(4-羟基丁基)琥珀酸氢酯 | 56149-52-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (4-羟基丁基)琥珀酸氢酯
• 英文名称: butanedioic acid monohydroxybutyl ester
• 英文别名: 4-(4-hydroxybutoxy)-4-oxobutanoic acid；1,4-succinic acid,1,4-butanediol；1,4-butanediol. Succinic acid；butylene glycol-succinic acid；butylene glycol, succinate；1,4-butanediol succinate；(4-Hydroxybutyl) hydrogen succinate
• CAS: 56149-52-1
• 化学式: C₈H₁₄O₅
• 分子量: 190.196
• InChiKey: KCROXMKUVBDUMP-UHFFFAOYSA-N

物化性质

• 沸点：
  373.6±27.0 °C(Predicted)
• 密度：
  1.217±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1,4-丁二醇 、 丁二酸 在 titanium(IV) isopropylate 作用下， 反应 2.0h， 生成 (4-羟基丁基)琥珀酸氢酯
  参考文献：
  名称：

  Synthesis of poly(butylene succinate) through oligomerization–cyclization–ROP route

  摘要：

  首次采用化学 ROP 法生产高浓度 PBS .

  DOI：

  10.1039/c4ra03373f

文献信息

• Synthesis of Macrocyclic Dilactones through Lipases
  作者：Mª Pilar Bosch、Angel Guerrero

  DOI：10.1055/s-2005-917099

  日期：——

  We report herein a selective and efficient method to prepare macrocyclic dilactones in good yields from diols and succinic anhydride through a biocatalytic condensation reaction.

  我们在此报告了一种通过生物催化缩合反应从二醇和琥珀酸酐以良好收率制备大环双内酯的选择性和有效方法。
• Hardenable unsaturated polyester resin compositions
  申请人：Takemoto Yushi Kabushiki Kaisha

  公开号：EP0234902A2

  公开（公告）日：1987-09-02

  A hardenable unsaturated polyester resin composition contains at least one block copolymer with the unsaturated polyester. The block copolymer includes both polyester parts and liquid rubber compound parts as constituent segments.

  一种可硬化的不饱和聚酯树脂组合物含有至少一种与不饱和聚酯的嵌段共聚物。 嵌段共聚物包括聚酯部分和液态橡胶化合物部分作为组成段。
• COATED AGRICULTURAL PESTICIDE GRANULES, PROCESS FOR PREPARING THE SAME, AND USE OF THE SAME
  申请人：CHISSO CORPORATION

  公开号：EP0848906A1

  公开（公告）日：1998-06-24

  The present invention provides a coated granular pesticide comprising a granular pesticide, which comprises at least one hardly water-soluble active ingredient and at least one water-swelling substance, and a thermoplastic resin-based film which covers the surface of the granular pesticide; a method for producing the same; and applications thereof. It is preferred to incorporate, into the film, a surfactant, inorganic powder insoluble or hardly soluble in water, water-absorbing and/or water-soluble polymer fine powder, a thermosetting resin, or a biodegradable polymer insoluble or hardly soluble in water, or a combination thereof. The coated granular pesticide of the present invention can externally release the hardly water-soluble active ingredient according to the following mechanism, due to the combined effects of the thermoplastic resin as the film-forming component and the water-swelling component as the core component. The water-swelling substance absorbs the water present in the exterior of the coated granular pesticide, which gradually penetrates into the granule through the coating film, the granular pesticide containing the water-swelling substance gradually expands, cracks are thus formed on the film after the elapse of a predetermined time, a large amount of water rapidly enters into the granule through the cracks thus formed, the coated granular pesticide is rapidly swollen to thus greatly grow the cracks and to thus rapidly disintegrate the film and the hardly water-soluble active ingredient included in the coated granular pesticide is thus brought into close contact with a large amount of water to externally release the active ingredient. The foregoing components to be incorporated into the film serve to control the disintegration time of the resulting film. The gradual release of the hardly water-soluble active ingredient is initiated after a predetermined time from the application of the coated granular pesticide and therefore, the latter exhibits a desired efficacy depending on a particular crop without being accompanied by any problem of damages of crops from the pesticide and of environmental load. For instance, the coated granular pesticide of the present invention may directly be applyed on the ground or may be used in the form of a mixture with soil, but preferably the coated granule is used in the form of a substrate for raising seedlings, which may be obtained by admixing with a seedling-support substance having water-holding properties.

