2-乙氧基-1,1,3,3,3-五氟丙-1-烯 | 2247-94-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: 2-乙氧基-1,1,3,3,3-五氟丙-1-烯
• 英文名称: ethyl pentafluoroisopropenyl ether
• 英文别名: 2-ethoxy-1,1,3,3,3-pentafluoro-propene；2-ethoxy-1,1,3,3,3-pentafluoropropene；2-Aethoxy-1.1.3.3.3-pentafluor-propen；Ethyl-pentafluorisopropenyl-ether；2-Ethoxyperfluoropropylene；2-Ethoxy-1,1,3,3,3-pentafluoroprop-1-ene
• CAS: 2247-94-1
• 化学式: C₅H₅F₅O
• 分子量: 176.086
• InChiKey: LLBCDOYDDNKNSQ-UHFFFAOYSA-N

物化性质

• 沸点：
  96.7±40.0 °C(Predicted)
• 密度：
  1.276±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-乙氧基-1,1,3,3,3-五氟丙-1-烯 在 三氧化硫 作用下， 生成 2-Keto-pentafluor-propansulfonsaeure-aethylester
  参考文献：
  名称：

  Sulfonation of acyclic fluorovinyl ethers

  摘要：

  DOI：

  10.1021/ja00446a037
• 作为产物：
  描述：

  六氟丙酮 、 亚磷酸三乙酯 反应 2.0h， 以79%的产率得到2-乙氧基-1,1,3,3,3-五氟丙-1-烯
  参考文献：
  名称：

  Poly(arylene ether sulfone) Statistical Copolymers Bearing Perfluoroalkylsulfonic Acid Moieties

  摘要：

  The perfluoroalkylsulfonate monomer, N,N-diisopropylethylammonium 2,2-bis(p-hydroxyphenyl)pentafluoropropanesulfonate (H PPS), was synthesized in three steps. Using triethyl phosphite, hexafluoroacetone was first converted to ethyl pentafluoroisopropenyl ether. Reaction of the ether with sulfur trioxide produced 2-ketopentafluoropropanesulfonic acid. The acid was condensed with 2 equiv of phenol, and the product was isolated as the N,N-diisopropylethylammonium salt. The structure of the final product was confirmed by X-ray crystallography. Poly(arylene ether sulfone)s (PAES) were prepared by homopolymerization of HPPS with bis(4-fluorophenyl) sulfone (FPS) and copolymerization of varying molar ratios of HPPS/biphenol (BP) with FPS. Copolymer number-average molecular weights were in the range 27 000-34 000 g/mol (GPC). Copolymer compositions ranged from 20 to 61 mol % HPPS (HPPS/BP molar ratio 0.25-1.56) as determined by F-19 NMR spectroscopy. Ion exchange capacity of the copolymers (by titration) ranged from 0.36 to 1.25 mequiv/g. Equilibrium water uptake of the copolymers at 80 degrees C and 90% relative humidity increased from 7.2 to 14.3 mol H2O/mol H+, and proton conductivity increased from 1.6 to 23 mS/cm, as the HPPS/PB ratio increased from 0.25 to 1.56.

  DOI：

  10.1021/ma102717d

文献信息

• .beta.-Carbonylpolyfluoroalkyl sulfonate esters
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04126631A1

  公开（公告）日：1978-11-21

  Novel .beta.-carbonylpolyfluoroalkyl sulfonate esters, e.g., ##STR1## are prepared by reacting SO.sub.3 with the corresponding acyclic fluorovinyl esters, e.g., CF.sub.3 CF.dbd.CFOCH.sub.3, at a temperature of about -40.degree. to 110.degree. C. These esters are useful as very active cationic initiators, e.g., for the polymerization of tetrahydrofuran.

  小说.beta.-羰基多氟烷基磺酸酯，例如，##STR1##是通过在约-40℃至110℃的温度下将SO.sub.3与相应的无环氟乙烯酯反应制备的，例如，CF.sub.3 CF.dbd.CFOCH.sub.3。这些酯类化合物可用作非常活性阳离子引发剂，例如，用于四氢呋喃的聚合反应。
• 2-Ketopentafluoropropanesulfonic acid and related acids
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04160780A1

  公开（公告）日：1979-07-10

  2-Ketopentafluoropropanesulfonic acid is obtained as a product of the reaction of sulfur trioxide and ethyl pentafluoroisopropenyl ether or by transesterification from corresponding esters. Similar sulfonic acids may be obtained by the latter process. The new compounds are useful as monomers for producing polymers, particularly moldable, dyeable, fluoropolymers, and as cationic initiators, e.g., for tetrahydrofuran polymerization.

  2-酮基五氟丙烷磺酸是由三氧化硫和乙基五氟异丙烯醚反应产生的产物，或通过相应酯的酯交换反应得到。类似的磺酸也可以通过后一种方法获得。这些新化合物可用作生产聚合物的单体，特别是可塑性、可染色、氟聚合物，以及作为阳离子引发剂，例如用于四氢呋喃聚合。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120
  作者：

  DOI：——

  日期：——
• Fluoro Ketones. II. Reactions with Trialkyl Phosphites
  作者：D. W. Wiley、H. E. Simmons

  DOI：10.1021/jo01030a051

  日期：1964.7
• Some new reactions of perfluorinated sulfonic acids
  作者：Carl G. Krespan

  DOI：10.1021/jo00394a037

  日期：1979.12