxy-2-(formyloxymethyl)alkanes, and 3,5-dialkyl-4-chloro- and 3,5-dialkyl-4-(formyloxy)tetrahydropyrans, in various yields. In the case of styrene, the chief products were limited to the former two. Similar products were obtained

  在 ZnCl2 或 HgCl2 存在下，烯烃与氯甲氧基甲烷 (CMM) 和过量甲酸在醚中反应，主要得到四种产物，1-氯-和 1-甲酰氧基-2-（甲酰氧基甲基）烷烃和 3,5-二烷基-4-氯-和3,5-二烷基-4-（甲酰氧基）四氢吡喃，以不同的产率。就苯乙烯而言，主要产品仅限于前两者。从 1-氯-1-乙氧基乙烷 (CEE) 中获得了类似的产品，但它们的产率非常低。
• CH3OCH.bul.+, a new stable C2H4O.bul.+ isomer, and a reassessment of the oxirane.bul.+ potential surface
  作者：J. M. Buschek、J. L. Holmes、J. K. Terlouw

  DOI：10.1021/ja00258a013

  日期：1987.11
• Salomaa, Acta Chemica Scandinavica (1947), 1957, vol. 11, p. 132,138
  作者：Salomaa

  DOI：——

  日期：——