  本发明提供了一种包衣颗粒状农药，包括颗粒状农药（其中包含至少一种难溶于水的活性成分和至少一种遇水膨胀的物质）和覆盖颗粒状农药表面的以热塑性树脂为基材的薄膜；本发明的生产方法及其应用。最好在薄膜中加入表面活性剂、不溶于水或难溶于水的无机粉末、吸水性和/或水溶性聚合物细粉、热固性树脂或不溶于水或难溶于水的生物可降解聚合物，或它们的组合。由于热塑性树脂作为成膜成分和水膨胀成分作为核心成分的共同作用，本发明的包衣颗粒农药可以按照以下机理从外部释放难溶于水的活性成分。水膨胀物质吸收包衣颗粒状农药外部的水分，水分通过包衣膜逐渐渗入颗粒内部，含有水膨胀物质的颗粒状农药逐渐膨胀，经过预定时间后，包衣膜上形成裂纹、大量的水通过裂缝迅速进入颗粒，包衣颗粒状农药迅速膨胀，使裂缝大大增加，从而使薄膜迅速崩解，包衣颗粒状农药中几乎不溶于水的有效成分与大量的水紧密接触，从外部释放出有效成分。加入薄膜中的上述成分可以控制薄膜的崩解时间。几乎不溶于水的活性成分在施用包衣颗粒杀虫剂后的预定时间后开始逐渐释放，因此，后者可根据特定作物的情况显示出所需的药效，而不会伴随着杀虫剂对作物的损害和环境负荷问题。 例如，本发明的包衣颗粒杀虫剂可以直接施用在地面上，也可以以与土壤混合的形式使用，但包衣颗粒最好以育苗基质的形式使用，育苗基质可以通过与具有保水特性的育苗物质混合获得。
• DEGRADABLE COAT BEARING GRANULAR COMPOSITIONS FOR AGRICULTURAL AND HORTICULTURAL USE, BIODEGRADABLE RESIN COMPOSITION, MOLDINGS AND FILMS OF THE SAME, PROCESS FOR THE PRODUCTION OF FILMS, AND DEGRADABLE TRASH BAGS
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP0934918A1

  公开（公告）日：1999-08-11

  The first aspect of the present invention relates to a particle-state composition for agriculture and gardening characterized in that a coating material A or a mixture composed of the coating material A and a coating material B is coated on a particle-state fertilizer, and the coating material A is a biodegradable cellulose ester composition, and the coating material B is at least one selected from the group consisting of an olefin polymer, a copolymer containing an olefin, a polyvinylidene chloride, a copolymer containing vinylidene chloride, a diene-based polymer, waxes, a petroleum resin, a natural resin, a cellulose acetate resin, a polycaprolactone, and oils & fats and a modified product therefrom. The second aspect of the present invention relates to a biodegradable resin composition which comprises the lactone resin, the synthetic aliphatic polyester resin, and the metallic salt or amide of a fatty acid, wherein the weight ratio of the lactone resin/the synthetic aliphatic polyester resin ranges in 5/95-70/30, and a proportion of the metallic salt of a fatty acid or an amide of a fatty acid is 0.2-5 parts by weight based on 100 parts by weight of the total amount of the lactone resin and the synthetic aliphatic polyester resin, and it relates to a film molded therefrom by an inflation method. The third aspect of the present invention is a bag for garbages in which the above-mentioned bag for garbages is particularly processed as a bag for removing water having many small openings.

  本发明的第一方面涉及一种用于农业和园艺的颗粒态组合物，其特征在于在颗粒态肥料上涂覆涂层材料A或由涂层材料A和涂层材料B组成的混合物，涂层材料A是可生物降解的纤维素酯组合物、涂层材料 B 至少是选自以下组别的一种：烯烃聚合物、含烯烃的共聚物、聚偏二氯乙烯、含偏二氯乙烯的共聚物、二烯基聚合物、蜡、石油树脂、天然树脂、醋酸纤维素树脂、聚己内酯、油脂及其改性产品。 本发明的第二个方面涉及一种可生物降解的树脂组合物，它包括内酯树脂、合成脂肪族聚酯树脂和脂肪酸的金属盐或酰胺，其中内酯树脂/合成脂肪族聚酯树脂的重量比为 5/95-70/30，脂肪酸的金属盐或酰胺的比例为 0.以内酯树脂和合成脂肪族聚酯树脂总量的100份重量计，其比例为2-5份重量，本发明还涉及用充气法用其模压而成的薄膜。 本发明的第三个方面是一种垃圾袋，特别是将上述垃圾袋加工成具有许多小开口的除水袋。
• A degradable laminated body and a method for the preparation thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP0987100A2

  公开（公告）日：2000-03-22

  Disclosed are a degradable laminated body which comprises a biodegradable resin layer and a metallic thin layer, which is high in strength, excellent in degradability, high in a property for shielding from the sunlight, temperature, and moisture, not apt to charge static electricity, being readily printed, and a method for the preparation thereof.

  本发明公开了一种由可生物降解树脂层和金属薄层组成的可降解层压体，该层压体强度高、降解性好、遮蔽阳光、温度和湿度的性能高、不易带静电、易于印刷，并公开了其制备方法。