Cd(II) tetraphenyltetrabenzoporphyrinate | 80529-83-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: Cd(II) tetraphenyltetrabenzoporphyrinate
• 英文别名: cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate；cadmium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate；meso-tetraphenyltetrabenzoporphin cadmium；tetraphenyltetrabenzoporphine cadmium(II)；CdTPTBP；Cd(tetraphenyltetrabenzophorphinato)
• CAS: 80529-83-5
• 化学式: C₆₀H₃₆CdN₄
• 分子量: 925.383
• InChiKey: CZVYMXIHVGBCTI-XJTLWADGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cd(II) tetraphenyltetrabenzoporphyrinate 在 copper diacetate 、 cadmium(II) acetate 作用下， 以 二甲基亚砜 为溶剂， 生成 copper(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate
  参考文献：
  名称：

  Metal exchange reactions in cadmium complexes with porphyrins of various structures

  摘要：

  The reaction kinetics of the metal exchange Cd(II)-Cu(II) and Cd(II)-Zn(II) in the cadmium complexes (CdP) with porphyrin ligands (H(2)P) differing by degree of stiffness (tetraphenylporphin, N-methyltetraphenylporphin, and tetraphenyltetrabenzoporphin) in the DMSO medium, was studied using spectrophotometric method. The rate of metal exchange reaction depends on the nature of the non-planatrity of H(2)P in the structure of CdP complexes, as well as on the additional screening of the reaction center MN(4) by the extra-ligands and substituents. The reduction of the coordinating ability of the anion X(-) in the structure of the solvate-salt of incoming metal M'X(2)(Solv) (n-2) in a series: acetylacetonate > acetate > chloride > nitrate favors the metal exchange. In the most studied cases the reaction of CdP proceeds along a combined associative-dissociative mechanism. The order of the metal exchange reaction is found to be depending on temperature indicating a change in the contributions of associative and combined routes. The "pure" associative reaction mechanism in a medium of DMSO was for the first time found for the labile complex CdTPTBP with the saddle-type nonplanar ligand.

  DOI：

  10.1134/s1070363210030254
• 作为产物：
  描述：

  cadmium(II) acetate 、 H2TPTBP 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.02h， 以75%的产率得到Cd(II) tetraphenyltetrabenzoporphyrinate
  参考文献：
  名称：

  中-四苯基四苯并卟啉锰配合物的合成与性能

  摘要：

  用分光光度法研究了内消旋-四苯基四苯并卟啉的配位及其Cd（II）与氯化锰（II）和乙酸盐在DMF和氯仿-甲醇混合物中的金属交换。在这些反应中形成的氯化锰（III）和乙酸酸的配合物已经被分离和表征。在固体KOH存在下，将合成的配合物溶解在DMF中，得到Mn（II）内消旋-四苯基四苯并卟啉。

  DOI：

  10.1134/s1070363216080211

文献信息

• Synthesis and Spectral Properties of Ni(II), Pd(II), Pt(II), and Pt(IV) Tetraphenyltetrabenzoporphyrinates
  作者：N. V. Chizhova、O. V. Mal’tseva、R. S. Kumeev、N. Zh. Mamardashvili

  DOI：10.1134/s0036023618050200

  日期：2018.5

  Complexation reactions of 5,10,15,20-tetraphenyltetrabenzoporphyrin and transmetallation of its cadmium complex with nickel(II) acetate, Ni(II), Pd(II), and Pt(II) chlorides in dimethylformamide and phenol have been studied. The corresponding Ni(II), Pd(II), and Pt(II) porphyrinates have been synthesized. (PtBr2)-Br-IV porphyrinate has been obtained by the treatment of Pt(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate with bromine in chloroform. The obtained compounds have been characterized by elemental analysis, electronic absorption and H-1 NMR spectroscopy and mass spectrometry.
• Copper(II), cobalt(II), cobalt(III), and tin(IV) 5,10,15,20-tetraphenyl tetrabenzoporphyrinates: Synthesis and properties
  作者：N. V. Chizhova、O. V. Mal’tseva、A. V. Zav’yalov、N. Zh. Mamardashvili

  DOI：10.1134/s0036023617050072

  日期：2017.5

  The complexation reactions of 5,10,15,20-tetraphenyl tetrabenzoporphyrin and the metal exchange reactions of its cadmium(II) complex with copper(II), cobalt(II), and tin(II) acetates and chlorides in a chloroform-methanol mixture and dimethylformamide were studied spectrophotometrically. Corresponding copper(II), cobalt(II), cobalt(II), and tin(IV) porphyrinates were synthesized and identified.
• Complexation of Tetraphenyltetrabenzoporphine with Cu(II), Cd(II), Zn(II), and Co(II) Salts in Organic Solvents
  作者：D. B. Berezin、O. V. Toldina

  DOI：10.1023/b:ruco.0000037437.92306.c1

  日期：2004.8

  The rate and activation parameters of tetraphenyltetrabenzoporphine (H2TPTBP) complexation with 3d-metal acetates and acetylacetonates are shown to be determined by the solvent nature. With an increase in the electron-donor properties of a solvent, the reaction rate increases due to protonation of N-H bonds and decreases as MA(m)(Solv)(n-m) salt solvates become more stable. As the result, the rate of a reaction with ZnAc2 increases in the series: DMF < DMSO < Py < PrOH-1 < CH3CN < C6H6. In inert and weakly coordinating solvents, the transition state of a reaction is supposed to be formed according to the mechanism of contraction of the salt coordination sphere. The rate of H2TPTBP reaction with metal acetates in pyridine changes in the series: Cu(II) > Cd(II) > Zn(II) > Co(II), while the stability of the obtained complexes decreases in the series Cu(II) > Co(II) > Zn(II) > Cd(II). It is shown that the spectral criterion of the complex stability can be used in the series of metal complexes with one ligand, but it is violated if the ligand structure is changed.
• Kopranenkov, V. N.; Dashkevich, S. N.; Lukyanets, E. Ya., Journal of general chemistry of the USSR, 1981, vol. 51, p. 2165 - 2168
  作者：Kopranenkov, V. N.、Dashkevich, S. N.、Lukyanets, E. Ya.

  DOI：——

  日期：——
• Berezin, B. D.; Kharitonov, S. V.; Petrova, R. A., Koordinatsionnaya Khimiya, 1984, vol. 10, p. 520 - 524
  作者：Berezin, B. D.、Kharitonov, S. V.、Petrova, R. A.、Potapova, T. I.、Lapshina, S. A.

  DOI：——

  日期：——