N-benzyl-1-phenylmethanediamine | 1345954-20-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-1-phenylmethanediamine
• 英文别名: N'-benzyl-1-phenylmethanediamine
• CAS: 1345954-20-2
• 化学式: C₁₄H₁₆N₂
• 分子量: 212.294
• InChiKey: OTNVYYFCEWHXNG-UHFFFAOYSA-N

物化性质

• 沸点：
  334.2±30.0 °C(Predicted)
• 密度：
  1.082±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯甲腈 在 Ni/Al₂O₃ 、 二氧化碳 、 氢气 作用下， 以 neat (no solvent) 为溶剂， 80.0 ℃ 、4.0 MPa 条件下， 生成 三苄胺 、 N-benzyl-1-phenylmethanediamine 、 N-苄烯丁胺 、 苯甲醛 、 苄胺 、 苯甲醇 、 二苄胺
  参考文献：
  名称：

  Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst

  摘要：

  Selective hydrogenation of benzonitrile was studied with Ni/Al2O3 in compressed CO2, hexane-CO2, ethanol-CO2 and H2O-CO2 systems. The phase behavior and the effect of CO2 on the conversion of benzonitrile and the yield of benzylamine were discussed. The reaction rate was retarded in solventless, hexane and ethanol, but accelerated in water in the presence of compressed CO2. The decrease in reaction rate was mainly ascribed to the formation of carbamate from benzylamine and the intermediate 1-aminodibenzylamine reacting with CO2, and it precipitated out to coat on the surface of catalyst in solventless and hexane, and the dilution effect of compressed CO2 in ethanol. But the yield of benzylamine was increased in solventless, hexane and ethanol due to the following nucleophilic addition of benzylamine and benzylimine to N-benzylidenebenzylamine was inhibited. Although, the reaction rate increased in water for the enhanced solubility of H-2 and benzonitrile in H2O and decreased mass-transfer resistance in the presence of compressed CO2, the yield of benzylamine decreased because of the acidic nature of H2O-CO2 favorites the elimination of NH3 and the formation of NH4HCO3. Accordingly, the possible reaction pathway of benzonitrile hydrogenation was proposed for all the studied systems. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2013.07.017

文献信息

• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2017099516A1

  公开（公告）日：2017-06-15

  The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound according to the present disclosure is capable of producing an organic electroluminescent device with reasonably improved color purity and efficiency.

  本公开涉及一种有机电致发光化合物和包括该化合物的有机电致发光器件。根据本公开的有机电致发光化合物能够制备出具有较好色纯度和效率的有机电致发光器件。
• [EN] A COMBINATION OF A HOST COMPOUND AND A DOPANT COMPOUND<br/>[FR] COMBINAISON D'UN COMPOSÉ HÔTE ET D'UN COMPOSÉ DOPANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015046916A1

  公开（公告）日：2015-04-02

  The present invention relates to a specific combination of dopant compounds and host compounds. By using a combination of the dopant and host compounds according to the present invention, an organic electroluminescent device has improved current efficiency compared with conventional light-emitting material, and thus has improved power efficiency at a low driving voltage.
• [EN] ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME<br/>[FR] COMPOSÉ ORGANIQUE ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT CE COMPOSÉ<br/>[KO] 유기 화합물 및 이를 포함하는 유기 전계 발광 소자
  申请人：DOOSAN CORP

  公开号：WO2015047018A1

  公开（公告）日：2015-04-02

  본 발명은 유기 화합물 및 이를 포함하는 유기 전계 발광 소자에 관한 것으로서, 본 발명에 따른 화합물은 유기 전계 발광 소자의 유기물층, 바람직하게는 발광층에 사용됨에 따라 유기 전계 발광 소자의 발광효율, 구동 전압, 수명 등을 향상시킬 수 있다.
• [EN] MULTI-COMPONENT HOST MATERIAL AND AN ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAU HÔTE À PLUSIEURS CONSTITUANTS ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT LEDIT MATÉRIAU
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015160224A1

  公开（公告）日：2015-10-22

  The present invention relates to a multi-component host material and an organic electroluminescent device comprising the same. By comprising a specific combination of the multi-component host compounds, the organic electroluminescent device according to the present invention can provide high luminous efficiency and excellent lifespan characteristics.
• [EN] MULTI-COMPONENT HOST MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAU HÔTE À CONSTITUANTS MULTIPLES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015174738A1

  公开（公告）日：2015-11-19

  The present invention relates to an organic electroluminescent device comprising at least one light-emitting layer between an anode and a cathode, wherein the light-emitting layer comprises a host and a dopant; the host consists of multi-component host compounds; at least a first host compound of the multi-component host compounds is a specific bicarbazole derivative containing an aryl group, and a second host compound is a specific carbazole derivative including a nitrogen-containing heteroaryl group. According to the present invention, an organic electroluminescent device using the multi-component host compounds has a high efficiency and long lifespan compared to the conventional organic electroluminescent device using one component of a host.