Al(c-C6H11O)3 | 1971-69-3

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: Al(c-C6H11O)3
• 英文别名: Aluminium-tricyclohexyloxid
• CAS: 1971-69-3
• 化学式: C₁₈H₃₃AlO₃
• 分子量: 324.44
• InChiKey: VIUSFAZQLJEWQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.06
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  3-[(4-氨基苯基)磺酰基]苯胺 、 Al(c-C6H11O)3 以 甲苯 、 苯 为溶剂， 反应 8.0h， 生成 N-[cyclohexyloxy(fluoro)phosphoryl]-N-methylmethanamine
  参考文献：
  名称：

  SELECTIVE BUTYRYLCHOLINESTERASE INHIBITORS AMONG DIALKYLPHOSPHORAMIDOFLUORIDATES

  摘要：

  Supposition of a relationship between blood butyrylcholinesterase (BuChE) activity and its lipid composition was reported in a number of works [1-7](dagger). To check this hypothesis, a search of selective BuChE inhibitors among substituted cyclohexyl ester N,N-dialkylphosphoramidofluoridic acids has been accomplished by us. For synthesis of substances to be investigated, interaction of N,N-dialkylphosphoramidic difluorides with Na and Al derivatives of corresponding alcohols was used. Investigation of purified, water soluble preparations of BuChE and acetylcholinesterase (AChE) indicated that there were high selective BuChE inhibitors among the investigated compounds. In particular, for N,N-diethyl-O-(trans-2-piperidinocyclohexyl)phosphoramidoflouridate, the reaction constants for cholinesterase inhibition were: k(BuChE)(0) = 1,4 X 10(8) M-1 X min(-1), k(AChE)(0) = 2,1 X 10(4) M-1 X min(-1) and for its derivative, 1-(trans-2-N,N-diethylamidofluorophosphoryloxycyclohexyl)-1-methylpiperidinium iodide k(BuChE)(0) = 2,6 X 10(7) M-1 X min(-1), while the AChE inhibition by that compound was reversible (K-i = 9,8 X 10(-6) M).

  DOI：

  10.1080/10426509708033703
• 作为试剂：
  描述：

  1,3-二苯丙烷 在 三氯化铝 、 硫酸 、 Al(c-C6H11O)3 、 环己醇 作用下， 以 氯苯 为溶剂， 反应 82.0h， 生成 2-(3-蒽-2-基丙基)蒽
  参考文献：
  名称：

  Ions derived from dianthrylethane species. How the mode of linking affects the intramolecular electron transfer

  摘要：

  Chemical and electrochemical reduction of dianthryl compounds affords mono-, di, tri-, and tetraanions via successive electron-transfer processes. The diamagnetic or paramagnetic ions are characterized by NMR and ESR spectroscopy, respectively, by cyclic voltammetry, and by quenching reactions. The title dianthryl systems have in common that two anthracene units are linked by ethane bridges in a sterically variable fashion. It appears that the mode of linking drastically affects the rate of intramolecular electron-transfer processes in radical monoanions as well as the charge-storage behavior.

  DOI：

  10.1021/ja00004a009

文献信息

• Lithium- und Caesium-Alkoxometallate
  作者：Jochen Pauls、Bernhard Neumüller

  DOI：10.1002/1521-3749(200109)627:9<2127::aid-zaac2127>3.0.co;2-7

  日期：2001.9

  ([3]n). 1, 2 und 3 wurden mittels NMR-, IR- und MS-Techniken sowie Rontgenstrukturanalysen untersucht. Danach liegt 1 als Tetramer in Losung und Festkorper vor. Das zentrale Strukturmotiv des Metallats 2 ist ein planarer, heteronuklearer LiO2Al-Vierring mit funffach-koordiniertem Li+-Ion. Im kettenformigen Koordinationspolymer [3]n wechseln sich Cs+-Ionen mit Koordinationszahl 5 und 6 ab. Lithium

  Das Aluminiumalkoxide, Al(OCH2Ph)3 (1), kann in einer Direktsynthese aus Al 和 PhCH2OH unter HgCl2-Katalyse dargestellt werden。Die Bildung des Metallats [(Diglyme)Li}Al(OtBu)4}] (2) unter Wasserstoff-Entwicklung erfolgt durch Reaktion von LiAlH4 mit tBuOH in THF 和 anschliesender Nachbehandlung mit zusatzlichem tBukenr in Diglyme Ein nukleophiler Angriff von F–-Ionen fuhrt nach Zusatz von CsF zu THF-Losungen
• Calcium alkoxyalanates
  作者：G. Dozzi、S. Cucinella、M. Bruzzone

  DOI：10.1016/s0022-328x(00)82562-0

  日期：1982.1